Efficient Thermally Activated Delayed Fluorescence Conjugated Polymeric Emitters with Tunable Nature of Excited States Regulated via Carbazole Derivatives for Solution-Processed OLEDs

2018 ◽  
Vol 51 (12) ◽  
pp. 4615-4623 ◽  
Author(s):  
Yuchao Liu ◽  
Yukun Wang ◽  
Chensen Li ◽  
Zhongjie Ren ◽  
Dongge Ma ◽  
...  
Keyword(s):  
Excited States ◽  
Delayed Fluorescence ◽  
Solution Processed ◽  
Thermally Activated Delayed Fluorescence ◽  
Carbazole Derivatives ◽  
Thermally Activated

Solvent Dependence of Structural Dynamics and Spin-flip Processes in 3,4,5-tri(9H-carbazole-9-yl)benzonitrile (ortho-3CzBN)

2020 ◽  
Author(s):  
Masaki Saigo ◽  
Kiyoshi Miyata ◽  
Hajime Nakanotani ◽  
Chihaya Adachi ◽  
Ken Onda
Keyword(s):  
Dft Calculations ◽  
Excited States ◽  
Structural Changes ◽  
Photophysical Properties ◽  
Delayed Fluorescence ◽  
Time Resolved ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Solvent Dependence ◽  
Acetonitrile Solutions

We have investigated the solvent-dependence of structural changes along with intersystem crossing of a thermally activated delayed fluorescence (TADF) molecule, 3,4,5-tri(9H-carbazole-9-yl)benzonitrile (o-3CzBN), in toluene, tetrahydrofuran, and acetonitrile solutions using time-resolved infrared (TR-IR) spectroscopy and DFT calculations. We found that the geometries of the S1 and T1 states are very similar in all solvents though the photophysical properties mostly depend on the solvent. In addition, the time-dependent DFT calculations based on these geometries suggested that the thermally activated delayed fluorescence process of o-3CzBN is governed more by the higher-lying excited states than by the structural changes in the excited states.<br>

New hole transport styrene polymers bearing highly π-extended conjugated side-chain moieties for high-performance solution-processable thermally activated delayed fluorescence OLEDs

2021 ◽  
Vol 12 (11) ◽  
pp. 1692-1699
Author(s):  
Ji Hye Lee ◽  
Jinhyo Hwang ◽  
Chai Won Kim ◽  
Amit Kumar Harit ◽  
Han Young Woo ◽  
...  
Keyword(s):  
High Performance ◽  
High Efficiency ◽  
Delayed Fluorescence ◽  
Hole Transport ◽  
Side Chain ◽  
Solution Processed ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Turn On ◽  
Solution Processable

New polystyrene-based polymers with high π-extended hole transport pendants were synthesized to obtain a low turn-on voltage and high efficiency in solution-processed green TADF-OLEDs.

scholarly journals Molecular design of efficient yellow- to red-emissive alkynylgold(iii) complexes for the realization of thermally activated delayed fluorescence (TADF) and their applications in solution-processed organic light-emitting devices

2021 ◽  
Author(s):  
Cathay Chai Au-Yeung ◽  
Lok-Kwan Li ◽  
Man-Chung Tang ◽  
Shiu-Lun Lai ◽  
Wai-Lung Cheung ◽  
...  
Keyword(s):  
Molecular Design ◽  
Delayed Fluorescence ◽  
Solution Processed ◽  
Thermally Activated Delayed Fluorescence ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Thermally Activated ◽  
New Class ◽  
Organic Light ◽  
Tunable Emission

We report the design of a new class of fused heterocyclic alkynyl ligand-containing gold(iii) complexes, which shows tunable emission colors spanning yellow to red region and exhibits thermally activated delayed fluorescence (TADF) properties.

scholarly journals Solution-Processed OLEDs Based on Thermally Activated Delayed Fluorescence Copper(I) Complexes with Intraligand Charge-Transfer Excited State

Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 1125
Author(s):  
Teng Teng ◽  
Jinfan Xiong ◽  
Gang Cheng ◽  
Changjiang Zhou ◽  
Xialei Lv ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Density Functional ◽  
Delayed Fluorescence ◽  
Quantum Yields ◽  
Functional Theory ◽  
Solution Processed ◽  
Thermally Activated Delayed Fluorescence ◽  
Light Emitting ◽  
Thermally Activated ◽  
Wide Range

A new series of tetrahedral heteroleptic copper(I) complexes exhibiting efficient thermally-activated delayed fluorescence (TADF) in green to orange electromagnetic spectral regions has been developed by using D-A type N^N ligand and P^P ligands. Their structures, electrochemical, photophysical, and electroluminescence properties have been characterized. The complexes exhibit high photoluminescence quantum yields (PLQYs) of up to 0.71 at room temperature in doped film and the lifetimes are in a wide range of 4.3–24.1 μs. Density functional theory (DFT) calculations on the complexes reveal the lowest-lying intraligand charge-transfer excited states that are localized on the N^N ligands. Solution-processed organic light emitting diodes (OLEDs) based on one of the new emitters show a maximum external quantum efficiency (EQE) of 7.96%.

Highly Luminescent Pincer Gold(III) Aryl Emitters: Thermally Activated Delayed Fluorescence and Solution-Processed OLEDs

2017 ◽  
Vol 56 (45) ◽  
pp. 14036-14041 ◽  
Author(s):  
Wai-Pong To ◽  
Dongling Zhou ◽  
Glenna So Ming Tong ◽  
Gang Cheng ◽  
Chen Yang ◽  
...  
Keyword(s):  
Delayed Fluorescence ◽  
Solution Processed ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated

Rotation-restricted thermally activated delayed fluorescence compounds for efficient solution-processed OLEDs with EQEs of up to 24.3% and small roll-off

2020 ◽  
Vol 56 (44) ◽  
pp. 5957-5960 ◽  
Author(s):  
Kuofei Li ◽  
Yunhui Zhu ◽  
Bing Yao ◽  
Yuannan Chen ◽  
Hao Deng ◽  
...  
Keyword(s):  
Efficient Solution ◽  
Delayed Fluorescence ◽  
Solution Processed ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated

A sandwich-like chromophore, composed of two donors and an inserted acceptor, is hitched onto a single carbazole to yield an efficient TADF emitter with excellent electroluminescent performance.

Asymmetric Sky-Blue Thermally Activated Delayed Fluorescence Emitters Bearing Tris(triazolo)triazine Moiety for Solution Processable Organic Light-Emitting Diodes

2022 ◽  
Author(s):  
Zhou Fang ◽  
Shengyue Wang ◽  
Junxu Liao ◽  
Xinrui Chen ◽  
Yuanyuan Zhu ◽  
...  
Keyword(s):  
Light Emitting Diodes ◽  
Delayed Fluorescence ◽  
Organic Light Emitting Diodes ◽  
Solution Processed ◽  
Thermally Activated Delayed Fluorescence ◽  
Light Emitting ◽  
Thermally Activated ◽  
Organic Light ◽  
Solution Processable

Efficient blue thermally activated delayed fluorescence (TADF) emitter is still a challenge in solution-processed organic light-emitting diodes (OLEDs). In this contribution, two asymmetric molecules of TTT-Ac and TTT-2Ac were synthesized...

Sign in / Sign up

Export Citation Format

Share Document