Bis(trithiocarbonate) Disulfides: From Chain Transfer Agent Precursors to Iniferter Control Agents in RAFT Polymerization

2021 ◽  
Author(s):  
Andrew Kerr ◽  
Guillaume Moriceau ◽  
Magdalena A. Przybyla ◽  
Timothy Smith ◽  
Sébastien Perrier
Keyword(s):  
Chain Transfer ◽  
Raft Polymerization ◽  
Chain Transfer Agent

A surfactant-free emulsion RAFT polymerization of methyl methacrylate in a continuous tubular reactor

2015 ◽  
Vol 6 (11) ◽  
pp. 1937-1943 ◽  
Author(s):  
Zhen Li ◽  
Weijie Chen ◽  
Zhengbiao Zhang ◽  
Lifen Zhang ◽  
Zhenping Cheng ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Chain Transfer ◽  
Mixed Solvent ◽  
Raft Polymerization ◽  
Tubular Reactor ◽  
Chain Transfer Agent ◽  
Dimethyl Formamide

A surfactant-free emulsion RAFT polymerization of methyl methacrylate was successfully conducted in a continuous tubular reactor with a mixed solvent of water and dimethyl formamide in the presence of air, using CTBCOOH as the chain transfer agent and emulsion stabilizer.

Initiator-chain transfer agent combo in the RAFT polymerization of styrene

2014 ◽  
Vol 50 (68) ◽  
pp. 9722-9724 ◽  
Author(s):  
Ying Wu ◽  
Wei Zhang ◽  
Zhengbiao Zhang ◽  
Xiangqiang Pan ◽  
Zhenping Cheng ◽  
...  
Keyword(s):  
Chain Transfer ◽  
Raft Polymerization ◽  
Chain Transfer Agent ◽  
Vinyl Monomers

A novel initiator-chain transfer agent combo was synthesized and applied in the homopolymerization of different vinyl monomers as well as copolymerization.

RAFT polymerization of N,N-diethylacrylamide: Influence of chain transfer agent and solvent on kinetics and induction period

Polymer ◽  
2010 ◽  
Vol 51 (14) ◽  
pp. 2947-2953 ◽  
Author(s):  
Xuewei Zhang ◽  
Olivia Giani ◽  
Sophie Monge ◽  
Jean-Jacques Robin
Keyword(s):  
Induction Period ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Chain Transfer Agent

Investigation into the mechanism of photo-mediated RAFT polymerization involving the reversible photolysis of the chain-transfer agent

2017 ◽  
Vol 8 (11) ◽  
pp. 1760-1770 ◽  
Author(s):  
Benjamin Cabannes-Boué ◽  
Qizhi Yang ◽  
Jacques Lalevée ◽  
Fabrice Morlet-Savary ◽  
Julien Poly
Keyword(s):  
Chain Transfer ◽  
Raft Polymerization ◽  
Chain Transfer Agent ◽  
Polymerization Mechanism ◽  
A Chain

A new dithiocarbamate with a N-carbazole Z group is synthesized and investigated as a chain-transfer agent (CTA) in a photo-mediated RAFT polymerization mechanism involving its partial and reversible photolysis.

Syntheses of 2-(trifluoromethyl)acrylate-containing block copolymers via RAFT polymerization using a universal chain transfer agent

2018 ◽  
Vol 9 (25) ◽  
pp. 3511-3521 ◽  
Author(s):  
Sanjib Banerjee ◽  
Marc Guerre ◽  
Bruno Améduri ◽  
Vincent Ladmiral
Keyword(s):  
Block Copolymers ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Chain Transfer Agent

2-(Trifluoromethyl)acrylate-containing block copolymers were synthesized via RAFT polymerization using a universal CTA.

RAFT Polymerization of 2,2,3,3-Tetrafluoropropyl Methacrylate in the Presence of Lewis Acids

2021 ◽  
Vol 899 ◽  
pp. 525-531
Author(s):  
Oleg A. Lebedev ◽  
Alexandra O. Grigoreva ◽  
Sergey D. Zaitsev
Keyword(s):  
Polymer Chain ◽  
Lewis Acids ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Point Of View ◽  
Chain Transfer Agent ◽  
Reversible Addition

The influence of various tacticity regulators on the reversible addition-fragmentation (RAFT) polymerization of 2,2,3,3-tetrafluoropropyl methacrylate in the presence of 2-cyano-2-propyldodecyltritiocarbonate as an chain transfer agent was investigated. Among Lewis acids considered, the polymerization of TFPMA in dioxane with ZnBr2 turned out to be the most effective from the point of view of tacticity; the polymer with the highest isotacticity is formed. The addition of hexafluoroisopropanol leads to an increase in the heterotacticity and a decrease in the isotacticity of the polymer chain.

Synthesis and Investigation of pH-Switchable RAFT Agent in Polymerization of Styrene

2021 ◽  
Vol 899 ◽  
pp. 638-643
Author(s):  
Artem Vlasov ◽  
Alexandra O. Grigoreva ◽  
Sergey D. Zaitsev
Keyword(s):  
Mass Distribution ◽  
Molar Mass ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Chain Transfer Agent ◽  
Molar Mass Distribution ◽  
Reversible Addition ◽  
Raft Agent ◽  
Kinetic Features

pH-switchable chain transfer agent 1-cyano-1-methylethyl (phenyl)(pyridin-4-yl)-carbamodithioate (CMPC) was synthesized and reversible addition-fragmentation chain-transfer (RAFT) polymerization of styrene in presence of CMPC was studied. It was shown that presence of CMPC affects molar mass distribution and kinetic features and realizes supposed mechanism of RAFT polymerization. Different effect of CMPC on polymerization of styrene in presence of protic acids was studied.

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