scholarly journals Lonely Atoms with Special Gifts: Breaking Linear Scaling Relationships in Heterogeneous Catalysis with Single-Atom Alloys

2018 ◽  
Vol 9 (18) ◽  
pp. 5636-5646 ◽  
Author(s):  
Matthew T. Darby ◽  
Michail Stamatakis ◽  
Angelos Michaelides ◽  
E. Charles. H. Sykes
Keyword(s):  
Heterogeneous Catalysis ◽  
Single Atom ◽  
Linear Scaling ◽  
Scaling Relationships ◽  
Single Atom Alloys

Copper-based single-atom alloys for heterogeneous catalysis

2021 ◽  
Author(s):  
Fengjuan Qin ◽  
Wenxing Chen
Keyword(s):  
Heterogeneous Catalysis ◽  
High Activity ◽  
Single Atom ◽  
Single Atom Alloys

Compared with traditional catalysts, copper-based SAAs have high activity and stability in heterogeneous catalysis due to their special structures and interactions.

scholarly journals UMA BREVE REVISÃO SOBRE A CATÁLISE POR ÁTOMOS ISOLADOS: CONCEITOS E APLICAÇÕES

Química Nova ◽  
2021 ◽  
Author(s):  
Luanne Ferreira ◽  
Ruan Ribeiro ◽  
Vinicius Madriaga ◽  
Sancler Vasconcelos ◽  
Eric Shimabukuro ◽  
...  
Keyword(s):  
Heterogeneous Catalysis ◽  
Homogeneous Catalysis ◽  
Industrial Revolution ◽  
Single Atom ◽  
Preparation Methods ◽  
High Exposure ◽  
Promising Alternative ◽  
Single Atoms ◽  
Catalytic Processes ◽  
Single Atom Alloys

A BRIEF OVERVIEW ON SINGLE-ATOM CATALYSIS: CONCEPTS AND APPLICATIONS. Catalytic processes became extremely important for the development of our society, especially after the second industrial revolution. Thus, the research for more efficient catalysts is an obstacle to overcome to achieve cheaper processes, higher yields, and selectivity of desired products. In this context, single-atom catalysis emerges as a promising alternative to unite the advantages of traditional homogeneous and heterogeneous catalysis. Catalysis by single-atoms is a bridge that unites in a single catalyst the ease of recovery and reuse (from heterogeneous catalysis) with the high exposure and uniformity of sites (from homogeneous catalysis). Thus, single-atom catalysts (SACs) and single-atom alloys (SAAs) have already found several applications in the literature, such as in hydrogenation, oxidation, conversion of biomass derivatives, electrocatalysis, and photocatalysis. However, it is essential to emphasize that it is still a field that is expanding and relatively new, with several opportunities and many barriers to surpass. In this review, concepts of homogeneous, enzymatic, and heterogeneous catalysis will be addressed, as well as fundamental aspects of single-atom catalysis, preparation methods, characterization, and current challenges.

scholarly journals Towards an object-oriented design of active hydrogen evolution catalysts on single-atom alloys

2021 ◽  
Author(s):  
Chuan Zhou ◽  
Jiayue Zhao ◽  
Peng Fei Liu ◽  
Jian-Fu Chen ◽  
Sheng Dai ◽  
...  
Keyword(s):  
Heterogeneous Catalysis ◽  
Hydrogen Evolution ◽  
Object Oriented ◽  
Single Atom ◽  
Active Hydrogen ◽  
Object Oriented Design ◽  
Single Atom Alloys

Given an oriented property, to locate the adequate material is always highly desired but very challenging in a range of applications including heterogeneous catalysis. Obviously, an object-oriented design/screening is an...

scholarly journals Highly dispersed Pt atoms and clusters on hydroxylated indium tin oxide: A view from first-principles calculations

2021 ◽  
Author(s):  
Simran Kumari ◽  
Philippe Sautet
Keyword(s):  
Heterogeneous Catalysis ◽  
Metal Atom ◽  
Tin Oxide ◽  
Indium Tin Oxide ◽  
First Principles ◽  
Catalytic Performance ◽  
Small Cluster ◽  
Single Atom ◽  
First Principles Calculations ◽  
Highly Dispersed

Supported single-atom and small cluster catalysts have become highly popular in heterogeneous catalysis. These catalysts can maximize the metal atom utilization while still showcasing superior catalytic performance. One of the...

Catalytic activity of palladium-doped silver dilute nanoalloys for formate oxidation from a theoretical perspective

2019 ◽  
Vol 21 (40) ◽  
pp. 22598-22610 ◽  
Author(s):  
Nan Zhang ◽  
Fuyi Chen ◽  
Longfei Guo
Keyword(s):  
Catalytic Activity ◽  
Oxidation Reaction ◽  
Theoretical Perspective ◽  
Single Atom ◽  
High Catalytic Activity ◽  
Formate Oxidation ◽  
First Time ◽  
Single Atom Alloys

We demonstrate for the first time that the Pd1Ag single-atom alloys exhibit a high catalytic activity for formate oxidation reaction.

PdCu single atom alloys supported on alumina for the selective hydrogenation of furfural

2021 ◽  
pp. 120652
Author(s):  
Mohammed J. Islam ◽  
Marta Granollers Mesa ◽  
Amin Osatiashtiani ◽  
Jinesh C. Manayil ◽  
Mark A. Isaacs ◽  
...  
Keyword(s):  
Selective Hydrogenation ◽  
Single Atom ◽  
Single Atom Alloys

Understanding the role of axial O in CO2 electroreduction on NiN4 single-atom catalysts via simulations in realistic electrochemical environment

2021 ◽  
Author(s):  
Xu Hu ◽  
Sai Yao ◽  
Letian Chen ◽  
Xu Zhang ◽  
Menggai Jiao ◽  
...  
Keyword(s):  
Sustainable Development ◽  
Heterogeneous Catalysis ◽  
Co2 Reduction ◽  
Reduction Reaction ◽  
Single Atom ◽  
Electrochemical Co2 Reduction ◽  
Co2 Electroreduction ◽  
Important Approach ◽  
Co2 Reduction Reaction

Electrochemical CO2 reduction reaction (CO2RR) is a very important approach to realize sustainable development. Single-atom catalysts show advantages in both homogeneous and heterogeneous catalysis, and considerable progress has been made...

Electrophilicity in heterogeneous catalysis: Role of surface and sub-surface modification

2021 ◽  
Author(s):  
Anand S Burange ◽  
Awais Ahmad ◽  
Rafael Luque
Keyword(s):  
Surface Modification ◽  
Heterogeneous Catalysis ◽  
Metal Nanoparticles ◽  
Organometallic Chemistry ◽  
Single Atom ◽  
Surface Organometallic Chemistry

Efforts to bridge the gap between homogeneous and heterogeneous catalysis include the use of surface organometallic chemistry, single atom catalysis and monodispersed metal nanoparticles, among others. In case of metal...

Methane Activation on Single-Atom Ir-doped Metal Nanoparticles from First-principles

2021 ◽  
Author(s):  
Yugang Ren ◽  
Xiaojing Liu ◽  
Zhaojun Zhang ◽  
Xiangjian Shen
Keyword(s):  
Electronic Structure ◽  
Heterogeneous Catalysis ◽  
Metal Nanoparticles ◽  
First Principles ◽  
Methane Activation ◽  
Single Atom ◽  
Surface Electronic Structure

The breaking of the C-H bond of CH4 is of great importance and one of the most efficient strategies in heterogeneous catalysis is to alter surface electronic structure by doping...

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