Directed Ortho Metalation in 2021: A Tribute to Victor Snieckus (August 1, 1937–December 18, 2020)

ChemInform Abstract: N-Cumyl Benzamide, Sulfonamide, and Aryl O-Carbamate Directed Metalation Groups. Mild Hydrolytic Lability for Facile Manipulation of Directed ortho Metalation Derived Aromatics.

ChemInform ◽

10.1002/chin.200004067 ◽

2010 ◽

Vol 31 (4) ◽

pp. no-no

Author(s):

Costa Metallinos ◽

Sven Nerdinger ◽

Victor Snieckus

Keyword(s):

Ortho Metalation

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Solid state chemistry of molecular metal oxide clusters. Ortho metalation and hydrogen transport in [(Ph3P)2IrH2]3PW12O40 probed by phosphorus-31 NMR long-range deuterium isotope effects

Journal of the American Chemical Society ◽

10.1021/ja00188a017 ◽

1989 ◽

Vol 111 (6) ◽

pp. 2058-2062 ◽

Cited By ~ 13

Author(s):

Allen R. Siedle ◽

R. A. Newmark

Keyword(s):

Solid State ◽

Metal Oxide ◽

Long Range ◽

Isotope Effects ◽

Solid State Chemistry ◽

Hydrogen Transport ◽

Metal Oxide Clusters ◽

Ortho Metalation ◽

Deuterium Isotope Effects

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Directed ortho-Metalation Methodology. The N,N-Dialkyl Aryl O-Sulfamate as a New Directed Metalation Group and Cross-Coupling Partner for Grignard Reagents.

ChemInform ◽

10.1002/chin.200545108 ◽

2005 ◽

Vol 36 (45) ◽

Cited By ~ 1

Author(s):

Todd K. Macklin ◽

Victor Snieckus

Keyword(s):

Cross Coupling ◽

Grignard Reagents ◽

Ortho Metalation ◽

Coupling Partner

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Fast ortho-metalation reactions in binuclear dirhodium compounds. Syntheses and molecular structures of a monometalated compound and two doubly metalated compounds with head-to-head configurations

Inorganic Chemistry ◽

10.1021/ic00033a019 ◽

1992 ◽

Vol 31 (7) ◽

pp. 1224-1232 ◽

Cited By ~ 37

Author(s):

Pascual Lahuerta ◽

Jorge Paya ◽

Maria Angela Pellinghelli ◽

Antonio Tiripicchio

Keyword(s):

Molecular Structures ◽

Ortho Metalation

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ChemInform Abstract: Reductive Cleavage of Aryl O-Carbamates to Phenols by the Schwartz Reagent. Expedient Link to the Directed ortho Metalation Strategy.

ChemInform ◽

10.1002/chin.201401072 ◽

2013 ◽

Vol 45 (1) ◽

pp. no-no

Author(s):

Justin Morin ◽

Yigang Zhao ◽

Victor Snieckus

Keyword(s):

Reductive Cleavage ◽

Ortho Metalation ◽

Schwartz Reagent

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Diphosphine ligand chelation and bridging and regiospecific ortho metalation in the reaction of 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) with Ir4(CO)12: X-ray diffraction structures of Ir4(CO)7(μ-CO)3(bpcd), Ir4(CO)5(μ-CO)3(bpcd)(μ-bpcd), and HIr4(CO)4(μ-CO)3(bpcd)[μ-PhP(C6H4)CC(PPh2)C(O)CH2C(O)]

Journal of Organometallic Chemistry ◽

10.1016/j.jorganchem.2007.07.016 ◽

2008 ◽

Vol 693 (8-9) ◽

pp. 1439-1448 ◽

Cited By ~ 4

Author(s):

William H. Watson ◽

Guanmin Wu ◽

Michael G. Richmond

Keyword(s):

Diphosphine Ligand ◽

X Ray Diffraction ◽

X Ray ◽

Ortho Metalation

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ChemInform Abstract: Synthesis of an Ethyl 6-Amino-3,5-difluorosalicylate Derivative by Sequential Regioselective Directed ortho-Metalation: A Practical Synthesis of 4′,5-Diamino-3′,6,8-trifluoroflavone, a Potent Antitumor Agent.

ChemInform ◽

10.1002/chin.199815129 ◽

2010 ◽

Vol 29 (15) ◽

pp. no-no

Author(s):

T. AKAMA ◽

K. UENO ◽

H. SAITO ◽

M. KASAI

Keyword(s):

Antitumor Agent ◽

Ortho Metalation ◽

Practical Synthesis

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ortho-Metalation/chlorination of benzoic acid derivatives: preparation of [benzene-U-13C]-rac-clopidogrel ([benzene-U-13C]-rac-SR25990C)

Journal of Labelled Compounds and Radiopharmaceuticals ◽

10.1002/1099-1344(200008)43:9<891::aid-jlcr373>3.0.co;2-0 ◽

2000 ◽

Vol 43 (9) ◽

pp. 891-898 ◽

Cited By ~ 8

Author(s):

Alain Burgos ◽

John M. Herbert ◽

Iain Simpson

Keyword(s):

Benzoic Acid ◽

Benzoic Acid Derivatives ◽

Ortho Metalation

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The tert-BUTYL sulfoxide directed ortho metalation group. New synthetic methodology for substituted aromatics and pyridines and comparisons with others metalation directors

Tetrahedron Letters ◽

10.1016/s0040-4039(00)79042-3 ◽

1992 ◽

Vol 33 (19) ◽

pp. 2625-2628 ◽

Cited By ~ 45

Author(s):

C. Quesnelle ◽

T. Iihama ◽

T. Aubert ◽

H. Perrier ◽

V. Snieckus

Keyword(s):

Synthetic Methodology ◽

Tert Butyl ◽

Ortho Metalation

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Connections to the died ortho metalation strategy. Pd(0)-catalyzed cross coupling of aryl boronic acids with aryl triflatest

Tetrahedron Letters ◽

10.1016/s0040-4039(00)88848-6 ◽

1990 ◽

Vol 31 (12) ◽

pp. 1665-1668 ◽

Cited By ~ 83

Author(s):

J.-m. Fu ◽

V. Snieckus

Keyword(s):

Cross Coupling ◽

Boronic Acids ◽

Ortho Metalation

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