scholarly journals Microscopic Dynamics in an Ionic Liquid Augmented with Organic Solvents

2019 ◽  
Vol 123 (32) ◽  
pp. 19354-19361 ◽  
Author(s):  
Naresh C. Osti ◽  
Ray A. Matsumoto ◽  
Matthew W. Thompson ◽  
Peter T. Cummings ◽  
Madhusudan Tyagi ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Organic Solvents ◽  
Microscopic Dynamics

Imidazolium chloride-based ionic liquid-assisted improvement of lipase activity in organic solvents

2011 ◽  
Vol 11 (3) ◽  
pp. 259-263 ◽  
Author(s):  
Somayeh Daneshjoo ◽  
Neda Akbari ◽  
Abbas Akhavan Sepahi ◽  
Bijan Ranjbar ◽  
Ramezan-Ali Khavarinejad ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Organic Solvents ◽  
Lipase Activity ◽  
Imidazolium Chloride

The wormlike micelles formed using an ionic liquid surfactant and polar organic solvents at low temperature without additives and their lubricant properties

Soft Matter ◽  
2021 ◽  
Author(s):  
Huijiao Cao ◽  
Wenlin Xu ◽  
Xia Guo
Keyword(s):  
Ionic Liquid ◽  
Low Temperature ◽  
Organic Solvent ◽  
Organic Solvents ◽  
Wormlike Micelles ◽  
Polar Organic Solvents ◽  
Ionic Liquid Surfactant ◽  
Nonpolar Organic

Wormlike micelles (or reverse wormlike micelles) are flexible cylindrical chains that are normally formed in water (or a nonpolar organic solvent) at 25.0 °C or above; the formation of wormlike micelles at lower temperatures is rare.

Ionic Liquid Promoted Eco-friendly and Efficient Synthesis of Six-membered Npolyheterocycles

2018 ◽  
Vol 15 (8) ◽  
pp. 1124-1146 ◽  
Author(s):  
Navjeet Kaur
Keyword(s):  
Organic Chemistry ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Organic Solvents ◽  
Review Article ◽  
Environmentally Benign ◽  
Wide Range ◽  
Catalyzed Reactions ◽  
Metal Catalyzed ◽  
Reaction Media

Background: The synthesis of N-polyheterocycles by environmentally benign method is highly attractive but challenging proposition. New strategies have been developed for the preparation of polycyclic heterocycles in the last decades. In this review article, the synthesis of nitrogen containing six-membered polycyclic heterocyclic compounds is presented with the application of ionic liquids. This contribution focuses on the literature related to the total synthesis of six-membered N-polyheterocycles. Objective: Ionic liquids not only acted as environmentally benign reaction media but also as catalysts which afforded the very promising replacements of traditional molecular solvents in organic chemistry due to their stability, non-flammability, non-volatility and ease of recyclability. Ionic liquids are utilized in metal catalyzed reactions in place of organic solvents in the last years. It has attracted considerable attention in recent years. Ionic liquids acted as alternatives of organic solvents and these ILs are environment friendly. Conclusion: In the area of green chemistry ionic liquid assisted synthesis is a very promising technique which afforded a flexible platform for the formation of heterocycles. The influence of ILs on the development of efficient and new synthetic protocols over the last decade for the construction of N-polyheterocycles is featured in this review article. These synthetic strategies will continue to attract more attention and will find a wide range of applications in organic synthesis. In conclusion, ionic liquids assisted syntheses have become an efficient and powerful tool in organic chemistry quickly.

A Phosphine-mediated Synthesis of 2,3,4,5-tetra-substituted Nhydroxypyrroles from α-oximino Ketones and Dialkyl Acetylenedicarboxylates Under Ionic Liquid Green-media

2018 ◽  
Vol 21 (1) ◽  
pp. 14-18
Author(s):  
Ashraf S. Shahvelayati ◽  
Maryam Ghazvini ◽  
Khadijeh Yadollahzadeh ◽  
Akram S. Delbari
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Organic Solvents ◽  
Condensation Reaction ◽  
Reaction Medium ◽  
Sustainable Chemistry ◽  
Polyfunctional Compounds ◽  
High Yields ◽  
Work Up ◽  
Reaction Media

Background: The development of multicomponent reactions (MCRs) in the presence of task-specific ionic liquids (ILs), used not only as environmentally benign reaction media, but also as catalysts, is a new approach that meet with the requirements of sustainable chemistry. In recent years, the use of ionic liquids as a green media for organic synthesis has become a chief study area. This is due to their unique properties such as non-volatility, non-flammability, chemical and thermal stability, immiscibility with both organic compounds and water and recyclability. Ionic liquids are used as environmentally friendly solvents instead of hazardous organic solvents. Objective: We report the condensation reaction between α-oximinoketone and dialkyl acetylene dicarboxylate in the presence of triphenylphosphine to afford substituted pyrroles under ionic liquid conditions in good yields. Result: Densely functionalized pyrroles was easily prepared from reaction of α-oximinoketones, dialkyl acetylene dicarboxylate in the presence of triphenylphosphine in a quantitative yield under ionic liquid conditions at room temperature. Conclusion: In conclusion, ionic liquids are indicated as a useful and novel reaction medium for the selective synthesis of functionalized pyrroles. This reaction medium can replace the use of hazardous organic solvents. Easy work-up, synthesis of polyfunctional compounds, decreased reaction time, having easily available-recyclable ionic liquids, and good to high yields are advantages of present method.

scholarly journals Colloidal nickel/gallium nanoalloys obtained from organometallic precursors in conventional organic solvents and in ionic liquids: noble-metal-free alkyne semihydrogenation catalysts

Nanoscale ◽  
2014 ◽  
Vol 6 (10) ◽  
pp. 5532-5544 ◽  
Author(s):  
Kai Schütte ◽  
Adinarayana Doddi ◽  
Clarissa Kroll ◽  
Hajo Meyer ◽  
Christian Wiktor ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Organic Solvents ◽  
Noble Metal ◽  
Recyclable Catalyst ◽  
Metal Free ◽  
Organometallic Precursors

The Hume-Rothery phase NiGa as nanoparticles in an ionic liquid is a recyclable catalyst for selective semihydrogenation with yields of about 90% and selectivities of up to 94%.

Recovery of lignin and ionic liquid by using organic solvents

2017 ◽  
Vol 49 ◽  
pp. 122-132 ◽  
Author(s):  
Piyarat Weerachanchai ◽  
Jong-Min Lee
Keyword(s):  
Ionic Liquid ◽  
Organic Solvents

Ionic liquid electrolytes for aluminium secondary battery: Influence of organic solvents

2015 ◽  
Vol 757 ◽  
pp. 167-175 ◽  
Author(s):  
Shuang Xia ◽  
Xiao-Min Zhang ◽  
Kuan Huang ◽  
Yong-Le Chen ◽  
You-Ting Wu
Keyword(s):  
Ionic Liquid ◽  
Organic Solvents ◽  
Secondary Battery ◽  
Liquid Electrolytes
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