Photoinduced Iron-Catalyzed Atom Transfer Radical Polymerization with ppm Levels of Iron Catalyst under Blue Light Irradiation

2017 ◽  
Vol 50 (20) ◽  
pp. 7967-7977 ◽  
Author(s):  
Sajjad Dadashi-Silab ◽  
Xiangcheng Pan ◽  
Krzysztof Matyjaszewski
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Blue Light ◽  
Iron Catalyst ◽  
Light Irradiation ◽  
Atom Transfer

scholarly journals Synthesis of Polymer Bioconjugates via Photoinduced Atom Transfer Radical Polymerization under Blue Light Irradiation

2018 ◽  
Vol 7 (10) ◽  
pp. 1248-1253 ◽  
Author(s):  
Liye Fu ◽  
Zhenhua Wang ◽  
Sushil Lathwal ◽  
Alan E. Enciso ◽  
Antonina Simakova ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Blue Light ◽  
Light Irradiation ◽  
Atom Transfer ◽  
Polymer Bioconjugates

Photomediated atom transfer radical polymerization of MMA under long-wavelength light irradiation

2018 ◽  
Vol 27 (11) ◽  
pp. 881-887 ◽  
Author(s):  
Le-Lin Zeng ◽  
Wan-Yun Xie ◽  
Cai-Xia Yang ◽  
Enxiang Liang ◽  
Guo-Xiang Wang
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Light Irradiation ◽  
Atom Transfer ◽  
Long Wavelength ◽  
Wavelength Light

scholarly journals Development of Environmentally Friendly Atom Transfer Radical Polymerization

Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 1987
Author(s):  
Ming Yuan ◽  
Xuetao Cui ◽  
Wenxian Zhu ◽  
Huadong Tang
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Iron Catalyst ◽  
Iron Complex ◽  
Point Of View ◽  
Research Progress ◽  
Atom Transfer ◽  
Complex Catalyst ◽  
Environmental Friendliness ◽  
Metal Free

Atom transfer radical polymerization (ATRP) is one of the most successful techniques for the preparation of well-defined polymers with controllable molecular weights, narrow molecular weight distributions, specific macromolecular architectures, and precisely designed functionalities. ATRP usually involves transition-metal complex as catalyst. As the most commonly used copper complex catalyst is usually biologically toxic and environmentally unsafe, considerable interest has been focused on iron complex, enzyme, and metal-free catalysts owing to their low toxicity, inexpensive cost, commercial availability and environmental friendliness. This review aims to provide a comprehensive understanding of iron catalyst used in normal, reverse, AGET, ICAR, GAMA, and SARA ATRP, enzyme as well as metal-free catalyst mediated ATRP in the point of view of catalytic activity, initiation efficiency, and polymerization controllability. The principle of ATRP and the development of iron ligand are briefly discussed. The recent development of enzyme-mediated ATRP, the latest research progress on metal-free ATRP, and the application of metal-free ATRP in interdisciplinary areas are highlighted in sections. The prospects and challenges of these three ATRP techniques are also described in the review.

A covalent organic framework as a photocatalyst for atom transfer radical polymerization under white light irradiation

2021 ◽  
Author(s):  
Zhen Lu ◽  
Xiaoling Fu ◽  
Hongjie Yang ◽  
Yulai Zhao ◽  
Longqiang Xiao ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
White Light ◽  
Light Irradiation ◽  
Atom Transfer ◽  
Co Catalyst ◽  
Covalent Organic Framework ◽  
Organic Framework

TFPPy-Td-COFs have been synthesized to serve as heterogeneous photocatalysts for mediating photo-induced ATRP with copper as a co-catalyst under white light irradiation.

An atom transfer radical polymerization system: catalyzed by an iron catalyst in PEG-400

2015 ◽  
Vol 17 (1) ◽  
pp. 271-278 ◽  
Author(s):  
Mingqiang Ding ◽  
Xiaowu Jiang ◽  
Jinying Peng ◽  
Lifen Zhang ◽  
Zhenping Cheng ◽  
...  
Keyword(s):  
Polyethylene Glycol ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Iron Catalyst ◽  
Atom Transfer ◽  
Polyethylene Glycol 400 ◽  
Aget Atrp ◽  
Peg 400 ◽  
Highly Efficient ◽  
Polymerization System

A robust and highly efficient iron catalyzed AGET ATRP of MMA in non-toxic polyethylene glycol 400 (PEG-400) without any additional ligands was successfully conducted.

Redox Responsive Behavior of Thiol/Disulfide-Functionalized Star Polymers Synthesized via Atom Transfer Radical Polymerization

2010 ◽  
Vol 43 (9) ◽  
pp. 4133-4139 ◽  
Author(s):  
Jun Kamada ◽  
Kaloian Koynov ◽  
Cathrin Corten ◽  
Azhar Juhari ◽  
Jeong Ae Yoon ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Star Polymers ◽  
Atom Transfer ◽  
Redox Responsive ◽  
Responsive Behavior
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