High-Temperature Ferroelastic Phase Transition in an Organic–Inorganic Hybrid: [(CH3)3NCH2Br]2–ZnBr4

2018 ◽  
Vol 122 (40) ◽  
pp. 23111-23116 ◽  
Author(s):  
Ji-Xing Gao ◽  
Xiu-Ni Hua ◽  
Peng-Fei Li ◽  
Xiao-Gang Chen ◽  
Wei-Qiang Liao
Keyword(s):  
Phase Transition ◽  
High Temperature ◽  
Inorganic Hybrid ◽  
Ferroelastic Phase Transition

A new ferroelastic hybrid material with a large spontaneous strain: (Me3NOH)2[ZnCl4]

2019 ◽  
Vol 55 (61) ◽  
pp. 8983-8986 ◽  
Author(s):  
Wei Yuan ◽  
Ying Zeng ◽  
Ya-Yin Tan ◽  
Jian-Hua Zhou ◽  
Wei-Jian Xu ◽  
...  
Keyword(s):  
Phase Transition ◽  
Hybrid Material ◽  
Spontaneous Strain ◽  
Inorganic Hybrid ◽  
Ferroelastic Phase Transition

A new organic–inorganic hybrid undergoes a ferroelastic phase transition at 351 K accompanied with a large spontaneous stain.

A high-temperature molecular ferroelastic phase transition and switchable dielectric response in the trimethylbromomethylammonium salt [C4H11NBr] [PF6]

2018 ◽  
Vol 42 (18) ◽  
pp. 14909-14913 ◽  
Author(s):  
Xiao-Gang Chen ◽  
Ji-Xing Gao ◽  
Xiu-Ni Hua ◽  
Wei-Qiang Liao
Keyword(s):  
Phase Transition ◽  
High Temperature ◽  
Dielectric Response ◽  
Ferroelastic Phase Transition

A new molecular ferroelastic compound [TMBMA] [PF6] was successfully synthesized, wherein the origin of the phase transition and dielectric anomalies is related to the order–disorder processes of the TMBMA cations.

An unprecedented hexagonal double perovskite organic-inorganic hybrid ferroelastic: (piperidinium)2[KBiCl6]

2021 ◽  
Author(s):  
Qian-Ru Meng ◽  
Wei-Jian Xu ◽  
Wang-Hua Hu ◽  
Hui Ye ◽  
Xiao-Xian Chen ◽  
...  
Keyword(s):  
Phase Transition ◽  
Double Perovskite ◽  
Type Structure ◽  
Spontaneous Strain ◽  
Inorganic Hybrid ◽  
Ferroelastic Phase Transition

An unprecedented A2MIMIIIX6-type double perovskite adopting a fully hexagonal BaNiO3-type structure, (piperidinium)2[KBiCl6], undergoes a 2/mF1̅ ferroelastic phase transition at 285 K with a spontaneous strain of 0.0615, arising from order-disorder...

scholarly journals High-temperature ferroelastic phase transition in a perovskite-like complex: [Et4N]2[PbBr3]2

RSC Advances ◽  
2019 ◽  
Vol 9 (18) ◽  
pp. 10364-10370 ◽  
Author(s):  
Yuan Huang ◽  
Jie Yang ◽  
Zi-jian Li ◽  
Kun Qian ◽  
Feng Sao
Keyword(s):  
Phase Transition ◽  
High Temperature ◽  
Crystal Structures ◽  
Dielectric Anomaly ◽  
Inorganic Complex ◽  
Ferroelastic Phase Transition ◽  
Lead Bromide

A new lead-bromide hybrid organic–inorganic complex [Et4N]2[PbBr3]2 (Et = ethyl) was synthesized, and its crystal structures could be described as a distorted perovskite-like one and a step-like dielectric anomaly was obtained at around 375/367 K.

scholarly journals A high-temperature organic–inorganic ferroelectric with outstanding switchable dielectric characteristics

RSC Advances ◽  
2017 ◽  
Vol 7 (76) ◽  
pp. 47933-47937 ◽  
Author(s):  
Cong Xu ◽  
Wenjun Zhang ◽  
Linsong Gao ◽  
Xuecheng Gan ◽  
Xiaofan Sun ◽  
...  
Keyword(s):  
Phase Transition ◽  
High Temperature ◽  
Ferroelectric Phase Transition ◽  
Ferroelectric Phase ◽  
Hybrid Compound ◽  
Dielectric Characteristics ◽  
Inorganic Hybrid ◽  
Compound C

A new molecular ferroelectric is discovered in an organic–inorganic hybrid compound, (C6H5NH3)2CdCl4, which undergoes a reversible order–disorder ferroelectric phase transition at 369 K.

A high-temperature halide perovskite molecular ferroelastic with evident dielectric switching

2021 ◽  
Author(s):  
Xiao-Qin Xu ◽  
Hua Zhang ◽  
Xue-Qin Huang ◽  
Yu-Ling Liu
Keyword(s):  
Phase Transition ◽  
High Temperature ◽  
Ferroelastic Phase Transition ◽  
Halide Perovskite

Under the quasi-spherical strategy, a hybrid halide perovskite (TMTB)CdCl3 is designed and synthesized and shows evident high-temperature ferroelastic phase transition and dielectric switching.

High-temperature structural phase transition coupled with dielectric switching in an organic–inorganic hybrid crystal: [NH3(CH2)2Br]3CdBr5

2017 ◽  
Vol 46 (14) ◽  
pp. 4711-4716 ◽  
Author(s):  
Hai-Peng Chen ◽  
Zhong-Xia Wang ◽  
Cheng Chen ◽  
Yang Lu ◽  
Zi Yin ◽  
...  
Keyword(s):  
Phase Transition ◽  
High Temperature ◽  
Structural Phase Transition ◽  
Structural Phase ◽  
Environmentally Friendly ◽  
Light Weight ◽  
Inorganic Hybrid ◽  
Intelligent Materials

Molecular bistable switches (electrical switches “ON” and “OFF”) represent a class of highly desirable intelligent materials due to their sensitive switchable responses, simple and environmentally friendly processing, light weight, and mechanical flexibility.

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