The Interplay Between Hydrogen Bonding and Coulombic Forces in Determining the Structure of Sulfuric Acid-Amine Clusters

2018 ◽  
Vol 9 (6) ◽  
pp. 1216-1222 ◽  
Author(s):  
Sarah E. Waller ◽  
Yi Yang ◽  
Eleanor Castracane ◽  
Emily E. Racow ◽  
John J. Kreinbihl ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Sulfuric Acid

Hydrogen bonding in cyclic complexes of carboxylic acid–sulfuric acid and their atmospheric implications

RSC Advances ◽  
2016 ◽  
Vol 6 (75) ◽  
pp. 71733-71743 ◽  
Author(s):  
Hailiang Zhao ◽  
Qun Zhang ◽  
Lin Du
Keyword(s):  
Hydrogen Bonding ◽  
Sulfuric Acid ◽  
Carboxylic Acid ◽  
Carboxylic Acids ◽  
Particle Formation ◽  
New Particle Formation ◽  
Ring Structures ◽  
Cyclic Complexes

Carboxylic acids form cyclic ring structures with sulfuric acid and they could potentially be important in new particle formation.

scholarly journals Ultrastable Imine-Based Covalent Organic Frameworks for Sulfuric Acid Recovery: An Effect of Interlayer Hydrogen Bonding

2018 ◽  
Vol 57 (20) ◽  
pp. 5797-5802 ◽  
Author(s):  
Arjun Halder ◽  
Suvendu Karak ◽  
Matthew Addicoat ◽  
Saibal Bera ◽  
Amit Chakraborty ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Sulfuric Acid ◽  
Covalent Organic Frameworks ◽  
Acid Recovery

scholarly journals Ultrastable Imine-Based Covalent Organic Frameworks for Sulfuric Acid Recovery: An Effect of Interlayer Hydrogen Bonding

2018 ◽  
Vol 130 (20) ◽  
pp. 5899-5904 ◽  
Author(s):  
Arjun Halder ◽  
Suvendu Karak ◽  
Matthew Addicoat ◽  
Saibal Bera ◽  
Amit Chakraborty ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Sulfuric Acid ◽  
Covalent Organic Frameworks ◽  
Acid Recovery

Effect of hydrogen bonding on the liquid crystalline behavior of Poly(p-phenylene terephthamide) in sulfuric acid

Polymer ◽  
2018 ◽  
Vol 143 ◽  
pp. 316-323 ◽  
Author(s):  
Sheng Zhou ◽  
Chang-Sheng Li ◽  
Xing-He Fan ◽  
Zhihao Shen
Keyword(s):  
Hydrogen Bonding ◽  
Sulfuric Acid ◽  
Liquid Crystalline

Protonation Dynamics and Hydrogen Bonding in Aqueous Sulfuric Acid

2015 ◽  
Vol 119 (35) ◽  
pp. 11732-11739 ◽  
Author(s):  
Johannes Niskanen ◽  
Christoph J. Sahle ◽  
Iina Juurinen ◽  
Jaakko Koskelo ◽  
Susi Lehtola ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Sulfuric Acid ◽  
Aqueous Sulfuric Acid

A whole zoo of hydrogen bonds in one crystal structure: tris(isonicotinium) hydrogensulfate sulfate monohydrate

2017 ◽  
Vol 73 (7) ◽  
pp. 525-530 ◽  
Author(s):  
Khai-Nghi Truong ◽  
Niklas Lothmann ◽  
Ulli Englert
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Sulfuric Acid ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Pyridine Ring ◽  
Isonicotinic Acid ◽  
Distance Range ◽  
Pyridinium Cation ◽  
Brönsted Acid

Depending on the reaction partner, the organic ditopic molecule isonicotinic acid (Hina) can act either as a Brønsted acid or base. With sulfuric acid, the pyridine ring is protonated to become a pyridinium cation. Crystallization from ethanol affords the title compound tris(4-carboxypyridinium) hydrogensulfate sulfate monohydrate, 3C6H6NO2 +·HSO4 −·SO4 2−·H2O or [(H2ina)3(HSO4)(SO4)(H2O)]. This solid contains 11 classical hydrogen bonds of very different flavour and nonclassical C—H...O contacts. All N—H and O—H donors find at least one acceptor within a suitable distance range, with one of the three pyridinium H atoms engaged in bifurcated N—H...O hydrogen bonds. The shortest hydrogen-bonding O...O distance is subtended by hydrogensulfate and sulfate anions, viz. 2.4752 (19) Å, and represents one of the shortest hydrogen bonds ever reported between these residues.

scholarly journals New insights into the oxidation of phenoxatellurine with sulfuric acid

2019 ◽  
Vol 42 (1) ◽  
pp. 150-152 ◽  
Author(s):  
Farzin Mostaghimi ◽  
Jens Bolsinger ◽  
Enno Lork ◽  
Jens Beckmann
Keyword(s):  
Hydrogen Bonding ◽  
Sulfuric Acid ◽  
Coordination Polymer ◽  
Crystal Lattice ◽  
Ion Pairs ◽  
Radical Cations ◽  
Sulfate Ions ◽  
X Ray ◽  
X Ray Crystallography ◽  
Double Decker

Abstract The oxidation of phenoxatellurine (PT) with conc. H2SO4 was reinvestigated. Two crystalline products, namely [PT2][H3O](SO4H)3 (1) and [PT](SO4) (2) were isolated and fully characterized by X-ray crystallography. The structure of 1 features [PT2]2+ dications giving rise to double-decker structures with two parallel PT layers that arise from dimerisation of two radical cations [PT]˙+. The [PT2]2+ dications and the hydrogensulfate ions are associated via secondary Te···O interations. The oxonium ion and the hydrogensulfate ions are involved in hydrogen bonding. The structure of 2 comprises ion pairs consisting of [PT]2+ dications and sulfate ions, which form a 2D coordination polymer. In addition, adjacent sulfate ions in the crystal lattice bind to tellurium atoms via secondary secondary Te···O interations.

scholarly journals Supramolecular Iron(III) Tetramesitylporphyrin Cluster Structure Assembled by Hydrogen Bonding with Sulfuric Acid

2019 ◽  
Vol 12 (1) ◽  
pp. 29-34
Author(s):  
Evgeny V. Kudrik ◽  
Sergey E. Nefedov ◽  
Alexander B. Sorokin
Keyword(s):  
Hydrogen Bonding ◽  
Sulfuric Acid ◽  
Cluster Structure
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