Core–Shell Fe–Pt Nanoparticles in Ionic Liquids: Magnetic and Catalytic Properties

2018 ◽  
Vol 122 (8) ◽  
pp. 4641-4650 ◽  
Author(s):  
Janice Adamski ◽  
Muhammad I. Qadir ◽  
Jilder P. Serna ◽  
Fabiano Bernardi ◽  
Daniel L. Baptista ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Catalytic Properties ◽  
Pt Nanoparticles ◽  
Core Shell

scholarly journals Single-Step Green Synthesis of Highly Concentrated and Stable Colloidal Dispersion of Core-Shell Silver Nanoparticles and Their Antimicrobial and Ultra-High Catalytic Properties

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 1007
Author(s):  
Azam Ali ◽  
Mariyam Sattar ◽  
Fiaz Hussain ◽  
Muhammad Humble Khalid Tareen ◽  
Jiri Militky ◽  
...  
Keyword(s):  
Silver Nanoparticles ◽  
Green Synthesis ◽  
Tannic Acid ◽  
Rate Constant ◽  
Catalytic Properties ◽  
Colloidal Dispersion ◽  
Alkaline Condition ◽  
Core Shell ◽  
Average Particle ◽  
Ag Nps

The versatile one-pot green synthesis of a highly concentrated and stable colloidal dispersion of silver nanoparticles (Ag NPs) was carried out using the self-assembled tannic acid without using any other hazardous chemicals. Tannic acid (Plant-based polyphenol) was used as a reducing and stabilizing agent for silver nitrate in a mild alkaline condition. The synthesized Ag NPs were characterized for their concentration, capping, size distribution, and shape. The experimental results confirmed the successful synthesis of nearly spherical and highly concentrated (2281 ppm) Ag NPs, capped with poly-tannic acid (Ag NPs-PTA). The average particle size of Ag NPs-PTA was found to be 9.90 ± 1.60 nm. The colloidal dispersion of synthesized nanoparticles was observed to be stable for more than 15 months in the ambient environment (25 °C, 65% relative humidity). The synthesized AgNPs-PTA showed an effective antimicrobial activity against Staphylococcus Aureus (ZOI 3.0 mM) and Escherichia coli (ZOI 3.5 mM). Ag NPs-PTA also exhibited enhanced catalytic properties. It reduces 4-nitrophenol into 4-aminophenol in the presence of NaBH4 with a normalized rate constant (Knor = K/m) of 615.04 mL·s−1·mg−1. For comparison, bare Ag NPs show catalytic activity with a normalized rate constant of 139.78 mL·s−1·mg−1. Furthermore, AgNPs-PTA were stable for more than 15 months under ambient conditions. The ultra-high catalytic and good antimicrobial properties can be attributed to the fine size and good aqueous stability of Ag NPs-PTA. The unique core-shell structure and ease of synthesis render the synthesized nanoparticles superior to others, with potential for large-scale applications, especially in the field of catalysis and medical.

PtPd nanoframes derived from Pd@PdPt core–shell rhombic dodecahedrals with excellent catalytic performance toward methanol oxidation

2021 ◽  
Author(s):  
Yangyang Ren ◽  
Chuanliang Li ◽  
Baosong Li ◽  
Fan Gao ◽  
Xinghua Zhang ◽  
...  
Keyword(s):  
Methanol Oxidation ◽  
Catalytic Properties ◽  
Catalytic Performance ◽  
Core Shell ◽  
Acid Environment ◽  
Excellent Catalytic Performance

PtPd nanoframes with excellent catalytic properties were obtained by etching Pd@PdPt core–shell RDs with Fe3+ in an acid environment.

Controlled deposition of Pt nanoparticles on Fe3O4@carbon microspheres for efficient oxidation of 5-hydroxymethylfurfural

RSC Advances ◽  
2016 ◽  
Vol 6 (56) ◽  
pp. 51229-51237 ◽  
Author(s):  
Yuwei Zhang ◽  
Zhimin Xue ◽  
Jinfang Wang ◽  
Xinhui Zhao ◽  
Yonghui Deng ◽  
...  
Keyword(s):  
Pt Nanoparticles ◽  
Core Shell ◽  
Carbon Microspheres ◽  
Spherical Morphology ◽  
Recyclable Catalysts ◽  
Controlled Deposition

We report core/shell structured magnetically recyclable catalysts with a well-defined spherical morphology. Using these as catalysts for the oxidation of HMF, a 100% yield of FDCA could be achieved in just 4 h at 90 °C in water .

Tetracarboxyl-Functionalized Ionic Liquid: Synthesis and Catalytic Properties

2015 ◽  
Vol 68 (10) ◽  
pp. 1513 ◽  
Author(s):  
Miaona Feng ◽  
Guoying Zhao ◽  
Hongling Gao ◽  
Suojiang Zhang
Keyword(s):  
Ionic Liquid ◽  
Catalytic Activity ◽  
Ionic Liquids ◽  
Propionic Acid ◽  
Propylene Carbonate ◽  
Propylene Oxide ◽  
High Stability ◽  
Ammonium Acetate ◽  
Catalytic Properties ◽  
Potential Applications

Novel tetracarboxyl-functionalized 2,2′-biimidazolium-based ionic liquids (ILs) with different anions were synthesized in two steps from readily available and sustainable starting materials including ammonium acetate, glyoxal, and halogenated propionic acid. The functionalized IL exhibited higher catalytic activity towards the cycloaddition of CO2 to terminal epoxides. With propylene oxide as a substrate, the optimum yield of propylene carbonate reached 82.7 % at an initial CO2 pressure of 2.0 MPa for 4 h at 140°C. Moreover, the functionalized IL catalyst displayed a high stability and can be reused for at least five cycles without obvious loss of catalytic activity. The results provide a simple and economical way to synthesize multi-functionalized imidazolium-based ILs with versatile potential applications.

Controllable fabrication of a N and B co-doped carbon shell on the surface of TiO2 as a support for boosting the electrochemical performances

2017 ◽  
Vol 5 (4) ◽  
pp. 1672-1678 ◽  
Author(s):  
Ying Chang ◽  
Conghui Yuan ◽  
Yuntong Li ◽  
Cheng Liu ◽  
Tong Wu ◽  
...  
Keyword(s):  
Shell Thickness ◽  
Pt Nanoparticles ◽  
Carbon Shell ◽  
Core Shell ◽  
Electrochemical Performances ◽  
Carbon Core ◽  
Controllable Fabrication ◽  
Co Doped

Pt nanoparticles loaded on TiO2@N,B co-doped carbon core–shell supports with tunable shell thickness possess enhanced electrochemical performances.

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