Organic–Inorganic Polycyclooctadienes with Double-Decker Silsesquioxanes in the Main Chains: Synthesis, Self-Healing, and Shape Memory Properties Regulated with Quadruple Hydrogen Bonds

2020 ◽  
Vol 53 (16) ◽  
pp. 7119-7131
Author(s):  
Bingjie Zhao ◽  
Honggang Mei ◽  
Ning Liu ◽  
Sixun Zheng
2021 ◽  
pp. 110838
Author(s):  
Liyuan Qiao ◽  
Chengde Liu ◽  
Cheng Liu ◽  
Lishuai Zong ◽  
Hongjian Gu ◽  
...  

2020 ◽  
Vol 2 (8) ◽  
pp. 3327-3338
Author(s):  
Sen Xu ◽  
Bingjie Zhao ◽  
Mohsin Raza ◽  
Lei Li ◽  
Huaming Wang ◽  
...  

2021 ◽  
Vol 45 (1) ◽  
pp. 314-320
Author(s):  
Yuewen Chen ◽  
Shengping Dai ◽  
Hao Zhu ◽  
Hongwei Hu ◽  
Ningyi Yuan ◽  
...  

Shape memory hydrogels offer new opportunities for the development of smart wearables due to their intelligent responsiveness.


Author(s):  
Jianfeng Ban ◽  
Linjiang Zhu ◽  
Shaojun Chen ◽  
Yiping Wang

To better understand the shape memory materials and self-healing materials, a new series of liquid-crystalline shape memory polyurethane (LC-SMPU) composites, named SMPU-OOBAm, were successfully prepared by incorporating 4-octyldecyloxybenzoic acid (OOBA) into the PEG-based SMPU. The effect of OOBA on the structure, morphology and properties has been carefully investigated. The results demonstrate that SMPU-OOBAm have liquid crystalline properties, triple-shape memory properties and self-healing properties. The incorporated OOBA promotes the crystallizability of both soft and hard segments of SMPU, and the crystallization rate of the hard segment of SMPU decreases when the OOBA-content increases. Additionally, the SMPU-OOBAm forms a two-phase separated structure (SMPU phase and OOBA phase), and it shows two-step modulus changes upon heating. Therefore, the SMPU-OOBAm shows triple-shape memory behavior, and the shape recovery ratio decreases with an increase in the OOBA content. Finally, SMPU-OOBAm shows self-healing properties. The new mechanism can be ascribed to the heating-induced “bleeding” of OOBA in the liquid crystalline state and the subsequent re-crystallization upon cooling. This successful combination of liquid crystalline properties, triple-shape memory properties and self-healing properties make the SMPU-OOBAm composites with many promise applications in smart optical devices, smart electronic devices and smart sensors.


2015 ◽  
Vol 3 (6) ◽  
pp. 2924-2933 ◽  
Author(s):  
Shaojun Chen ◽  
Funian Mo ◽  
Yan Yang ◽  
Florian J. Stadler ◽  
Shiguo Chen ◽  
...  

Novel zwitterionic polyurethanes containing sulfobetaines, featuring excellent multi-shape-memory properties and self-healing properties, are prepared from N-methyldiethanolamine, hexamethylene diisocyanate and 1,3-propanesultone.


Soft Matter ◽  
2019 ◽  
Vol 15 (30) ◽  
pp. 6171-6179 ◽  
Author(s):  
Yukai Lv ◽  
Zheng Pan ◽  
Cunzheng Song ◽  
Yulong Chen ◽  
Xin Qian

Double-network hydrogels based on two natural polysaccharide polymers, locust bean gum and gellan gum, have been fabricated and exhibited excellent self-healing, thermo-processability, and pH-driven shape memory properties.


2015 ◽  
Vol 127 (31) ◽  
pp. 9112-9115 ◽  
Author(s):  
Kohei Miyamae ◽  
Masaki Nakahata ◽  
Yoshinori Takashima ◽  
Akira Harada

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