scholarly journals Segmental Dynamics Measured by Quasi-Elastic Neutron Scattering and Ion Transport in Chemically Distinct Polymer Electrolytes

2020 ◽  
Vol 53 (7) ◽  
pp. 2406-2411 ◽  
Author(s):  
Katrina Irene S. Mongcopa ◽  
Daniel A. Gribble ◽  
Whitney S. Loo ◽  
Madhusudan Tyagi ◽  
Scott A. Mullin ◽  
...  
Keyword(s):  
Ion Transport ◽  
Neutron Scattering ◽  
Polymer Electrolytes ◽  
Segmental Dynamics ◽  
Elastic Neutron ◽  
Elastic Neutron Scattering

scholarly journals Study of segmental dynamics and ion transport in polymer–ceramic composite electrolytes by quasi-elastic neutron scattering

2019 ◽  
Vol 4 (2) ◽  
pp. 379-385 ◽  
Author(s):  
X. Chelsea Chen ◽  
Robert L. Sacci ◽  
Naresh C. Osti ◽  
Madhusudan Tyagi ◽  
Yangyang Wang ◽  
...  
Keyword(s):  
Ionic Conductivity ◽  
Ion Transport ◽  
Neutron Scattering ◽  
Polymer Electrolyte ◽  
Ceramic Composite ◽  
Composite Electrolytes ◽  
Segmental Dynamics ◽  
Elastic Neutron ◽  
Elastic Neutron Scattering

This work elucidates the effects of Li+ conducting ceramic on the segmental dynamics and ionic conductivity of polymer electrolyte using quasi-elastic neutron scattering.

scholarly journals Study of the Segmental Dynamics and Ion Transport of Solid Polymer Electrolytes in the Semi-crystalline State

2021 ◽  
Vol 8 ◽  
Author(s):  
Xi Chelsea Chen ◽  
Robert L. Sacci ◽  
Naresh C. Osti ◽  
Madhusudan Tyagi ◽  
Yangyang Wang ◽  
...  
Keyword(s):  
Ionic Conductivity ◽  
Ion Transport ◽  
Polymer Electrolytes ◽  
Crystalline State ◽  
Room Temperature ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Segmental Dynamics ◽  
Elastic Neutron ◽  
Elastic Neutron Scattering

Solid polymer electrolytes are promising in fulfilling the requirements for a stable lithium metal anode toward higher energy and power densities. In this work, we investigate the segmental dynamics, ionic conductivity, and crystallinity of a polymer electrolyte consisting of poly(ethylene oxide) (PEO) and lithium triflate salt, in the semi-crystalline state. Using quasi-elastic neutron scattering, the segmental dynamics of PEO chains confined between the crystalline lamellae is quantified, using Cole–Cole analysis. We show that the structural relaxation time, τ0, of PEO equilibrated near room temperature is six-fold longer than the same sample that had just cooled down to room temperature. This corresponds to a three-fold smaller ionic conductivity in the equilibrated condition. This work reveals that the segmental dynamics of semi-crystalline polymer electrolytes is very sensitive to thermal history. We demonstrate that quasi-elastic neutron scattering can be used to characterize the ion transport and segmental dynamics in the semi-crystalline state.

scholarly journals Relationship between Segmental Dynamics Measured by Quasi-Elastic Neutron Scattering and Conductivity in Polymer Electrolytes

2018 ◽  
Vol 7 (4) ◽  
pp. 504-508 ◽  
Author(s):  
Katrina Irene S. Mongcopa ◽  
Madhusudan Tyagi ◽  
Jonathan P. Mailoa ◽  
Georgy Samsonidze ◽  
Boris Kozinsky ◽  
...  
Keyword(s):  
Neutron Scattering ◽  
Polymer Electrolytes ◽  
Segmental Dynamics ◽  
Elastic Neutron ◽  
Elastic Neutron Scattering

scholarly journals Correction: Study of segmental dynamics and ion transport in polymer–ceramic composite electrolytes by quasi-elastic neutron scattering

2019 ◽  
Vol 4 (4) ◽  
pp. 983-983
Author(s):  
X. Chelsea Chen ◽  
Robert L. Sacci ◽  
Naresh C. Osti ◽  
Madhusudan Tyagi ◽  
Beth L. Armstrong ◽  
...  
Keyword(s):  
Ion Transport ◽  
Neutron Scattering ◽  
Ceramic Composite ◽  
Composite Electrolytes ◽  
Segmental Dynamics ◽  
Elastic Neutron ◽  
Elastic Neutron Scattering

Correction for ‘Study of segmental dynamics and ion transport in polymer–ceramic composite electrolytes by quasi-elastic neutron scattering’ by X. Chelsea Chen et al., Mol. Syst. Des. Eng., 2019, 4, 379–385.

scholarly journals Quasi-Elastic Neutron Scattering Investigation of Dynamics in Polymer Electrolytes

2004 ◽  
Vol 37 (23) ◽  
pp. 8653-8660 ◽  
Author(s):  
Olga Russina ◽  
Alessandro Triolo ◽  
Yuichi Aihara ◽  
Mark T. F. Telling ◽  
Hans Grimm
Keyword(s):  
Neutron Scattering ◽  
Polymer Electrolytes ◽  
Elastic Neutron ◽  
Elastic Neutron Scattering

Membranes studied using neutron scattering and NMR

1995 ◽  
Vol 73 (11-12) ◽  
pp. 687-696 ◽  
Author(s):  
Myer Bloom ◽  
Thomas M. Bayerl
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Neutron Scattering ◽  
Spectral Characteristics ◽  
Nmr Relaxation ◽  
Elastic Neutron ◽  
Fluid Membranes ◽  
Dynamical Properties ◽  
Elastic Neutron Scattering ◽  
Complementary Techniques

After reviewing some of the basic measurements that characterize the study of physical properties of matter using neutron scattering and nuclear magnetic resonance (NMR), connections between information obtained in current research on fluid membranes using these two complementary techniques are explored in two major chapters. In the first, the type of information on the structure of fluid membranes obtained from coherent elastic neutron scattering is compared with that from NMR spectral characteristics. Then, the type of information obtained on dynamical properties from NMR relaxation (T1 and T2) measurements is compared with that from quasi-elastic neutron scattering. Examples of such connections are given with an emphasis on relationships between the time and distance scales intrinsic to neutron scattering and NMR.

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