Disentangling Electron–Phonon Coupling and Thermal Expansion Effects in the Band Gap Renormalization of Perovskite Nanocrystals

2020 ◽  
pp. 569-575
Author(s):  
Andrea Rubino ◽  
Adrián Francisco-López ◽  
Alex J. Barker ◽  
Annamaria Petrozza ◽  
Mauricio E. Calvo ◽  
...  
Keyword(s):  
Thermal Expansion ◽  
Band Gap ◽  
Phonon Coupling ◽  
Perovskite Nanocrystals ◽  
Electron Phonon Coupling

scholarly journals Resonance and antiresonance in Raman scattering in GaSe and InSe crystals

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
M. Osiekowicz ◽  
D. Staszczuk ◽  
K. Olkowska-Pucko ◽  
Ł. Kipczak ◽  
M. Grzeszczyk ◽  
...  
Keyword(s):  
Raman Scattering ◽  
Temperature Effect ◽  
Band Gap ◽  
Raman Spectra ◽  
Quantum Interference ◽  
Optical Band Gap ◽  
Phonon Coupling ◽  
Phonon Modes ◽  
Electron Phonon Coupling ◽  
Resonant Raman

AbstractThe temperature effect on the Raman scattering efficiency is investigated in $$\varepsilon$$ ε -GaSe and $$\gamma$$ γ -InSe crystals. We found that varying the temperature over a broad range from 5 to 350 K permits to achieve both the resonant conditions and the antiresonance behaviour in Raman scattering of the studied materials. The resonant conditions of Raman scattering are observed at about 270 K under the 1.96 eV excitation for GaSe due to the energy proximity of the optical band gap. In the case of InSe, the resonant Raman spectra are apparent at about 50 and 270 K under correspondingly the 2.41 eV and 2.54 eV excitations as a result of the energy proximity of the so-called B transition. Interestingly, the observed resonances for both materials are followed by an antiresonance behaviour noticeable at higher temperatures than the detected resonances. The significant variations of phonon-modes intensities can be explained in terms of electron-phonon coupling and quantum interference of contributions from different points of the Brillouin zone.

Low temperature photoluminescence properties of CsPbBr3 quantum dots embedded in glasses

2017 ◽  
Vol 19 (26) ◽  
pp. 17349-17355 ◽  
Author(s):  
Bing Ai ◽  
Chao Liu ◽  
Zhao Deng ◽  
Jing Wang ◽  
Jianjun Han ◽  
...  
Keyword(s):  
Activation Energy ◽  
Quantum Dots ◽  
Thermal Expansion ◽  
Low Temperature ◽  
Size Dependence ◽  
Phonon Coupling ◽  
Photoluminescence Properties ◽  
Electron Phonon Coupling ◽  
Cspbbr3 Quantum Dots ◽  
Low Temperature Photoluminescence

Size dependence of exciton activation energy, electron–phonon coupling strength, and thermal expansion of the bandgap of CsPbBr3 QDs were studied.

Harnessing Hot Phonon Bottleneck in Metal Halide Perovskite Nanocrystals via Interfacial Electron–Phonon Coupling

Nano Letters ◽  
2020 ◽  
Vol 20 (6) ◽  
pp. 4610-4617 ◽  
Author(s):  
Zhonghui Nie ◽  
Xuanzhao Gao ◽  
Yinjuan Ren ◽  
Siyang Xia ◽  
Yuhan Wang ◽  
...  
Keyword(s):  
Metal Halide ◽  
Phonon Coupling ◽  
Perovskite Nanocrystals ◽  
Phonon Bottleneck ◽  
Metal Halide Perovskite ◽  
Electron Phonon Coupling ◽  
Halide Perovskite

Investigations of the Thermal Shifts and Electron–Phonon Coupling Parameters of R1 and R2 Lines for Cr3+-doped Forsterite

2014 ◽  
Vol 69 (8-9) ◽  
pp. 497-500 ◽  
Author(s):  
Xiao-Xuan Wu ◽  
Wen-Chen Zheng
Keyword(s):  
Thermal Expansion ◽  
Spectral Lines ◽  
Coupling Coefficients ◽  
Phonon Coupling ◽  
Lattice Thermal Expansion ◽  
Phonon Interaction ◽  
Electron Phonon Interaction ◽  
Electron Phonon Coupling ◽  
Coupling Parameters ◽  
Vibrational Contribution

The thermal shifts of R1 and R2 lines in Cr3+-doped forsterite (Mg2SiO4) are studied by considering both the static contribution due to lattice thermal expansion and the vibrational contribution due to electron-phonon interaction. In the studies, the thermal expansion coefficient of the Cr3+ center is assumed reasonably as that of the corresponding cluster in the host crystal. The results suggest that for R1 and R2 lines the static contributions are opposite in sign and in magnitude about 37% and 45%, respectively, of the corresponding vibrational contributions. The true electron-phonon coupling coefficients α' (obtained by considering both contributions) increase by about 58% and 81%, respectively, for R1 and R2 lines in comparison with the corresponding parameters α obtained by considering only the vibrational contribution. It appears that for the reasonable explanation of thermal shift of spectral lines and the exact estimation of electron-phonon coupling coefficient, both the static and vibrational contributions should be taken into account

Lattice Dynamics and Electron–Phonon Coupling in Lead-Free Cs2AgIn1–xBixCl6 Double Perovskite Nanocrystals

2020 ◽  
Vol 11 (6) ◽  
pp. 2113-2120 ◽  
Author(s):  
Debjit Manna ◽  
Jiban Kangsabanik ◽  
Tapan Kumar Das ◽  
Debashish Das ◽  
Aftab Alam ◽  
...  
Keyword(s):  
Lattice Dynamics ◽  
Double Perovskite ◽  
Lead Free ◽  
Phonon Coupling ◽  
Perovskite Nanocrystals ◽  
Electron Phonon Coupling

From 0D Cs3Bi2I9 to 2D Cs3Bi2I6Cl3: Dimensional Expansion Induces a Direct Band Gap but Enhances Electron–Phonon Coupling

2019 ◽  
Vol 31 (7) ◽  
pp. 2644-2650 ◽  
Author(s):  
Kyle M. McCall ◽  
Constantinos C. Stoumpos ◽  
Oleg Y. Kontsevoi ◽  
Grant C. B. Alexander ◽  
Bruce W. Wessels ◽  
...  
Keyword(s):  
Band Gap ◽  
Phonon Coupling ◽  
Direct Band Gap ◽  
Electron Phonon Coupling ◽  
Direct Band

Experimental determination of surface thermal expansion and electron–phonon coupling constant of 1T-PtTe2

2D Materials ◽  
2020 ◽  
Vol 7 (2) ◽  
pp. 025007 ◽  
Author(s):  
Gloria Anemone ◽  
Manuela Garnica ◽  
Marilena Zappia ◽  
Pablo Casado Aguilar ◽  
Amjad Al Taleb ◽  
...  
Keyword(s):  
Thermal Expansion ◽  
Experimental Determination ◽  
Coupling Constant ◽  
Phonon Coupling ◽  
Electron Phonon Coupling
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