Exciton Binding Energies of Nonfullerene Small Molecule Acceptors: Implication for Exciton Dissociation Driving Forces in Organic Solar Cells

2018 ◽  
Vol 122 (39) ◽  
pp. 22309-22316 ◽  
Author(s):  
Lingyun Zhu ◽  
Yuanping Yi ◽  
Zhixiang Wei
Keyword(s):  
Solar Cells ◽  
Small Molecule ◽  
Organic Solar Cells ◽  
Driving Forces ◽  
Binding Energies ◽  
Exciton Dissociation

Improving All Ternary Small-Molecule Organic Solar Cells by Optimizing Short Wavelength Photon Harvesting and Exciton Dissociation based on a Bisadduct analogue of [70]PCBM as a Third Component Materials

2022 ◽  
Author(s):  
Zhiyong Liu ◽  
Hong-En Wang
Keyword(s):  
Solar Cells ◽  
Small Molecule ◽  
Organic Solar Cells ◽  
Short Wavelength ◽  
Exciton Dissociation

Ternary small-molecule organic solar cells (OSCs) are efficiently optimized and fabricated with small-molecule benzodithiophene terthiophene rhodanine (BTR) as donors and blends of Y6 and bisPC71BM or PC71BM used as acceptors....

The Effect of Donor Molecular Structure on Power Conversion Efficiency of Small-Molecule-Based Organic Solar Cells

2019 ◽  
Vol 16 (3) ◽  
pp. 236-243 ◽  
Author(s):  
Hui Zhang ◽  
Yibing Ma ◽  
Youyi Sun ◽  
Jialei Liu ◽  
Yaqing Liu ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Small Molecule ◽  
Organic Solar Cells ◽  
Molecular Design ◽  
Power Conversion ◽  
The Relationship

In this review, small-molecule donors for application in organic solar cells reported in the last three years are highlighted. Especially, the effect of donor molecular structure on power conversion efficiency of organic solar cells is reported in detail. Furthermore, the mechanism is proposed and discussed for explaining the relationship between structure and power conversion efficiency. These results and discussions draw some rules for rational donor molecular design, which is very important for further improving the power conversion efficiency of organic solar cells based on the small-molecule donor.

Fullerene/Non-fullerene Alloy for High-Performance All-Small-Molecule Organic Solar Cells

2021 ◽  
Vol 13 (5) ◽  
pp. 6461-6469
Author(s):  
María Privado ◽  
Fernando G. Guijarro ◽  
Pilar de la Cruz ◽  
Rahul Singhal ◽  
Fernando Langa ◽  
...  
Keyword(s):  
Solar Cells ◽  
Small Molecule ◽  
Organic Solar Cells ◽  
High Performance

scholarly journals Recent progress in small‐molecule donors for non‐fullerene all‐small‐molecule organic solar cells

Nano Select ◽  
2021 ◽  
Author(s):  
Ze Zhang ◽  
Yaokun Wang ◽  
Chenkai Sun ◽  
Zitong Liu ◽  
Haiqiao Wang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Small Molecule ◽  
Organic Solar Cells ◽  
Recent Progress

Unraveling the Temperature Dependence of Exciton Dissociation and Free Charge Generation in Nonfullerene Organic Solar Cells

Solar RRL ◽  
2021 ◽  
Vol 5 (4) ◽  
pp. 2000789
Author(s):  
Chao Ma ◽  
Christopher C. S. Chan ◽  
Xinhui Zou ◽  
Han Yu ◽  
Jianquan Zhang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Temperature Dependence ◽  
Organic Solar Cells ◽  
Free Charge ◽  
Exciton Dissociation ◽  
Charge Generation

scholarly journals The Effects of Molecular Packing Behavior of Small-Molecule Acceptors in Ternary Organic Solar Cells

2021 ◽  
Vol 11 (2) ◽  
pp. 755
Author(s):  
Eunhee Lim
Keyword(s):  
Solar Cells ◽  
Energy Level ◽  
Ternary System ◽  
Small Molecule ◽  
Organic Solar Cells ◽  
Orbital Energy ◽  
Working Mechanism ◽  
Energy Level Structure ◽  
The Third ◽  
Molecular Backbone

Herein, two diketopyrrolopyrrole (DPP)-based, small-molecule isomers, o- and p-DPP-PhCN, were introduced as acceptors in ternary organic solar cells (OSCs). The isomers have the same molecular backbone but differ in the positions of the cyanide (CN) substituents (ortho and para), which greatly affects their packing behavior. Ternary solar cells composed of poly(3-hexylthiophene) (P3HT):DPP-PhCN:phenyl-C61-butyric acid methyl ester (PCBM) were fabricated, and the effects of the different packing behaviors of the third component on the device performance and the working mechanism of the ternary cells were investigated. The addition of o-DPP-PhCN with a relatively high-lying lowest unoccupied molecular orbital energy level resulted in an increase in the open-circuit voltage (VOC) in the ternary devices, demonstrating the alloy-like structure of the two acceptors (o-DPP-PhCN and PCBM) in the ternary system. However, the p-DPP-PhCN-based ternary cells exhibited VOC values similar to that of a P3HT:PCBM binary cell, irrespective of the addition of p-DPP-PhCN, indicating a cascade energy-level structure in the ternary system and an effective charge transfer from the P3HT to the PCBM. Importantly, by increasing the addition of p-DPP-PhCN, the short-circuit current density increased substantially, resulting in pronounced shoulder peaks in the external quantum efficiency responses in the long-wavelength region, corresponding to the contribution of the photocurrent generated by the light absorption of p-DPP-PhCN. Despite sharing the same molecular backbone, the two DPP-PhCNs exhibited substantially different packing behaviors according to the position of their CN substituents, which also greatly affected the working mechanism of the ternary devices fabricated using the DPP-PhCNs as the third component.

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