Influence of Precursor Functional Groups on the Formation and Performance of Iron-Coordinating Ordered Mesoporous Carbons as Fuel Cell Catalysts

2017 ◽  
Vol 121 (40) ◽  
pp. 21827-21835 ◽  
Author(s):  
C. Janson ◽  
A. E. C. Palmqvist
Keyword(s):  
Fuel Cell ◽  
Functional Groups ◽  
Mesoporous Carbons ◽  
Ordered Mesoporous Carbons ◽  
Ordered Mesoporous ◽  
Fuel Cell Catalysts ◽  
And Performance

Transition Metal Ion-Chelating Ordered Mesoporous Carbons as Noble Metal-Free Fuel Cell Catalysts

2013 ◽  
Vol 25 (6) ◽  
pp. 856-861 ◽  
Author(s):  
Johanna K. Dombrovskis ◽  
Hu Y. Jeong ◽  
Kjell Fossum ◽  
Osamu Terasaki ◽  
Anders E. C. Palmqvist
Keyword(s):  
Fuel Cell ◽  
Transition Metal ◽  
Noble Metal ◽  
Metal Ion ◽  
Mesoporous Carbons ◽  
Transition Metal Ion ◽  
Ordered Mesoporous Carbons ◽  
Metal Free ◽  
Ordered Mesoporous ◽  
Fuel Cell Catalysts

Universal and Versatile Route for Selective Covalent Tethering of Single-Site Catalysts and Functional Groups on the Surface of Ordered Mesoporous Carbons

2014 ◽  
Vol 26 (9) ◽  
pp. 2873-2882 ◽  
Author(s):  
Madhura Joglekar ◽  
Svitlana Pylypenko ◽  
Megan M. Otting ◽  
Justin S. Valenstein ◽  
Brian G. Trewyn
Keyword(s):  
Functional Groups ◽  
Single Site ◽  
Mesoporous Carbons ◽  
Ordered Mesoporous Carbons ◽  
Ordered Mesoporous ◽  
Single Site Catalysts

scholarly journals Design of Paracetamol Delivery Systems Based on Functionalized Ordered Mesoporous Carbons

Materials ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4151 ◽  
Author(s):  
Joanna Goscianska ◽  
Aleksander Ejsmont ◽  
Anna Olejnik ◽  
Dominika Ludowicz ◽  
Anna Stasiłowicz ◽  
...  
Keyword(s):  
Functional Groups ◽  
Adsorption Kinetics ◽  
Release Rate ◽  
Carbon Materials ◽  
Delivery Systems ◽  
Hexagonal Structure ◽  
Mesoporous Carbons ◽  
Ordered Mesoporous Carbons ◽  
Ordered Mesoporous ◽  
Pseudo Second Order

The oxidized ordered mesoporous carbons of cubic and hexagonal structure obtained by two templating methods (soft and hard) were applied for the first time as delivery systems for paracetamol—the most common antipyretic and analgesic drug in the world. The process of carbon oxidation was performed using an acidic ammonium persulfate solution at 60 °C for 6 h. The functionalization was found to reduce the specific surface area and pore volume of carbon materials, but it also led to an increasing number of acidic oxygen-containing functional groups. The most important element and the novelty of the presented study was the evaluation of adsorption and release ability of carbon carriers towards paracetamol. It was revealed that the sorption capacity and the drug release rate were mainly affected by the materials’ textural parameters and the total amount of surface functional groups, notably different in pristine and oxidized samples. The adsorption of paracetamol on the surface of ordered mesoporous carbons occurred according to different mechanisms: donor–acceptor complexes and hydrogen bond formation. The adsorption kinetics was assessed using pseudo-first- and pseudo-second-order models. The regression results indicated that the adsorption kinetics was more accurately represented by the pseudo-second-order model. Paracetamol was adsorbed onto the carbon materials studied following the Langmuir type isotherm. The presence of oxygen-containing functional groups on the surface of ordered mesoporous carbons enhanced the amount of paracetamol adsorbed and its release rate. The optimal drug loading capacity and expected release pattern exhibited oxidized ordered mesoporous carbon with a hexagonal structure obtained by the hard template method.

scholarly journals Nitrogen-doped carbon materials with cubic ordered mesostructure: low-temperature autoclaving synthesis for electrochemical supercapacitor and CO2 capture

RSC Advances ◽  
2017 ◽  
Vol 7 (21) ◽  
pp. 12524-12533 ◽  
Author(s):  
Lei Liu ◽  
Shi-Da Xu ◽  
Feng-Yun Wang ◽  
Yue-Jun Song ◽  
Jie Liu ◽  
...  
Keyword(s):  
Low Temperature ◽  
Co2 Capture ◽  
Carbon Materials ◽  
Mesoporous Carbons ◽  
Body Centered Cubic ◽  
Ordered Mesoporous Carbons ◽  
Nitrogen Doped ◽  
Electrochemical Supercapacitor ◽  
Ordered Mesoporous ◽  
Nitrogen Doped Carbon

Nitrogen doped ordered mesoporous carbons with a 3-D body-centered cubic pore structure have been synthesized by means of a low-temperature autoclaving route under basic conditions, showing excellent performances for supercapacitors and CO2 capture.

A comparative study of ordered mesoporous carbons with different pore structures as anode materials for lithium-ion batteries

RSC Advances ◽  
2015 ◽  
Vol 5 (53) ◽  
pp. 42922-42930 ◽  
Author(s):  
Diganta Saikia ◽  
Tzu-Hua Wang ◽  
Chieh-Ju Chou ◽  
Jason Fang ◽  
Li-Duan Tsai ◽  
...  
Keyword(s):  
Comparative Study ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Cycling Stability ◽  
Mesoporous Carbons ◽  
Ordered Mesoporous Carbons ◽  
Ordered Mesoporous

Ordered mesoporous carbons CMK-3 and CMK-8 with different mesostructures are evaluated as anode materials for lithium-ion batteries. CMK-8 possesses higher reversible capacity, better cycling stability and rate capability than CMK-3.

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