All-Solid-State Electrospun Poly(vinylidene fluoride-co-hexafluoropropylene)/Li7.1La3Ba0.05Zr1.95O12 Nanohybrid Membrane Electrolyte for High-Energy Li-Ion Capacitors

2019 ◽  
Vol 123 (50) ◽  
pp. 30145-30154 ◽  
Author(s):  
Dheeraj Kumar Maurya ◽  
Vignesh Murugadoss ◽  
Subramania Angaiah
2001 ◽  
Vol 39 (12) ◽  
pp. 1371-1380 ◽  
Author(s):  
Koh Nakamura ◽  
Masayuki Nagai ◽  
Tetsuo Kanamoto ◽  
Yoshiyuki Takahashi ◽  
Takeo Furukawa

Author(s):  
Xiangyu Meng ◽  
Yuzhao Liu ◽  
Zhiyu Wang ◽  
Yizhou Zhang ◽  
Xingyu Wang ◽  
...  

Recent years have witnessed a thriving pursuit of high-energy Li metal batteries for replacing existing Li-ion batteries. However, the cell chemistry involving extremely reactive Li metal anode in flammable organic...


2020 ◽  
Vol 13 (06) ◽  
pp. 2051042
Author(s):  
Zhong Yang ◽  
Jing Wang ◽  
Long He ◽  
Chaoyong Deng ◽  
Kongjun Zhu

Flexible dielectric capacitors are becoming shining stars in modern electronic devices. Ceramic particles with large dielectric constants and benign compatibility are attractive candidates to enhance the energy storage density of pristine polymer capacitors while guaranteeing their flexibility. In this work, double-shell structure of Al2O3 (AO) and dopamine (PDA) were successively coated on the Nd-doped BaTiO3 (NBT) particles and then introduced into the Poly(vinylidene fluoride) (PVDF) matrix. Obvious enhancement in dielectric constants was observed while the dielectric loss remained nearly constant. For the composite films with 1–4[Formula: see text]vol.% NBT@AO@PDA NPs, the maximum energy density of 9.1[Formula: see text]J/cm3 and energy efficiency of 65% was achieved at 430[Formula: see text]MV/m in the sample with 1[Formula: see text]vol.% filling ratio, which are 1.4 and 1.3 times larger than those of pristine PVDF at 450[Formula: see text]MV/m. The finite element simulation reveals the effective relief of the electric field concentration in the composite film induced by the AO and PDA layers. The greater improvement in the energy storage performance could be anticipated if the dispersity of NBT@AO@PDA NPs was further improved.


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