Size-Dependent Pt-TiO2 Strong Metal–Support Interaction

2020 ◽  
Vol 11 (12) ◽  
pp. 4603-4607
Author(s):  
Zongfang Wu ◽  
Yangyang Li ◽  
Weixin Huang
Keyword(s):  
Size Dependent ◽  
Support Interaction ◽  
Metal Support Interaction ◽  
Metal Support ◽  
Strong Metal Support Interaction

Size-dependent strong metal-support interaction in Pd/ZnO catalysts for hydrogenation of CO2 to methanol

2021 ◽  
Author(s):  
Liangcai Zhang ◽  
Xinyu Liu ◽  
Hengwei Wang ◽  
Lina Cao ◽  
Chenxi Huang ◽  
...  
Keyword(s):  
Catalytic Reactions ◽  
Hydrogenation Of Co2 ◽  
Size Dependent ◽  
Support Interaction ◽  
Metal Support Interaction ◽  
Metal Support ◽  
The Stability ◽  
Smsi Effect ◽  
Strong Metal Support Interaction

Strong metal-support interaction (SMSI) has long been studied in catalytic reactions. Proper utilization of the SMSI effect might not only improve the stability of the catalysts, but also the activity...

scholarly journals Size-dependent strong metal-support interaction in TiO2 supported Au nanocatalysts

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Xiaorui Du ◽  
Yike Huang ◽  
Xiaoli Pan ◽  
Bing Han ◽  
Yang Su ◽  
...  
Keyword(s):  
Catalytic Performance ◽  
Hydrogenation Reaction ◽  
Au Nps ◽  
Size Dependent ◽  
Support Interaction ◽  
Alternative Approach ◽  
Metal Support Interaction ◽  
Metal Support ◽  
Thermodynamic Equilibrium Model ◽  
Strong Metal Support Interaction

AbstractThe strong metal-support interaction (SMSI) has long been studied in heterogonous catalysis on account of its importance in stabilizing active metals and tuning catalytic performance. As a dynamic process taking place at the metal-support interface, the SMSI is closely related to the metal surface properties which are usually affected by the size of metal nanoparticles (NPs). In this work we report the discovery of a size effect on classical SMSI in Au/TiO2 catalyst where larger Au particles are more prone to be encapsulated than smaller ones. A thermodynamic equilibrium model was established to describe this phenomenon. According to this finding, the catalytic performance of Au/TiO2 catalyst with uneven size distribution can be improved by selectively encapsulating the large Au NPs in a hydrogenation reaction. This work not only brings in-depth understanding of the SMSI phenomenon and its formation mechanism, but also provides an alternative approach to refine catalyst performance.

Dynamical Observation and Detailed Description of Catalysts under Strong Metal–Support Interaction

Nano Letters ◽  
2016 ◽  
Vol 16 (7) ◽  
pp. 4528-4534 ◽  
Author(s):  
Shuyi Zhang ◽  
Philipp N. Plessow ◽  
Joshua J. Willis ◽  
Sheng Dai ◽  
Mingjie Xu ◽  
...  
Keyword(s):  
Support Interaction ◽  
Metal Support Interaction ◽  
Metal Support ◽  
Strong Metal Support Interaction
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