Unique Orientation of the Solid–Solid Interface at the Janus Particle Boundary Induced by Ionic Liquids

Ayuna Tsyrenova; Muhammad Q. Farooq; Stephen M. Anthony; Keyvan Mollaeian; Yifan Li; Fei Liu; Kyle Miller; Juan Ren; Jared L. Anderson; Shan Jiang

doi:10.1021/acs.jpclett.0c02813

Unique Orientation of the Solid–Solid Interface at the Janus Particle Boundary Induced by Ionic Liquids

The Journal of Physical Chemistry Letters ◽

10.1021/acs.jpclett.0c02813 ◽

2020 ◽

Vol 11 (22) ◽

pp. 9834-9841

Author(s):

Ayuna Tsyrenova ◽

Muhammad Q. Farooq ◽

Stephen M. Anthony ◽

Keyvan Mollaeian ◽

Yifan Li ◽

...

Keyword(s):

Ionic Liquids ◽

Janus Particle ◽

Solid Interface ◽

Particle Boundary

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Adsorbed and near surface structure of ionic liquids at a solid interface

Physical Chemistry Chemical Physics ◽

10.1039/c3cp44163f ◽

2013 ◽

Vol 15 (9) ◽

pp. 3320 ◽

Cited By ~ 89

Author(s):

Juan José Segura ◽

Aaron Elbourne ◽

Erica J. Wanless ◽

Gregory G. Warr ◽

Kislon Voïtchovsky ◽

...

Keyword(s):

Ionic Liquids ◽

Surface Structure ◽

Near Surface ◽

Solid Interface

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Atom-probe analysis of the solid-liquid interface

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100139755 ◽

1995 ◽

Vol 53 ◽

pp. 676-677

Author(s):

J.A. Panitz

Keyword(s):

Molecular Level ◽

Selective Adsorption ◽

Electronic Devices ◽

Atom Probe ◽

Chemical Agent ◽

Hostile Environment ◽

Solid Interface ◽

Solid Liquid Interface ◽

Solid Liquid ◽

Chemically Selective

The first few atomic layers of a solid can form a barrier between its interior and an often hostile environment. Although adsorption at the vacuum-solid interface has been studied in great detail, little is known about adsorption at the liquid-solid interface. Adsorption at a liquid-solid interface is of intrinsic interest, and is of technological importance because it provides a way to coat a surface with monolayer or multilayer structures. A pinhole free monolayer (with a reasonable dielectric constant) could lead to the development of nanoscale capacitors with unique characteristics and lithographic resists that surpass the resolution of their conventional counterparts. Chemically selective adsorption is of particular interest because it can be used to passivate a surface from external modification or change the wear and the lubrication properties of a surface to reflect new and useful properties. Immunochemical adsorption could be used to fabricate novel molecular electronic devices or to construct small, “smart”, unobtrusive sensors with the potential to detect a wide variety of preselected species at the molecular level. These might include a particular carcinogen in the environment, a specific type of explosive, a chemical agent, a virus, or even a tumor in the human body.

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