Treatment of Ion-Size Asymmetry in Lattice-Gas Models for Electrical Double Layer

2018 ◽  
Vol 122 (50) ◽  
pp. 28652-28664 ◽  
Author(s):  
Yufan Zhang ◽  
Jun Huang
Keyword(s):  
Double Layer ◽  
Electrical Double Layer ◽  
Lattice Gas ◽  
Lattice Gas Models ◽  
Ion Size ◽  
Size Asymmetry

Monte Carlo simulations of the electrical double layer forces in the presence of divalent electrolyte solutions: effect of the ion size

Soft Matter ◽  
2011 ◽  
Vol 7 (4) ◽  
pp. 1441-1449 ◽  
Author(s):  
Alberto Martín-Molina ◽  
José Guadalupe Ibarra-Armenta ◽  
Enrique González-Tovar ◽  
Roque Hidalgo-Álvarez ◽  
Manuel Quesada-Pérez
Keyword(s):  
Monte Carlo ◽  
Monte Carlo Simulations ◽  
Double Layer ◽  
Electrical Double Layer ◽  
Electrolyte Solutions ◽  
Ion Size

scholarly journals Thickness of electrical double layer. Effect of ion size

2001 ◽  
Vol 46 (19) ◽  
pp. 3033-3040 ◽  
Author(s):  
Klemen Bohinc ◽  
Veronika Kralj-Iglič ◽  
Aleš Iglič
Keyword(s):  
Double Layer ◽  
Electrical Double Layer ◽  
Layer Effect ◽  
Ion Size

scholarly journals Lattice-gas models of adsorption in the double layer

1996 ◽  
Vol 41 (14) ◽  
pp. 2175-2184 ◽  
Author(s):  
P.A. Rikvold ◽  
J. Zhang ◽  
Y.-E. Sung ◽  
A. Wieckowski
Keyword(s):  
Double Layer ◽  
Lattice Gas ◽  
Lattice Gas Models

Adsorption and Condensation of Xanthine at the Mercury/Solution Interface

1998 ◽  
Vol 63 (12) ◽  
pp. 1977-1993 ◽  
Author(s):  
Viktor Dražan ◽  
Vladimír Vetterl
Keyword(s):  
Double Layer ◽  
Electrode Surface ◽  
Lattice Gas ◽  
Standard Gibbs Energy ◽  
Mercury Electrode ◽  
Ising Lattice ◽  
Compact Layer ◽  
Solution Interface ◽  
Double Layer Capacity ◽  
Lattice Gas Models

The adsorption and two-dimensional condensation of xanthine at the mercury electrode in 0.2 and 2 M NaCl was studied by electrode double layer capacity measurements. The condensation of xanthine molecules adsorbed at the electrode was observed at pH 6.0 and 7.4, but not at 9.0. The standard Gibbs energy of adsorption, energy of lateral interactions and the surface occupied by one xanthine molecule in a compact layer were calculated from the temperature dependence of the capacity pit using the Frumkin and Ising lattice gas models. The orientation of xanthine molecules in a compact layer at the electrode surface was estimated. At higher bulk concentrations of xanthine, the double layer capacity decreases to a very low value of about 1.5 mF cm-2, which might be an indication of the formation of a xanthine multilayer at the electrode surface.

Poisson–Boltzmann Description of the Electrical Double Layer Including Ion Size Effects

Langmuir ◽  
2011 ◽  
Vol 27 (23) ◽  
pp. 13970-13974 ◽  
Author(s):  
José Juan López-García ◽  
José Horno ◽  
Constantino Grosse
Keyword(s):  
Double Layer ◽  
Size Effects ◽  
Electrical Double Layer ◽  
Poisson Boltzmann ◽  
Ion Size

Theory of the electrical double layer: Ion size effects in a molecular solvent

1989 ◽  
Vol 91 (10) ◽  
pp. 6367-6375 ◽  
Author(s):  
G. M. Torrie ◽  
P. G. Kusalik ◽  
G. N. Patey
Keyword(s):  
Double Layer ◽  
Size Effects ◽  
Electrical Double Layer ◽  
Ion Size
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