Kinetic Analysis of Overlapping Multistep Thermal Decomposition of 2,6-Diamino-3,5-dinitropyrazine-1-oxide (LLM-105)

2018 ◽  
Vol 122 (45) ◽  
pp. 25999-26006 ◽  
Author(s):  
Qian Yu ◽  
Yu Liu ◽  
Heliang Sui ◽  
Jie Sun ◽  
Jinshan Li
Keyword(s):  
Thermal Decomposition ◽  
Kinetic Analysis

scholarly journals Kinetic Analysis of the Thermal Decomposition of Iron(III) Phosphates: Fe(NH3)2PO4 and Fe(ND3)2PO4

2020 ◽  
Vol 21 (3) ◽  
pp. 781
Author(s):  
Isabel Iglesias ◽  
José A. Huidobro ◽  
Belén F. Alfonso ◽  
Camino Trobajo ◽  
Aránzazu Espina ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Kinetic Analysis ◽  
Room Temperature ◽  
Isoconversional Methods ◽  
Iron Phosphate ◽  
Dihydrogen Phosphate ◽  
Monoclinic System ◽  
Space Group ◽  
X Ray ◽  
Group A

The hydrothermal synthesis and both the chemical and structural characterization of a diamin iron phosphate are reported. A new synthetic route, by using n-butylammonium dihydrogen phosphate as a precursor, leads to the largest crystals described thus far for this compound. Its crystal structure is determined from single-crystal X-ray diffraction data. It crystallizes in the orthorhombic system (Pnma space group, a = 10.1116(2) Å, b = 6.3652(1) Å, c = 7.5691(1) Å, Z = 4) at room temperature and, below 220 K, changes towards the monoclinic system P21/n, space group. The in situ powder X-ray thermo-diffraction monitoring for the compound, between room temperature and 1100 K, is also included. Thermal analysis shows that the solid is stable up to ca. 440 K. The kinetic analysis of thermal decomposition (hydrogenated and deuterated forms) is performed by using the isoconversional methods of Vyazovkin and a modified version of Friedman. Similar values for the kinetic parameters are achieved by both methods and they are checked by comparing experimental and calculated conversion curves.

scholarly journals Erratum to: Kinetic Analysis of the Thermal Decomposition of Lowland and High-Moor Peats

2020 ◽  
Vol 54 (4) ◽  
pp. 251-251
Author(s):  
S. I. Islamova ◽  
S. S. Timofeeva ◽  
A. R. Khamatgalimov ◽  
D. V. Ermolaev
Keyword(s):  
Thermal Decomposition ◽  
Kinetic Analysis ◽  
High Moor

Isothermal kinetic analysis of the thermal decomposition of kaolinite: The thermogravimetric study

2010 ◽  
Vol 501 (1-2) ◽  
pp. 24-29 ◽  
Author(s):  
Petr Ptáček ◽  
Dana Kubátová ◽  
Jaromír Havlica ◽  
Jiří Brandštetr ◽  
František Šoukal ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Kinetic Analysis ◽  
Thermogravimetric Study ◽  
Isothermal Kinetic Analysis ◽  
Isothermal Kinetic

The non-isothermal kinetic analysis of the thermal decomposition of kaolinite by thermogravimetric analysis

2010 ◽  
Vol 204 (2-3) ◽  
pp. 222-227 ◽  
Author(s):  
Petr Ptáček ◽  
Dana Kubátová ◽  
Jaromír Havlica ◽  
Jiří Brandštetr ◽  
František Šoukal ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Thermogravimetric Analysis ◽  
Kinetic Analysis ◽  
Isothermal Kinetic Analysis ◽  
Isothermal Kinetic
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