scholarly journals Correction to “Stern Layer Structure and Energetics at Mica–Water Interfaces”

2019 ◽  
Vol 123 (4) ◽  
pp. 2690-2690
Author(s):  
Ian C. Bourg ◽  
Sang Soo Lee ◽  
Paul Fenter ◽  
Christophe Tournassat
Keyword(s):  
Layer Structure ◽  
Stern Layer

scholarly journals Divalent Ion-Specific Outcomes on Stern Layer Structure and Total Surface Potential at the Silica:Water Interface

2021 ◽  
Author(s):  
Emily Ma ◽  
Franz Geiger
Keyword(s):  
Layer Structure ◽  
Divalent Cations ◽  
Potential Drop ◽  
Fused Silica ◽  
Interfacial Structure ◽  
Nonlinear Susceptibility ◽  
Stern Layer ◽  
Phase Measurements ◽  
Total Potential ◽  
Interfacial Potential

The second-order nonlinear susceptibility, chi(2), in the Stern layer, and the total interfacial potential drop, Phi(0)tot, across the oxide:water interface are estimated from SHG amplitude and phase measurements for divalent cations (Mg2+, Ca2+, Sr2+, Ba2+) at the silica:water interface at pH 5.8 and various ionic strengths. We find that interfacial structure and total potential depend strongly on ion valency. We observe statistically significant differences between the experimentally determined chi(2) value for NaCl and that of the alkali earth series, but smaller differences between ions of the same valency in that series. These differences are particularly pronounced at intermediate salt concentrations, which we attribute to the influence of hydration structure in the Stern layer. Furthermore, we corroborate the differences by examining the effects of anion substitution (SO4 2- for Cl-). Finally, we identify that hysteresis in measuring the reversibility of ion adsorption and desorption at fused silica in forward and reverse titrations manifests itself both in Stern layer structure and in total interfacial potential for some of the salts, most notable CaCl2 and MgSO4, but less so for BaCl2 and NaCl.

scholarly journals Stern Layer Structure and Energetics at Mica–Water Interfaces

2017 ◽  
Vol 121 (17) ◽  
pp. 9402-9412 ◽  
Author(s):  
Ian C. Bourg ◽  
Sang Soo Lee ◽  
Paul Fenter ◽  
Christophe Tournassat
Keyword(s):  
Layer Structure ◽  
Stern Layer

Backscattered Electron Imaging of GaAs/AlGaAs Super Lattice Structures with an Ultra-High- Resolution SEM

1988 ◽  
Vol 46 ◽  
pp. 204-205
Author(s):  
Kazumichi Ogura ◽  
Michael M. Kersker
Keyword(s):  
High Resolution ◽  
Layer Structure ◽  
High Sensitivity ◽  
Beam Current ◽  
Electron Beam Current ◽  
Lattice Structures ◽  
Super Lattice ◽  
Different Types ◽  
Backscattered Electron ◽  
Electron Imaging

Backscattered electron (BE) images of GaAs/AlGaAs super lattice structures were observed with an ultra high resolution (UHR) SEM JSM-890 with an ultra high sensitivity BE detector. Three different types of super lattice structures of GaAs/AlGaAs were examined. Each GaAs/AlGaAs wafer was cleaved by a razor after it was heated for approximately 1 minute and its crosssectional plane was observed.First, a multi-layer structure of GaAs (100nm)/AlGaAs (lOOnm) where A1 content was successively changed from 0.4 to 0.03 was observed. Figures 1 (a) and (b) are BE images taken at an accelerating voltage of 15kV with an electron beam current of 20pA. Figure 1 (c) is a sketch of this multi-layer structure corresponding to the BE images. The various layers are clearly observed. The differences in A1 content between A1 0.35 Ga 0.65 As, A1 0.4 Ga 0.6 As, and A1 0.31 Ga 0.69 As were clearly observed in the contrast of the BE image.

Generation of 4H and 6H Structures During the Hexagonal-Rhombohedral Transformation in Dy2Co17

1975 ◽  
Vol 33 ◽  
pp. 38-39
Author(s):  
C. W. Allen ◽  
D. L. Kuruzar
Keyword(s):  
Elevated Temperatures ◽  
Layer Structure ◽  
Transition Element ◽  
Temperature Structure ◽  
Allotropic Transformation ◽  
Layer Plane ◽  
Planar Defects ◽  
Topologically Close Packed ◽  
Transformation Mechanisms ◽  
Shear Transformation

The rare earth/transition element intermetallics R2T17 are essentially topologically close packed phases for which layer structure models have already been presented. Many of these compounds are known to undergo allotropic transformation of the type at elevated temperatures. It is not unexpected that shear transformation mechanisms are involved in view of the layering character of the structures. The transformations are evidently quite sluggish, illustrated in furnace cooled Dy2Co17 by the fact that only rarely has the low temperature rhombohedral form been seen. The more usual structures observed so far in furnace cooled alloys include 4H and 6H in Dy2Co17 (Figs. 1 and 2) . In any event it is quite clear that the general microstructure is very complicated as a consequence of the allotropy, illustrated in Fig. 3. Numerous planar defects in the layer plane orientation are evident as are non-layer plane defects inherited from a high temperature structure.

КОНСТРУКТИВНО-ТЕХНОЛОГІЧНІ ОСОБЛИВОСТІ ХВОСТО-ВИХ БАЛОК СІТЧАСТОГО ТИПУ З ПОЛІМЕРНИХ КОМПО-ЗИЦІЙНИХ МАТЕРІАЛІВ ВЕРТОЛЬОТІВ ТРАНСПОРТНОЇ КАТЕГОРІЇ

2020 ◽  
pp. 15-30
Author(s):  
А. Г. Гребеников ◽  
И. В. Малков ◽  
В. А. Урбанович ◽  
Н. И. Москаленко ◽  
Д. С. Колодийчик
Keyword(s):  
Finite Element ◽  
Strain State ◽  
Layer Structure ◽  
Metal Structure ◽  
Element Model ◽  
Stress Strain ◽  
Element Analysis ◽  
Mesh Structure ◽  
Stress Strain State ◽  
Mesh Structures

The analysis of the design and technological features of the tail boom (ТB) of a helicopter made of polymer composite materials (PCM) is carried out.Three structural and technological concepts are distinguished - semi-monocoque (reinforced metal structure), monocoque (three-layer structure) and mesh-type structure. The high weight and economic efficiency of mesh structures is shown, which allows them to be used in aerospace engineering. The physicomechanical characteristics of the network structures are estimated and their uniqueness is shown. The use of mesh structures can reduce the weight of the product by a factor of two or more.The stress-strain state (SSS) of the proposed tail boom design is determined. The analysis of methods for calculating the characteristics of the total SSS of conical mesh shells is carried out. The design of the tail boom is presented, the design diagram of the tail boom of the transport category rotorcraft is developed. A finite element model was created using the Siemens NX 7.5 system. The calculation of the stress-strain state (SSS) of the HC of the helicopter was carried out on the basis of the developed structural scheme using the Advanced Simulation module of the Siemens NX 7.5 system. The main zones of probable fatigue failure of tail booms are determined. Finite Element Analysis (FEA) provides a theoretical basis for design decisions.Shown is the effect of the type of technological process selected for the production of the tail boom on the strength of the HB structure. The stability of the characteristics of the PCM tail boom largely depends on the extent to which its design is suitable for the use of mechanized and automated production processes.A method for the manufacture of a helicopter tail boom from PCM by the automated winding method is proposed. A variant of computer modeling of the tail boom of a mesh structure made of PCM is shown.The automated winding technology can be recommended for implementation in the design of the composite tail boom of the Mi-2 and Mi-8 helicopters.

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