Effect of Nanoparticle Shape on the Electrical and Thermal Properties of Solid Polymer Electrolytes

2019 ◽  
Vol 123 (17) ◽  
pp. 10720-10726 ◽  
Author(s):  
Sandhya Vasudevan ◽  
Susan K. Fullerton-Shirey
Keyword(s):  
Thermal Properties ◽  
Polymer Electrolytes ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Nanoparticle Shape

Effect of nanochitosan on electrochemical, interfacial and thermal properties of composite solid polymer electrolytes

Ionics ◽  
2012 ◽  
Vol 18 (8) ◽  
pp. 737-745 ◽  
Author(s):  
K. Karuppasamy ◽  
S. Thanikaikarasan ◽  
R. Antony ◽  
S. Balakumar ◽  
X. Sahaya Shajan
Keyword(s):  
Thermal Properties ◽  
Polymer Electrolytes ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Composite Solid

Influence of Fe2O3 Nanofiller Shape on the Conductivity and Thermal Properties of Solid Polymer Electrolytes: Nanorods versus Nanospheres

2012 ◽  
Vol 116 (40) ◽  
pp. 21216-21223 ◽  
Author(s):  
Nhu Suong T. Do ◽  
Dean M. Schaetzl ◽  
Barnali Dey ◽  
Alan C. Seabaugh ◽  
Susan K. Fullerton-Shirey
Keyword(s):  
Thermal Properties ◽  
Polymer Electrolytes ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer

Siloxane Diacrylate-based All-Solid Polymer Electrolytes for Lithium Batteries

2015 ◽  
Vol 2 (1) ◽  
pp. 23-27
Author(s):  
Jijeesh Nair ◽  
◽  
Matteo Destro ◽  
Claudio Gerbaldi ◽  
Federico Bella
Keyword(s):  
Lithium Batteries ◽  
Polymer Electrolytes ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer

Solid Polymer Electrolytes from Crosslinked PEG and Dilithium N,N'-Bis(trifluoromethanesulfonyl)perfluoroalkane-1,ω-disulfonamide and Lithium Bis(trifluoromethanesulfonyl)imide Salts

2008 ◽  
Vol 73 (12) ◽  
pp. 1777-1798 ◽  
Author(s):  
Olt E. Geiculescu ◽  
Rama V. Rajagopal ◽  
Emilia C. Mladin ◽  
Stephen E. Creager ◽  
Darryl D. Desmarteau
Keyword(s):  
Ionic Conductivity ◽  
Polymer Electrolytes ◽  
Minimum Energy ◽  
Ionic Conductivities ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Segmental Motion ◽  
Concentrated Electrolytes ◽  
Two Factors ◽  
Poly Ethylene

The present work consists of a series of studies with regard to the structure and charge transport in solid polymer electrolytes (SPE) prepared using various new bis(trifluoromethanesulfonyl)imide (TFSI)-based dianionic dilithium salts in crosslinked low-molecular-weight poly(ethylene glycol). Some of the thermal properties (glass transition temperature, differential molar heat capacity) and ionic conductivities were determined for both diluted (EO/Li = 30:1) and concentrated (EO/Li = 10:1) SPEs. Trends in ionic conductivity of the new SPEs with respect to anion structure revealed that while for the dilute electrolytes ionic conductivity is generally rising with increased length of the perfluoroalkylene linking group in the dianions, for the concentrated electrolytes the trend is reversed with respect to dianion length. This behavior could be the result of a combination of two factors: on one hand a decrease in dianion basicity that results in diminished ion pairing and an enhancement in the number of charge carriers with increasing fluorine anion content, thereby increasing ionic conductivity while on the other hand the increasing anion size and concentration produce an increase in the friction/entanglements of the polymeric segments which lowers even more the reduced segmental motion of the crosslinked polymer and decrease the dianion contribution to the overall ionic conductivity. DFT modeling of the same TFSI-based dianionic dilithium salts reveals that the reason for the trend observed is due to the variation in ion dissociation enthalpy, derived from minimum-energy structures, with respect to perfluoroalkylene chain length.

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