Preparation of Supramolecular Ionic Liquid Gels Based on Host–Guest Interactions and Their Swelling and Ionic Conductive Properties

2019 ◽  
Vol 52 (8) ◽  
pp. 2932-2938 ◽  
Author(s):  
Garry Sinawang ◽  
Yuichiro Kobayashi ◽  
Yongtai Zheng ◽  
Yoshinori Takashima ◽  
Akira Harada ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Conductive Properties

Electro-conductive properties of poly(3,4-ethylenedioxythiophene)/poly(ionic liquid) films with respect to its structure and morphology

2009 ◽  
Vol 159 (23-24) ◽  
pp. 2453-2457 ◽  
Author(s):  
Tae Hee Lee ◽  
Tae Young Kim ◽  
Ha Thi Thuy Duong ◽  
Jong Eun Kim ◽  
Kwang S. Suh
Keyword(s):  
Ionic Liquid ◽  
Liquid Films ◽  
Structure And Morphology ◽  
Poly Ionic Liquid ◽  
Conductive Properties

scholarly journals Thermal, mechanical and conductive properties of imidazolium-containing thiol-ene poly(ionic liquid) networks

Polymer ◽  
2016 ◽  
Vol 100 ◽  
pp. 1-9 ◽  
Author(s):  
Taylor C. Rhoades ◽  
James C. Wistrom ◽  
R. Daniel Johnson ◽  
Kevin M. Miller
Keyword(s):  
Ionic Liquid ◽  
Poly Ionic Liquid ◽  
Conductive Properties

Mechanical, adhesive and self-healing ionic liquid hydrogels for electrolytes and flexible strain sensors

2020 ◽  
Vol 8 (32) ◽  
pp. 11119-11127 ◽  
Author(s):  
Zijian Gao ◽  
Lingshu Kong ◽  
Rining Jin ◽  
Xin Liu ◽  
Wei Hu ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Strain Sensors ◽  
Self Healing ◽  
Flexible Sensor ◽  
Conductive Properties

The prepared ionic liquid hydrogel was employed as flexible sensor and electrolyte with great mechanical, self-healing, adhesive and conductive properties.

Thermomechanical and Conductive Properties of Thiol–Ene Poly(ionic liquid) Networks Containing Backbone and Pendant Imidazolium Groups

2018 ◽  
Vol 57 (48) ◽  
pp. 16526-16536 ◽  
Author(s):  
Abigail F. Bratton ◽  
Sung-Soo Kim ◽  
Christopher J. Ellison ◽  
Kevin M. Miller
Keyword(s):  
Ionic Liquid ◽  
Poly Ionic Liquid ◽  
Conductive Properties

Facile fabrication of thermal-control ionic liquid compound based on undecatungstophosphoindic polyoxometalate with fast ionic conductivity

2016 ◽  
Vol 40 (9) ◽  
pp. 7923-7927 ◽  
Author(s):  
Xuefei Wu ◽  
Xuhua Zhou ◽  
Qingyin Wu ◽  
Wenfu Yan
Keyword(s):  
Activation Energy ◽  
Ionic Liquid ◽  
Phase Transformation ◽  
Ionic Conductivity ◽  
Layer Structure ◽  
Thermal Control ◽  
Facile Fabrication ◽  
Gel Phase ◽  
Conductive Properties ◽  
Reversible Phase

Thermal-depended conductive properties of the ternary-POM-based layer-structure ionic liquid [TOAMe]4[In(H2O)PW11O39] was investigated. It shows fast ionic conductivity as high as 2.2 × 10−3 S cm−1 at 90 °C with the conductive activation energy of 30.19 kJ mol−1, which is related to its state, obviously increasing during the reversible phase transformation from a quasi-solid-state gel phase to an isotropic sol phase.

Ion conductive properties in ionic liquid crystalline phases confined in a porous membrane

2015 ◽  
Vol 3 (24) ◽  
pp. 6144-6147 ◽  
Author(s):  
Y. Uchida ◽  
T. Matsumoto ◽  
T. Akita ◽  
N. Nishiyama
Keyword(s):  
Phase Transition ◽  
Ionic Liquid ◽  
Aluminum Oxide ◽  
Liquid Crystalline ◽  
Porous Membrane ◽  
Crystalline Phases ◽  
Liquid Crystalline Phases ◽  
Cylindrical Pores ◽  
Conductive Properties ◽  
Oxide Membranes

The anisotropic ion conductivity and phase transition behaviours of ionic liquid crystalline samples confined in aluminum oxide membranes with cylindrical pores were demonstrated.

scholarly journals Modification of Thiol-Ene Ionogels with Octakis(methacryloxypropyl) Silsesquioxane

Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 385
Author(s):  
Aneta Lewandowska ◽  
Piotr Gajewski ◽  
Katarzyna Szcześniak ◽  
Mariola Sadej ◽  
Piotr Patelski ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Ionic Liquid ◽  
Network Formation ◽  
Physical And Mechanical Properties ◽  
Imidazolium Ionic Liquid ◽  
Puncture Strength ◽  
Oligomeric Silsesquioxane ◽  
Conductive Properties ◽  
Kinetics Of

The effect of polyhedral oligomeric silsesquioxane (POSS) on the synthesis and properties of hybrid organic–inorganic ionogels was investigated using octakis(methacryloxypropyl) silsesquioxane (methacryl-POSS). Ionogels were prepared in situ by thiol-ene photopolymerization of triallyl isocyanurate with pentaerythritol tetrakis(3-mercaptopropionate) in a mixture of imidazolium ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMImNTf2) and propylene carbonate (PC). Investigations included the kinetics of hybrid materials formation and selected physical and mechanical properties. The disadvantage of ionogels without the methacryl-POSS modifier is leakage and insufficient mechanical properties. Modifying the thiol-ene matrix by the addition of methacryl-POSS made it possible to obtain non-leaking ionogels with improved mechanical and conductive properties. The steric hindrance of POSS cages and high-density network formation played important roles in ionogel synthesis: decrease of polymerization rate (with almost no effect on conversion), as well as dimensions of the formed polymer spheres during dispersion polymerization (highly cross-linked polymer has poorer solubility in polymerizing medium at a similar conversion, and nucleation begins at lower conversion), an increase of glass transition temperature and puncture strength. Hybrid ionogels with high ionic conductivity in the range of 4.0–5.1 mS∙cm−1 with the maximum parameter for 1.5 wt.% addition of the methacryl-POSS were obtained, which can be associated with ion-pair dissociations in ionic liquid clusters caused by methacryl-POSS.

scholarly journals Proton conductive ionic liquid crystalline poly(ethyleneimine) polymers functionalized with oxadiazole

RSC Advances ◽  
2018 ◽  
Vol 8 (66) ◽  
pp. 37700-37706 ◽  
Author(s):  
Alberto Concellón ◽  
Silvia Hernández-Ainsa ◽  
Joaquín Barberá ◽  
Pilar Romero ◽  
José Luis Serrano ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Liquid Crystal ◽  
Liquid Crystalline ◽  
Liquid Crystal Polymers ◽  
Conductive Properties

Two novel series of ionic liquid crystal polymers that display proton conductive properties are presented here.

scholarly journals Joint-Linker Type Ionic Gels Using Polymerizable Ionic Liquid as a Crosslinker via Thiol-Ene Click Reactions

Polymers ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 2844
Author(s):  
Kumkum Ahmed ◽  
Aoi Inagaki ◽  
Naofumi Naga
Keyword(s):  
Ionic Liquid ◽  
Ionic Conductivity ◽  
Solvent System ◽  
The Novel ◽  
Compression Tests ◽  
Click Reactions ◽  
Ene Reaction ◽  
Good Thermal Stability ◽  
Monomer Content ◽  
Conductive Properties

In this work, we report the synthesis of ion-conductive gels, or ionic gels, via thiol-ene click reactions. The novel gel systems consist of the multifunctional thiol monomers tris[(3-mercaptopropionyloxy)-ethyl]-isocyanurate (TEMPIC), pentaerythritol tetrakis(3-mercaptopropionate) (PEMP), and dipentaerythritol hexakis(3-mercaptopionate) (DPMP) as joint molecules and bifunctional allyl ionic liquid (IL) as a crosslinker. The thiol-ene reaction was carried out in lithium bis(trifluoromethanesulfonyl)imide (Li-TFSI) in a propylene carbonate (PC) (1 M) solvent system via a photopolymerization process. The chemical structure and mechanical, thermal, and conductive properties of the gels were investigated using Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), compression tests, and impedance spectroscopy, respectively. The mechanical and conductive properties of the ionic gels were found to be largely dependent on the monomer content and functionalities of the joint molecules. TGA revealed good thermal stability of the gels up to 100 °C. An ionic conductivity of 4.89 mS cm−1 was realized at room temperature (298 K) for low-functional thiol monomers, and a further increase in ionic conductivity was observed with an increase in Li+ ion content and temperature.

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