Effective Impact of Dielectric Constant on Thermally Activated Delayed Fluorescence and Nonlinear Optical Properties: Through-Bond/-Space Charge Transfer Architectures

2018 ◽  
Vol 122 (33) ◽  
pp. 18850-18859 ◽  
Author(s):  
Jin-Ting Ye ◽  
Li Wang ◽  
Hong-Qiang Wang ◽  
Xiu-Mei Pan ◽  
Hai-Ming Xie ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Optical Properties ◽  
Charge Transfer ◽  
Space Charge ◽  
Nonlinear Optical ◽  
Delayed Fluorescence ◽  
Nonlinear Optical Properties ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated

The Inspiration and Challenge for Through-Space Charge Transfer Architecture: From Thermally Activated Delayed Fluorescence to Nonlinear Optical Properties

2021 ◽  
Author(s):  
Jin-Ting Ye ◽  
Yongqing Qiu
Keyword(s):  
Optical Properties ◽  
Charge Transfer ◽  
Space Charge ◽  
Electron Acceptor ◽  
Nonlinear Optical ◽  
Organic Molecules ◽  
Building Blocks ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated

Organic molecules consisting of electron donor (D) and electron acceptor (A) subunits linked by π-conjugated bridge are promising building blocks for the thermally activated delayed fluorescence (TADF) and nonlinear optical...

scholarly journals Through-space charge transfer hexaarylbenzene dendrimers with thermally activated delayed fluorescence and aggregation-induced emission for efficient solution-processed OLEDs

2019 ◽  
Vol 10 (10) ◽  
pp. 2915-2923 ◽  
Author(s):  
Xingdong Wang ◽  
Shumeng Wang ◽  
Jianhong Lv ◽  
Shiyang Shao ◽  
Lixiang Wang ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Space Charge ◽  
Efficient Solution ◽  
Delayed Fluorescence ◽  
Electron Donors ◽  
Solution Processed ◽  
Thermally Activated Delayed Fluorescence ◽  
Aggregation Induced Emission ◽  
Thermally Activated

Through-space charge transfer hexaarylbenzene dendrimers containing circularly-arrayed electron donors and acceptors exhibit thermally activated delayed fluorescence and aggregation-induced emission effects, giving EQE of 14.2% for solution-processed OLEDs.

The Second-Order NLO and TADF Properties of Donor−Acceptor Dihydropyrene – Cyclophanediene System: the Impact of Molecular Architectures and Polarizable Environment

2021 ◽  
Author(s):  
yao Yao ◽  
Hongliang Xu ◽  
Zhong-Min Su
Keyword(s):  
Optical Properties ◽  
Nonlinear Optical ◽  
Delayed Fluorescence ◽  
Second Order ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Donor Acceptor ◽  
Molecular Architectures ◽  
The Impact

The electro-optical properties (nonlinear optical (NLO) and thermally activated delayed fluorescence (TADF) properties) of negative T-type dihydropyrene (DHP)-cyclophanediene (CPD) photoswitch were studied systematically in this work. An interesting “seesaw” phenomenon...

Through-Space Charge Transfer Dendrimers Employing Oxygen-Bridged Triarylboron Acceptors for Efficient Deep-Blue Electroluminescence

2021 ◽  
Author(s):  
Baoyun Du ◽  
Xingdong Wang ◽  
Fan Chen ◽  
Qingqing Yang ◽  
Shiyang Shao ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Space Charge ◽  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
State Of The Art ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Deep Blue

Though-space charge transfer dendrimers consisting of dendritic triacridan donors and oxygen-bridged triarylboron acceptors are demonstrated to exhibit deep-blue thermally activated delayed fluorescence with state-of-the-art external quantum efficiency of 14.6% for...

scholarly journals Intramolecular Through-Space Charge-Transfer Emitters Featuring Thermally Activated Delayed Fluorescence for High-Efficiency Electroluminescent Devices

2021 ◽  
Author(s):  
Yongjun song ◽  
lei he ◽  
Mingxing Tian ◽  
Renyou Yu
Keyword(s):  
Charge Transfer ◽  
Space Charge ◽  
High Efficiency ◽  
Theoretical Calculations ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Light Emitting ◽  
Thermally Activated ◽  
Donor Acceptor ◽  
First Time

Through-space charge-transfer (TSCT) emitters have been extensively explored for thermally activated delayed fluorescence (TADF), but arranging various donors and acceptors into rigid cofacial conformations for various efficient TSCT TADF emitters has still remained a challenge. Here we report for the first time a “fixing acceptor” design to reach various efficient TSCT TADF emitters. By chemically fixing the acceptor (benzophenone) with a rigid spiro structure and cofacially aligning various donors with the fixed acceptor, a series of efficient TSCT TADF emitters have been developed. Single-crystal structures and theoretical calculations have verified closely-packed cofacial donor/acceptor conformations and favorable TSCT in the emitters. The emitters afford sky-blue to yellow TADF emission in doped films, with high photoluminescent efficiencies of up to 0.92 and reverse intersystem crossing rates of up to 1.0×106 s−1. Organic light-emitting diodes using the emitters afford sky-blue to yellow electroluminescence with high external quantum efficiencies of up to 20.9%. The work opens a new avenue toward a wide variety of efficient TSCT TADF emitters.

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