Random Copolymers from Polyamide 11 and Polyamide 12 by Reactive Extrusion: Synthesis, Eutectic Phase Behavior, and Polymorphism

2016 ◽  
Vol 49 (3) ◽  
pp. 876-890 ◽  
Author(s):  
Lien Telen ◽  
Peter Van Puyvelde ◽  
Bart Goderis
Polymers ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 81
Author(s):  
Francesco Sillani ◽  
Ramis Schiegg ◽  
Manfred Schmid ◽  
Eric MacDonald ◽  
Konrad Wegener

Powder bed fusion of polymers is becoming increasingly adopted by a variety of industries to tailor the strength, weight and functionality of end-use products. To meet the high standards of the modern manufacturing industry, parts built with powder bed fusion require consistent properties and to be free of defects, which is intrinsically connected to the quality of the powder bed prior to melting. The hypothesis of this work is that the roughness of the top surface of an unmelted powder bed can serve as a proxy for the powder bed density, which is known to correlate with final part density. In this study, a laser line scan profilometer is integrated onto the recoater arm of a custom powder test bench, which is able to automatically create layers of powder. A diverse group of polymers was investigated including polyamide 12 (PA12), polyamide 11 (PA11), polypropylene (PP), and a thermoplastic elastomer (TPU) under different recoating speed in order to increase the variance of the dataset. Data analytics were employed to compare roughness to measured powder bed density and a statically significant correlation was established between them.


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