Optimization of Thermoelectric Properties of Polymers by Incorporating Oligoethylene Glycol Side Chains and Sequential Solution Doping with Preannealing Treatment

2020 ◽  
Vol 53 (16) ◽  
pp. 7063-7072
Author(s):  
Ayushi Tripathi ◽  
Youngjun Ko ◽  
Miso Kim ◽  
Yeran Lee ◽  
Soonyong Lee ◽  
...  
Keyword(s):  
Thermoelectric Properties ◽  
Side Chains ◽  
Sequential Solution ◽  
Oligoethylene Glycol ◽  
Solution Doping

A study of the thermoelectric properties of benzo[1,2-b:4,5-b′]dithiophene–based donor–acceptor conjugated polymers

2018 ◽  
Vol 9 (35) ◽  
pp. 4440-4447 ◽  
Author(s):  
Luhai Wang ◽  
Chengjun Pan ◽  
Zhongming Chen ◽  
Xiaoyan Zhou ◽  
Chunmei Gao ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Thermoelectric Properties ◽  
Thermoelectric Materials ◽  
Side Chains ◽  
Organic Thermoelectric Materials ◽  
Donor Acceptor

Three benzo[1,2-b:4,5-b′]dithiophene (BDT)-based donor–acceptor (D–A) conjugated polymers with different side chains were designed, synthesized, and investigated as organic thermoelectric materials.

Simple furan-based polymers featuring self-healing function enable efficient eco-friendly organic solar cells with high stability

2021 ◽  
Author(s):  
Shangwen Lu ◽  
Shengchun Qu ◽  
Yingying Deng ◽  
Yueyue Gao ◽  
Gentian Yue ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Solar Cells ◽  
Organic Solar Cells ◽  
High Stability ◽  
Hole Mobility ◽  
Side Chains ◽  
Self Healing ◽  
Good Solubility ◽  
Large Dielectric Constant ◽  
Oligoethylene Glycol

Herein, two simple furan-based polymers PFO3 and PFO4 grafting oligoethylene glycol (OEG) side chains are developed. PFO3 and PFO4 feature high hole mobility, large dielectric constant and good solubility. Compared...

scholarly journals Conjugated Polymers with Oligoethylene Glycol Side Chains for Improved Photocatalytic Hydrogen Evolution

iScience ◽  
2019 ◽  
Vol 13 ◽  
pp. 33-42 ◽  
Author(s):  
Zhicheng Hu ◽  
Zhenfeng Wang ◽  
Xi Zhang ◽  
Haoran Tang ◽  
Xiaocheng Liu ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Hydrogen Evolution ◽  
Side Chains ◽  
Photocatalytic Hydrogen Evolution ◽  
Oligoethylene Glycol

Antibacterial and hemolytic properties of acrylate-based random ternary copolymers comprised of same center cationic, ethyl and poly(oligoethylene glycol) side chains

2020 ◽  
Vol 132 ◽  
pp. 109757 ◽  
Author(s):  
Jeremiah Brittin ◽  
Michelle R. Fry ◽  
Ashish Punia ◽  
Keith A. Johnson ◽  
Arijit Sengupta
Keyword(s):  
Side Chains ◽  
Oligoethylene Glycol

scholarly journals Green-Solvent-Processed Conjugated Polymers for Organic Solar Cells: The Impact of Oligoethylene Glycol Side Chains

2019 ◽  
Vol 1 (4) ◽  
pp. 804-814 ◽  
Author(s):  
Zheng Chen ◽  
Liang Yan ◽  
Jeromy James Rech ◽  
Jun Hu ◽  
Qianqian Zhang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Conjugated Polymers ◽  
Organic Solar Cells ◽  
Side Chains ◽  
Green Solvent ◽  
Oligoethylene Glycol ◽  
The Impact

A New Challenge of Polymer Thermoelectric Materials as Ecomaterials

2007 ◽  
Vol 539-543 ◽  
pp. 2329-2332 ◽  
Author(s):  
Yoshikazu Shinohara ◽  
Yoshio Imai ◽  
Yukihiro Isoda ◽  
Kentaro Hiraishi ◽  
Hachiro Nakanishi
Keyword(s):  
Electrical Conductivity ◽  
Seebeck Coefficient ◽  
Thermoelectric Properties ◽  
Oxidative Polymerization ◽  
Side Chain ◽  
Side Chains ◽  
Nmr Analysis ◽  
Alkyl Side Chains ◽  
High Seebeck Coefficient ◽  
Polymer Thermoelectric

Typical conductive polymers of poly(3-alkylthiophenes) were synthesized by oxidative polymerization. Polythiophene with no side chain was also electrolyticaly polymerized. Alkyl side chains were CnH2n+1 with n=4, 6, 8, 12. The regioregularity with the HT linkage was larger than 99% based on NMR analysis. We have evaluated the effect of side chain size on the thermoelectric properties of Seebeck coefficient and electrical conductivity. The results were as follows: 1) Seebeck coefficient decreased with an increasing electrical conductivity. 2) High Seebeck coefficient >1mV/K was observed at low electrical conductivity <10-2S/cm. 3) Small side chains, especially no side chain caused higher thermoelectric properties of polythiophene series.

scholarly journals Tuning of the elastic modulus of a soft polythiophene through molecular doping

2021 ◽  
Author(s):  
Sepideh Zokaei ◽  
Donghyun Kim ◽  
Emmy Järsvall ◽  
Abigail M. Fenton ◽  
Albree R. Weisen ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Elastic Modulus ◽  
Side Chains ◽  
Molecular Doping ◽  
Oligoethylene Glycol

Molecular doping of a polythiophene with oligoethylene glycol side chains is found to strongly modulate not only the electrical but also the mechanical properties of the polymer.

Fine-tuning the solid-state ordering and thermoelectric performance of regioregular P3HT analogues by sequential oxygen-substitution of carbon atoms along the alkyl side chains

2019 ◽  
Vol 7 (8) ◽  
pp. 2333-2344 ◽  
Author(s):  
Liangjun Chen ◽  
Wei Liu ◽  
Yonggao Yan ◽  
Xianli Su ◽  
Shengqiang Xiao ◽  
...  
Keyword(s):  
Solid State ◽  
Thermoelectric Properties ◽  
Fine Tuning ◽  
Thermoelectric Performance ◽  
Side Chains ◽  
Alkyl Side Chains ◽  
Film Microstructure ◽  
Oxygen Substitution

Sequential O-substitution along the alkyl side chains of regioregular P3HT analogues enables fine-tuning of their film microstructure and thermoelectric properties.

Thermoelectric Properties of Poly(3-Alkylthiophenes)

2005 ◽  
Vol 492-493 ◽  
pp. 141-144 ◽  
Author(s):  
Yoshikazu Shinohara ◽  
K. Ohara ◽  
Hachiro Nakanishi ◽  
Yoshio Imai ◽  
Yukihiro Isoda
Keyword(s):  
Electrical Conductivity ◽  
Seebeck Coefficient ◽  
Thermoelectric Properties ◽  
Conductive Polymers ◽  
Oxidative Polymerization ◽  
Side Chain ◽  
Side Chains ◽  
Nmr Analysis ◽  
Alkyl Side Chains ◽  
High Seebeck Coefficient

Typical conductive polymers of poly(3-alkylthiophenes) were synthesized by oxidative polymerization. Alkyl side chains were CnH2n+1 with n=4, 6, 8, 12. The regioregularity with the HT linkage was larger than 99% based on NMR analysis. Completely regioregular head-to-tail (HT) poly(3-alkylthiophenes) were obtained. We have evaluated the effect of side chain size on the thermoelectric properties of Seebeck coefficient and electrical conductivity. The results were as follows: 1) Seebeck coefficient decreased with an increasing electrical conductivity. 2) High Seebeck coefficient >1mV/K was observed at low electrical conductivity <10-2S/cm. 3) The small side chain caused the higher electrical conductivity in the range of electrical conductivity <10- 1S/cm.

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