Ionization and Neutralization Dynamics of CsPbBr3 Perovskite Nanocrystals Revealed by Double-Pump Transient Absorption Spectroscopy

2019 ◽  
Vol 10 (16) ◽  
pp. 4731-4736 ◽  
Author(s):  
Satoshi Nakahara ◽  
Keiichi Ohara ◽  
Hirokazu Tahara ◽  
Go Yumoto ◽  
Tokuhisa Kawawaki ◽  
...  
RSC Advances ◽  
2020 ◽  
Vol 10 (57) ◽  
pp. 34651-34657
Author(s):  
Virendra Kumar ◽  
Vandana Nagal ◽  
Rahul Kumar ◽  
Shubhda Srivastava ◽  
Bipin Kumar Gupta ◽  
...  

A mechanistic framework for hot carrier cooling process in CsPbBr3 PNC is depicted via transient absorption spectroscopy.


MRS Advances ◽  
2020 ◽  
Vol 5 (51) ◽  
pp. 2613-2621
Author(s):  
Michael L. Crawford ◽  
James C. Sadighian ◽  
Yasser Hassan ◽  
Henry J. Snaith ◽  
Cathy Y. Wong

AbstractLead halide perovskite nanocrystals (NCs) are promising for applications in light emitting devices owing to a strong emission spectrum that is tunable throughout the visible region by altering halide composition. However, in mixed-halide perovskite systems photoinduced migration drives formation of halide-segregated domains, altering the emission spectrum. The mechanism by which this segregation occurs is currently the subject of intense investigation. Processes involving the perovskite surface are expected to be of enhanced prevalence in NCs due to their large surface area to volume ratio. In this work, we use transient absorption spectroscopy to probe the excited-state dynamics of NCs before and after halide segregation. Comparison of global fit spectra of the measured signals suggests the accumulation of iodide at the surface, resulting in a redshifted emission spectrum.


2021 ◽  
Author(s):  
Ying Liu ◽  
Jianmin Lu ◽  
Qianxiao Zhang ◽  
Yajie Bai ◽  
Xuliang Pang ◽  
...  

Decoration of Ag-ultrathin Ni-MOF onside Cu2O was firstly fabricated. The charge-transfer dynamics at heterostructure was in-depth revealed by ultrafast transient absorption spectroscopy. NH3 yield rate (4.63 μg h-1 cm-2) with...


2021 ◽  
Vol 3 (1) ◽  
Author(s):  
Giovanni Cistaro ◽  
Luis Plaja ◽  
Fernando Martín ◽  
Antonio Picón

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