scholarly journals In Situ Formation of TiB2 Nanoparticles for Enhanced Dehydrogenation/Hydrogenation Reaction Kinetics of LiBH4–MgH2 as a Reversible Solid-State Hydrogen Storage Composite System

2018 ◽  
Vol 122 (22) ◽  
pp. 11671-11681 ◽  
Author(s):  
Fahim Karimi ◽  
María V. C. Riglos ◽  
Antonio Santoru ◽  
Armin Hoell ◽  
Vikram S. Raghuwanshi ◽  
...  
Keyword(s):  
Solid State ◽  
Hydrogen Storage ◽  
Reaction Kinetics ◽  
Composite System ◽  
Hydrogenation Reaction ◽  
In Situ Formation ◽  
Kinetics Of

In-situ formation of LiF-rich composite interlayer for dendrite-free all-solid-state lithium batteries

2021 ◽  
Vol 411 ◽  
pp. 128534
Author(s):  
Jianli Wang ◽  
Zhao Zhang ◽  
Hangjun Ying ◽  
Gaorong Han ◽  
Wei-Qiang Han
Keyword(s):  
Solid State ◽  
Lithium Batteries ◽  
In Situ Formation

Catalytic effect of in situ formed Mg2Ni and REH (RE: Ce and Y) on thermodynamics and kinetics of Mg-RE-Ni hydrogen storage alloy

2020 ◽  
Vol 157 ◽  
pp. 828-839 ◽  
Author(s):  
Hui Yong ◽  
Shihai Guo ◽  
Zeming Yuan ◽  
Yan Qi ◽  
Dongliang Zhao ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Catalytic Effect ◽  
Hydrogen Storage Alloy ◽  
Thermodynamics And Kinetics ◽  
Kinetics Of

Structural analysis of calcium reactive hydride composite for solid state hydrogen storage

2014 ◽  
Vol 47 (1) ◽  
pp. 67-75 ◽  
Author(s):  
Fahim Karimi ◽  
P. Klaus Pranzas ◽  
Armin Hoell ◽  
Ulla Vainio ◽  
Edmund Welter ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Composite System ◽  
Structural Investigation ◽  
Sorption Kinetics ◽  
Hydrogen Storage Material ◽  
X Ray ◽  
X Ray Scattering ◽  
Diffusion Paths ◽  
X Ray Absorption ◽  
Kinetics Of

Owing to a theoretical hydrogen storage capacity of 10.5 wt% H2, Ca(BH4)2+MgH2, the so-called calcium reactive hydride composite (Ca-RHC), has a great potential as a hydrogen storage material. However, its dehydrogenation temperature (∼623 K) is too high for any mobile applications. By addition of 10 mol% of NbF5into Ca(BH4)2+MgH2, a decrease of the dehydrogenation onset temperature by ∼120 K is observed. In order to understand the reasons behind this desorption temperature decrement two sets of samples [Ca(BH4)2+MgH2and Ca(BH4)2+MgH2+0.1NbF5] in different hydrogenation states, were prepared. The structural investigation of the above mentioned sets of samples by means of volumetric measurements, anomalous small-angle X-ray scattering (ASAXS) and X-ray absorption spectroscopy (XAS) is reported here. The XAS results show that after the milling procedure NbB2is formed and remains stable upon further de/rehydrogenation cycling. The results of Nb ASAXS point to nanometric spherical NbB2particles distributed in the hydride matrix, with a mean diameter of ∼10 nm. Results from Ca ASAXS indicate Ca-containing nanostructures in the Ca-RHC+0.1NbF5samples to be ∼50% finer compared to those without additive. Thus, a higher reaction surface area and shorter diffusion paths for the constituents are concluded to be important contributions to the catalytic effect of an NbF5additive on the hydrogen sorption kinetics of the Ca(BH4)2+MgH2composite system.

In Situ Formation of a Stable Interface in Solid-State Batteries

2019 ◽  
Vol 4 (7) ◽  
pp. 1650-1657 ◽  
Author(s):  
Lilu Liu ◽  
Xingguo Qi ◽  
Shijun Yin ◽  
Qiangqiang Zhang ◽  
Xiaozhi Liu ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Batteries ◽  
In Situ Formation

scholarly journals Reaction kinetics of organo-clay hybrid films: In-situ IRRAS, FIM and AFM studies

2010 ◽  
Vol 71 (3) ◽  
pp. 323-328 ◽  
Author(s):  
Syed Arshad Hussain ◽  
Md N. Islam ◽  
D. Bhattacharjee
Keyword(s):  
Reaction Kinetics ◽  
Hybrid Films ◽  
Organo Clay ◽  
Kinetics Of
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