Ultrafast Transient Spectra and Dynamics of MXene (Ti3C2Tx) in Response to Light Excitations of Various Wavelengths

2020 ◽  
Vol 124 (11) ◽  
pp. 6441-6447 ◽  
Author(s):  
Qi Zhang ◽  
Li Yan ◽  
Mingsheng Yang ◽  
Guorong Wu ◽  
Mingjun Hu ◽  
...  
Keyword(s):  
2020 ◽  
Author(s):  
François Lapointe ◽  
Martin Wolf ◽  
Kramer Campen ◽  
Yujin Tong

<p>The hydrated electron has fundamental and practical significance in radiation and radical chemistry, catalysis and radiobiology. While its bulk properties have been extensively studied, its behavior at buried solid/liquid interfaces is still unclear due to the lack of effective tools to characterize this short-lived species in between two condensed matter layers. In this study, we develop a novel optoelectronic technique for the characterization of the birth and structural evolution of solvated electrons at the metal/liquid interface with a femtosecond time resolution. We thus recorded for the first time their transient spectra (in a photon energy range from 0.31 to 1.85 eV) <i>in situ</i><i> </i>with a time resolution of 50 fs. The transient species show state-dependent optical transition behaviors from being isotropic in the hot state to perpendicular to the surface in the trapped and solvated states. The technique will enable a better understanding of hot electron-driven reactions at electrochemical interfaces.</p>


2003 ◽  
Vol 107 (11) ◽  
pp. 1689-1696 ◽  
Author(s):  
Paolo Foggi ◽  
Frederik V. R. Neuwahl ◽  
Laura Moroni ◽  
Pier Remigio Salvi

1967 ◽  
Vol 29 (1) ◽  
pp. 149-151
Author(s):  
A. K. Ghatak ◽  
I. C. Goyal ◽  
L. S. Kothari
Keyword(s):  

1987 ◽  
Vol 59 (19) ◽  
pp. 2149-2152 ◽  
Author(s):  
J. E. Golub ◽  
T. W. Mossberg

1999 ◽  
Vol 28 (8) ◽  
pp. 805-806 ◽  
Author(s):  
Shigero Oishi ◽  
Hirotaka Tsubaki ◽  
Hideyo Matsuzawa
Keyword(s):  

1982 ◽  
Vol 18 (21) ◽  
pp. 904 ◽  
Author(s):  
Pao-Lo Liu ◽  
T.P. Lee ◽  
C.A. Burrus ◽  
I.P. Kaminow ◽  
J.-S. Ko

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