Radical Generation and Termination in SARA ATRP of Methyl Acrylate: Effect of Solvent, Ligand, and Chain Length

2016 ◽  
Vol 49 (8) ◽  
pp. 2977-2984 ◽  
Author(s):  
Pawel Krys ◽  
Yu Wang ◽  
Krzysztof Matyjaszewski ◽  
Simon Harrisson
Keyword(s):  
Chain Length ◽  
Methyl Acrylate ◽  
Effect Of Solvent ◽  
Radical Generation

Access to Chain Length Dependent Termination Rate Coefficients of Methyl Acrylate via Reversible Addition−Fragmentation Chain Transfer Polymerization

2005 ◽  
Vol 38 (7) ◽  
pp. 2595-2605 ◽  
Author(s):  
Alexander Theis ◽  
Achim Feldermann ◽  
Nathalie Charton ◽  
Martina H. Stenzel ◽  
Thomas P. Davis ◽  
...  
Keyword(s):  
Chain Length ◽  
Methyl Acrylate ◽  
Chain Transfer ◽  
Rate Coefficients ◽  
Termination Rate ◽  
Reversible Addition ◽  
Chain Transfer Polymerization

How Well Can Theory Predict Addition - Fragmentation Equilibrium Constants in RAFT Polymerization?

2009 ◽  
Vol 62 (11) ◽  
pp. 1479 ◽  
Author(s):  
Ching Yeh Lin ◽  
Michelle L. Coote
Keyword(s):  
Ab Initio ◽  
Chain Length ◽  
Methyl Acrylate ◽  
Raft Polymerization ◽  
Equilibrium Constants ◽  
Molecular Orbital Calculations ◽  
Related System ◽  
Order Of Magnitude ◽  
Good Order ◽  
High Level

High level ab initio molecular orbital calculations are used to study the addition–fragmentation equilibrium constants of S-S’-bis(methyl-2-propionate)-trithiocarbonate mediated polymerization of methyl acrylate in toluene at –30°C. The results, which show strong solvent and chain length effects, are in good order of magnitude agreement with recent experimental results for a closely related system.

Synthesis and Characterization of Methyl Acrylate-Copolymerized Medium-Chain-Length Poly-3-hydroxyalkanoates

2021 ◽  
Author(s):  
S. M. Daniel Syed Mohamed ◽  
Khairul Anwar Ishak ◽  
Mohamad Suffian Mohamad Annuar ◽  
Thamil Selvi Velayutham
Keyword(s):  
Chain Length ◽  
Methyl Acrylate ◽  
Synthesis And Characterization ◽  
Medium Chain ◽  
Medium Chain Length

Mapping Chain Length and Conversion Dependent Termination Rate Coefficients in Methyl Acrylate Free Radical Polymerization

2005 ◽  
Vol 38 (24) ◽  
pp. 10323-10327 ◽  
Author(s):  
Alexander Theis ◽  
Thomas P. Davis ◽  
Martina H. Stenzel ◽  
Christopher Barner-Kowollik
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Chain Length ◽  
Methyl Acrylate ◽  
Free Radical Polymerization ◽  
Rate Coefficients ◽  
Termination Rate

Satiation in humans is modulated by fatty acid chain length

2001 ◽  
Vol 120 (5) ◽  
pp. A710-A710
Author(s):  
S LAL ◽  
J MCLAUGHLIN ◽  
O NIAZ ◽  
G DOCKRAY ◽  
A VARRO ◽  
...  
Keyword(s):  
Fatty Acid ◽  
Chain Length ◽  
Fatty Acid Chain Length ◽  
Fatty Acid Chain

Effect of Solvent Quality on the Behaviour of Highly Charged Polyelectrolytes

1995 ◽  
Vol 5 (9) ◽  
pp. 1269-1275 ◽  
Author(s):  
W. Essafi ◽  
F. Lafuma ◽  
C. E. Williams
Keyword(s):  
Effect Of Solvent ◽  
Solvent Quality
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