Effect of Second-Sphere Interactions on the Magnetic Anisotropy of Lanthanide Single-Molecule Magnets: Electrostatic Interactions and Supramolecular Contacts

2020 ◽  
Vol 124 (9) ◽  
pp. 5308-5320 ◽  
Author(s):  
Yolimar Gil ◽  
Leonel Llanos ◽  
Patricio Cancino ◽  
Pablo Fuentealba ◽  
Andrés Vega ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Single Molecule ◽  
Electrostatic Interactions ◽  
Single Molecule Magnets ◽  
Supramolecular Contacts

Magnetic anisotropy on demand exploiting high-pressure as remote control: an ab initio proof-of-concept

2021 ◽  
Author(s):  
Matteo Briganti ◽  
Federico Totti
Keyword(s):  
High Pressure ◽  
High Temperature ◽  
Remote Control ◽  
Magnetic Anisotropy ◽  
Ab Initio ◽  
Single Molecule ◽  
Boiling Temperature ◽  
Proof Of Concept ◽  
Single Molecule Magnets ◽  
On Demand

Lanthanide based single molecule magnets have recently become very promising systems for creating single molecule device working at high temperature (nitrogen boiling temperature). However, the variation of direction of the...

Enhanced energy barriers triggered by magnetic anisotropy modulation via tuning the functional groups on the bridging ligands in Dy2 single-molecule magnets

2018 ◽  
Vol 47 (42) ◽  
pp. 15197-15205 ◽  
Author(s):  
Yaru Qin ◽  
Yu Jing ◽  
Yu Ge ◽  
Wei Liu ◽  
Yahong Li ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Functional Groups ◽  
Single Molecule ◽  
Energy Barrier ◽  
Energy Barriers ◽  
Single Molecule Magnets ◽  
Bridging Ligands

Two dinuclear dysprosium complexes of 1 and 2 have been synthesized and both of them exhibit SMM behavior. The energy barrier is enhanced ca. 35 K by elaborately tuning the backbones of the ligands.

scholarly journals Polarized Neutron Diffraction: An Excellent Tool to Evidence the Magnetic Anisotropy—Structural Relationships in Molecules

2021 ◽  
Vol 7 (12) ◽  
pp. 158
Author(s):  
Dominique Luneau ◽  
Béatrice Gillon
Keyword(s):  
Neutron Diffraction ◽  
Magnetic Anisotropy ◽  
Single Molecule ◽  
Coordination Compounds ◽  
Single Molecule Magnets ◽  
Structural Relationships ◽  
Polarized Neutron ◽  
The Individual ◽  
The Relationship ◽  
Excellent Tool

This publication reviews recent advances in polarized neutron diffraction (PND) studies of magnetic anisotropy in coordination compounds comprising d or f elements and having different nuclearities. All these studies illustrate the extent to which PND can provide precise and direct information on the relationship between molecular structure and the shape and axes of magnetic anisotropy of the individual metal sites. It makes this experimental technique (PND) an excellent tool to help in the design of molecular-based magnets and especially single-molecule magnets for which strong uniaxial magnetic anisotropy is required.

Electronic control of strong magnetic anisotropy in Co-based single-molecule magnets

2021 ◽  
Vol 104 (13) ◽  
Author(s):  
Zahra Hooshmand ◽  
Jie-Xiang Yu ◽  
Hai-Ping Cheng ◽  
Mark R Pederson
Keyword(s):  
Magnetic Anisotropy ◽  
Single Molecule ◽  
Electronic Control ◽  
Single Molecule Magnets

Single-Molecule Magnets of Ferrous Cubes:  Structurally Controlled Magnetic Anisotropy

2004 ◽  
Vol 126 (28) ◽  
pp. 8805-8812 ◽  
Author(s):  
Hiroki Oshio ◽  
Norihisa Hoshino ◽  
Tasuku Ito ◽  
Motohiro Nakano
Keyword(s):  
Magnetic Anisotropy ◽  
Single Molecule ◽  
Single Molecule Magnets

Three tetracoordinate Co(ii) complexes [Co(biq)X2] (X = Cl, Br, I) with easy-plane magnetic anisotropy as field-induced single-molecule magnets

2015 ◽  
Vol 44 (40) ◽  
pp. 17565-17571 ◽  
Author(s):  
L. Smolko ◽  
J. Černák ◽  
M. Dušek ◽  
J. Miklovič ◽  
J. Titiš ◽  
...  
Keyword(s):  
External Field ◽  
Magnetic Anisotropy ◽  
Single Molecule ◽  
Easy Plane ◽  
Single Molecule Magnets ◽  
Mononuclear Complexes ◽  
Superparamagnetic Behaviour

Three mononuclear complexes [CoII(biq)X2] (biq = 2,2′-biquinoline; X = Cl, Br, I) possess a sizable magnetic anisotropy, and they display a superparamagnetic behaviour in an applied external field that culminates between BDC = 0.2–0.3 T.

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