Replacing Alkyl with Oligo(ethylene glycol) as Side Chains of Conjugated Polymers for Close π–π Stacking

2015 ◽  
Vol 48 (13) ◽  
pp. 4357-4363 ◽  
Author(s):  
Bin Meng ◽  
Haiyang Song ◽  
Xingxing Chen ◽  
Zhiyuan Xie ◽  
Jun Liu ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Conjugated Polymers ◽  
Side Chains ◽  
Π Stacking

Titelbild: Diketopyrrolopyrrole-based Conjugated Polymers Bearing Branched Oligo(Ethylene Glycol) Side Chains for Photovoltaic Devices (Angew. Chem. 35/2016)

2016 ◽  
Vol 128 (35) ◽  
pp. 10307-10307
Author(s):  
Xingxing Chen ◽  
Zijian Zhang ◽  
Zicheng Ding ◽  
Jun Liu ◽  
Lixiang Wang
Keyword(s):  
Ethylene Glycol ◽  
Conjugated Polymers ◽  
Side Chains ◽  
Photovoltaic Devices

Diketopyrrolopyrrole-based Conjugated Polymers Bearing Branched Oligo(Ethylene Glycol) Side Chains for Photovoltaic Devices

2016 ◽  
Vol 128 (35) ◽  
pp. 10532-10536 ◽  
Author(s):  
Xingxing Chen ◽  
Zijian Zhang ◽  
Zicheng Ding ◽  
Jun Liu ◽  
Lixiang Wang
Keyword(s):  
Ethylene Glycol ◽  
Conjugated Polymers ◽  
Side Chains ◽  
Photovoltaic Devices

Diketopyrrolopyrrole-based Conjugated Polymers Bearing Branched Oligo(Ethylene Glycol) Side Chains for Photovoltaic Devices

2016 ◽  
Vol 55 (35) ◽  
pp. 10376-10380 ◽  
Author(s):  
Xingxing Chen ◽  
Zijian Zhang ◽  
Zicheng Ding ◽  
Jun Liu ◽  
Lixiang Wang
Keyword(s):  
Ethylene Glycol ◽  
Conjugated Polymers ◽  
Side Chains ◽  
Photovoltaic Devices

Oligo(ethylene glycol) as side chains of conjugated polymers for optoelectronic applications

2020 ◽  
Vol 11 (7) ◽  
pp. 1261-1270 ◽  
Author(s):  
Bin Meng ◽  
Jun Liu ◽  
Lixiang Wang
Keyword(s):  
Ethylene Glycol ◽  
Conjugated Polymers ◽  
Electronic Device ◽  
Device Performance ◽  
Side Chains ◽  
Alkyl Side Chains ◽  
Optoelectronic Applications

Except hydrophobic alkyl side chains, hydrophilic oligo(ethylene glycol) (OEG) has also been used as side chains of conjugated polymers and endow the resulting polymers with interesting properties and excellent opto-electronic device performance.

Aqueous-Alcohol-Processable High-Mobility Semiconducting Copolymers with Engineered Oligo(ethylene glycol) Side Chains

2019 ◽  
Vol 32 (3) ◽  
pp. 1111-1119 ◽  
Author(s):  
Boseok Kang ◽  
Ziang Wu ◽  
Min Je Kim ◽  
Han Young Woo ◽  
Jeong Ho Cho
Keyword(s):  
Ethylene Glycol ◽  
High Mobility ◽  
Side Chains ◽  
Aqueous Alcohol

Theoretical study of charge-transport and optical properties of indeno[1,2-b]fluorene-6,12-dione-based semiconducting materials

2018 ◽  
Vol 74 (6) ◽  
pp. 705-711 ◽  
Author(s):  
Jin-Dou Huang ◽  
Jinfeng Zhao ◽  
Kun Yu ◽  
Xiaohua Huang ◽  
Shi-Bo Cheng ◽  
...  
Keyword(s):  
Optical Properties ◽  
Charge Transport ◽  
Near Infrared ◽  
Reorganization Energy ◽  
Hole Mobility ◽  
Side Chains ◽  
Semiconducting Materials ◽  
Π Stacking ◽  
Electron Transfer Theory ◽  
Reorganization Energies

The conducting and optical properties of a series of indeno[1,2-b]fluorene-6,12-dione (IFD)-based molecules have been systematically studied and the influences of butyl, butylthio and dibutylamino substituents on the reorganization energies, intermolecular electronic couplings and charge-injection barriers of IFD have been discussed. The quantum-chemical calculations combined with electron-transfer theory reveal that the incorporation of sulfur-linked side chains decreases reorganization energy associated with hole transfer and optimizes intermolecular π–π stacking, which results in excellent ambipolar charge-transport properties (μh = 1.15 cm2 V−1 s−1 and μe = 0.08 cm2 V−1 s−1); in comparison, addition of dibutylamino side chains increases intermolecular steric interactions and hinders perfect intermolecular π–π stacking, which results in the weak electronic couplings and finally causes the low intrinsic hole mobility (μh = 0.01 cm2 V−1 s−1). Furthermore, electronic spectra of butyl-IFD, butylthio-IFD and dibutylamino-IFD were simulated and compared with the reported experimental data. Calculations demonstrate that IFD-based molecules possess potential for developing novel infrared and near-infrared probe materials via suitable chemical modifications.

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