Ethanediylidenebis(isoquinolinedione): A Six-Membered-Ring Diimide Building Block for Ambipolar Semiconducting Polymers

2019 ◽  
Vol 52 (21) ◽  
pp. 8238-8247
Author(s):  
Jianyao Huang ◽  
Yuchai Pan ◽  
Zhihui Chen ◽  
Weifeng Zhang ◽  
Gui Yu
2014 ◽  
Vol 5 (10) ◽  
pp. 3753-3760 ◽  
Author(s):  
Masahito Murai ◽  
Sung-Yu Ku ◽  
Neil D. Treat ◽  
Maxwell J. Robb ◽  
Michael L. Chabinyc ◽  
...  

The properties of isomeric azulene derivatives, substituted through the 5-membered ring, were examined using a combination of experimentation and theoretical calculations for a series of well-defined electroactive oligomers.


2013 ◽  
Vol 52 (10) ◽  
pp. 6136-6141 ◽  
Author(s):  
Wenjiao Yao ◽  
Hongwei Huang ◽  
Jiyong Yao ◽  
Tao Xu ◽  
Xingxing Jiang ◽  
...  
Keyword(s):  

Molbank ◽  
10.3390/m1122 ◽  
2020 ◽  
Vol 2020 (2) ◽  
pp. M1122 ◽  
Author(s):  
Kristin Leyerer ◽  
Stefan Koppermann ◽  
Christian Ducho

Naturally occurring nucleoside-peptide antibiotics such as muraymycins or caprazamycins are of major interest for the development of novel antibacterial agents. However, the synthesis of new analogues of these natural products for structure–activity relationship (SAR) studies is challenging. In our synthetic efforts towards a muraymycin-derived nucleoside building block suitable for attachment to a solid support, we came across an interesting side product. This compound resulted from an undesired Fmoc deprotection with subsequent cyclization, thus furnishing a remarkable caprazamycin-like seven-membered diazepanone ring.


2011 ◽  
Vol 13 (2) ◽  
pp. 324-327 ◽  
Author(s):  
Qingdong Zheng ◽  
Shanci Chen ◽  
Bo Zhang ◽  
Lixin Wang ◽  
Changquan Tang ◽  
...  

2013 ◽  
Vol 9 ◽  
pp. 2544-2555 ◽  
Author(s):  
Bernd Schmidt ◽  
Oliver Kunz

Starting from the conveniently available ex-chiral pool building block (R,R)-hexa-1,5-diene-3,4-diol, the ten-membered ring lactones stagonolide E and curvulide A were synthesized using a bidirectional olefin-metathesis functionalization of the terminal double bonds. Key steps are (i) a site-selective cross metathesis, (ii) a highly diastereoselective extended tethered RCM to furnish a (Z,E)-configured dienyl carboxylic acid and (iii) a Ru–lipase-catalyzed dynamic kinetic resolution to establish the desired configuration at C9. Ring closure was accomplished by macrolactonization. Curvulide A was synthesized from stagonolide E through Sharpless epoxidation.


RSC Advances ◽  
2019 ◽  
Vol 9 (52) ◽  
pp. 30496-30502 ◽  
Author(s):  
Xiaocheng Zhou ◽  
Zhifang Zhang ◽  
Arthur D. Hendsbee ◽  
Jenner H. L. Ngai ◽  
Pankaj Kumar ◽  
...  

A new electron acceptor building block, [2,2′-bithiophene]-4,4′-dicarboxamide, is synthesized and used to develop donor polymers for organic solar cells.


2014 ◽  
Vol 15 (2) ◽  
pp. 024201 ◽  
Author(s):  
Itaru Osaka ◽  
Koki Komatsu ◽  
Tomoyuki Koganezawa ◽  
Kazuo Takimiya

2011 ◽  
Vol 33 (1) ◽  
pp. 9-20 ◽  
Author(s):  
Prakash Sista ◽  
Michael C. Biewer ◽  
Mihaela C. Stefan

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