Dramatic Tunability of the Glass Transition Temperature and Fragility of Low Molecular Weight Polystyrene by Initiator Fragments Located at Chain Ends

Lanhe Zhang; John A. Marsiglio; Tian Lan; John M. Torkelson

doi:10.1021/acs.macromol.5b02704

Dramatic Tunability of the Glass Transition Temperature and Fragility of Low Molecular Weight Polystyrene by Initiator Fragments Located at Chain Ends

Macromolecules ◽

10.1021/acs.macromol.5b02704 ◽

2016 ◽

Vol 49 (6) ◽

pp. 2387-2398 ◽

Cited By ~ 22

Author(s):

Lanhe Zhang ◽

John A. Marsiglio ◽

Tian Lan ◽

John M. Torkelson

Keyword(s):

Molecular Weight ◽

Glass Transition ◽

Transition Temperature ◽

Glass Transition Temperature ◽

Low Molecular Weight

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Enhanced glass transition temperature of low molecular weight poly(methyl methacrylate) by initiator fragments located at chain ends

Polymer ◽

10.1016/j.polymer.2017.06.054 ◽

2017 ◽

Vol 122 ◽

pp. 194-199 ◽

Cited By ~ 6

Author(s):

Lanhe Zhang ◽

John M. Torkelson

Keyword(s):

Molecular Weight ◽

Glass Transition ◽

Transition Temperature ◽

Glass Transition Temperature ◽

Methyl Methacrylate ◽

Low Molecular Weight ◽

Poly Methyl Methacrylate

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Dynamic Mechanical Relaxation Behavior of Low Molecular Weight Side-Chain Cyclic Liquid Crystalline Compounds near the Glass Transition Temperature

Macromolecules ◽

10.1021/ma951773o ◽

1996 ◽

Vol 29 (17) ◽

pp. 5650-5657 ◽

Cited By ~ 7

Author(s):

Michael E. De Rosa ◽

W. Wade Adams ◽

Timothy J. Bunning ◽

Hongqin Shi ◽

Shaw H. Chen

Keyword(s):

Molecular Weight ◽

Glass Transition ◽

Transition Temperature ◽

Glass Transition Temperature ◽

Liquid Crystalline ◽

Relaxation Behavior ◽

Side Chain ◽

Mechanical Relaxation ◽

Low Molecular Weight ◽

Dynamic Mechanical

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Prediction of the glass transition temperature of low molecular weight components and polysaccharide mixtures

Journal of Food Engineering ◽

10.1016/j.jfoodeng.2020.110345 ◽

2021 ◽

Vol 292 ◽

pp. 110345

Author(s):

Sebastian Linnenkugel ◽

Anthony H.J. Paterson ◽

Lee M. Huffman ◽

John E. Bronlund

Keyword(s):

Molecular Weight ◽

Glass Transition ◽

Transition Temperature ◽

Glass Transition Temperature ◽

Low Molecular Weight

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Glass transition temperature of low molecular weight poly(3-aminopropyl methyl siloxane). A molecular dynamics study

Polymer ◽

10.1016/s0032-3861(02)00442-1 ◽

2002 ◽

Vol 43 (22) ◽

pp. 6049-6055 ◽

Cited By ~ 22

Author(s):

Javier Pozuelo ◽

Juan Baselga

Keyword(s):

Molecular Dynamics ◽

Molecular Weight ◽

Glass Transition ◽

Transition Temperature ◽

Glass Transition Temperature ◽

Low Molecular Weight

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Glass transition temperature of low molecular weight styrene–isoprene block copolymers

Journal of Polymer Science Polymer Chemistry Edition ◽

10.1002/pol.1976.170140913 ◽

1976 ◽

Vol 14 (9) ◽

pp. 2233-2242 ◽

Cited By ~ 18

Author(s):

P. M. Toporowski ◽

J. E. L. Roovers

Keyword(s):

Molecular Weight ◽

Glass Transition ◽

Transition Temperature ◽

Glass Transition Temperature ◽

Block Copolymers ◽

Low Molecular Weight

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Methacrylate-based polymer films useful in lithographic applications exhibit different glass transition temperature-confinement effects at high and low molecular weight

Polymer ◽

10.1016/j.polymer.2014.01.031 ◽

2014 ◽

Vol 55 (5) ◽

pp. 1249-1258 ◽

Cited By ~ 36

Author(s):

Tian Lan ◽

John M. Torkelson

Keyword(s):

Molecular Weight ◽

Glass Transition ◽

Transition Temperature ◽

Glass Transition Temperature ◽

Polymer Films ◽

Low Molecular Weight ◽

Confinement Effects

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Excess heat capacity for low-molecular-weight amorphous polystyrene below the glass-transition temperature: influence of end groups

Polymer Journal ◽

10.1038/s41428-020-0310-4 ◽

2020 ◽

Vol 52 (6) ◽

pp. 575-580 ◽

Cited By ~ 2

Author(s):

Marika Yokota ◽

Eri Nishiyama ◽

Jun Fujimura ◽

Itaru Tsukushi

Keyword(s):

Molecular Weight ◽

Heat Capacity ◽

Glass Transition ◽

Transition Temperature ◽

Glass Transition Temperature ◽

Excess Heat Capacity ◽

Low Molecular Weight ◽

Temperature Influence ◽

Excess Heat ◽

End Groups

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End unit effect on the glass transition temperature of low-molecular-weight polymers and copolymers

Polymer ◽

10.1016/0032-3861(93)90054-e ◽

1993 ◽

Vol 34 (17) ◽

pp. 3687-3693 ◽

Cited By ~ 43

Author(s):

F Danusso ◽

M Levi ◽

G Gianotti ◽

S Turri

Keyword(s):

Molecular Weight ◽

Glass Transition ◽

Transition Temperature ◽

Glass Transition Temperature ◽

Low Molecular Weight

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Mechanical dispersions of polar polymers sensitive to the presence of low molecular weight substances below the glass transition temperature: The influence of the side-chain length and the end hydroxyl group of swollen poly(methacrylic acid) esters

Journal of Polymer Science Part C Polymer Symposia ◽

10.1002/polc.5070230145 ◽

2007 ◽

Vol 23 (1) ◽

pp. 373-383 ◽

Cited By ~ 2

Author(s):

Josef Janáček

Keyword(s):

Molecular Weight ◽

Glass Transition ◽

Transition Temperature ◽

Glass Transition Temperature ◽

Methacrylic Acid ◽

Hydroxyl Group ◽

Side Chain ◽

Low Molecular Weight ◽

Polar Polymers ◽

Acid Esters

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Molecular Weight Dependence of the Glass Transition Temperature (Tg)-Confinement Effect in Well-Dispersed Poly(2-vinyl pyridine)–Silica Nanocomposites: Comparison of Interfacial Layer Tg and Matrix Tg

Macromolecules ◽

10.1021/acs.macromol.0c01577 ◽

2020 ◽

Vol 53 (19) ◽

pp. 8725-8736

Author(s):

Tong Wei ◽

John M. Torkelson

Keyword(s):

Molecular Weight ◽

Glass Transition ◽

Transition Temperature ◽

Glass Transition Temperature ◽

Interfacial Layer ◽

Confinement Effect ◽

Silica Nanocomposites ◽

Molecular Weight Dependence ◽

Vinyl Pyridine

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