Characteristic Features of CO2 and CO Adsorptions to Paddle-Wheel-type Porous Coordination Polymer

2017 ◽  
Vol 121 (35) ◽  
pp. 19129-19139 ◽  
Author(s):  
Jia-Jia Zheng ◽  
Shinpei Kusaka ◽  
Ryotaro Matsuda ◽  
Susumu Kitagawa ◽  
Shigeyoshi Sakaki
Keyword(s):  
Coordination Polymer ◽  
Paddle Wheel ◽  
Porous Coordination Polymer ◽  
Characteristic Features

scholarly journals A catalytically active porous coordination polymer based on a dinuclear rhodium paddle-wheel unit

2014 ◽  
Vol 2 (1) ◽  
pp. 144-148 ◽  
Author(s):  
Georg Nickerl ◽  
Ulrich Stoeck ◽  
Ulrich Burkhardt ◽  
Irena Senkovska ◽  
Stefan Kaskel
Keyword(s):  
Coordination Polymer ◽  
Paddle Wheel ◽  
Catalytically Active ◽  
Porous Coordination Polymer

Guest exchange dynamics in a flexible bilayer porous coordination polymer

2012 ◽  
Vol 16 ◽  
pp. 65-69 ◽  
Author(s):  
Shuyun Wang ◽  
Jingxin Ma ◽  
Lina Li ◽  
Tianliang Chen ◽  
Zhihua Sun ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Porous Coordination Polymer

scholarly journals Crystal structure ofcatena-poly[hemi[1,3-bis(2,6-diisopropylphenyl)imidazolium] [[μ3-acetato-κ3O:O:O′-tri-μ2-acetato-κ6O:O′-dicopper(II)(Cu—Cu)]-μ-chlorido] dichloromethane sesquisolvate]

2015 ◽  
Vol 71 (8) ◽  
pp. m148-m149
Author(s):  
Mohammad Iqbal ◽  
James Raftery ◽  
Peter Quayle
Keyword(s):  
Coordination Polymer ◽  
Rotation Axis ◽  
Metal Organic Framework ◽  
Solvent Molecule ◽  
Central Metal ◽  
Imidazolium Cation ◽  
One Dimensional ◽  
Paddle Wheel ◽  
Internuclear Axis ◽  
Solvent Molecules

The title copper(II) complex, {(C27H37N2)[Cu4(CH3COO)8Cl]·3CH2Cl2}n, is a one-dimensional coordination polymer. The asymmetric unit is composed of a copper(II) tetraacetate paddle-wheel complex, a Cl−anion situated on a twofold rotation axis, half a 1,3-bis(2,6-diisopropylphenyl)imidazolium cation (the whole molecule being generated by twofold rotation symmetry) and one and a half of a dichloromethane solvent molecule (one being located about a twofold rotation axis). The central metal-organic framework comprises of a tetranuclear copper(II) acetate `paddle-wheel' complex which arises from the dimerization of the copper(II) tetraacetate core comprising of three μ2-bidentate acetate and one μ3-tridentate acetate ligands per binuclear paddle-wheel complex. Both CuIIatoms of the binuclear component adopt a distorted square-pyramidal coordination geometry (τ = 0.04), with a Cu...Cu separation of 2.6016 (2) Å. The apical coordination site of one CuIIatom is occupied by an O atom of a neighbouring acetate bridge [Cu—O = 2.200 (2) Å], while that of the second CuIIatom is occupied by a bridging chloride ligand [Cu...Cl = 2.4364 (4) Å]. The chloride bridge is slightly bent with respect to the Cu...Cu internuclear axis [Cu—Cl—Cu = 167.06 (6)°] and the tetranuclear units are located about a twofold rotation axis, forming the one-dimensional polymer that propagates along [101]. Charge neutrality is maintained by the inclusion of the 1,3-bis(2,6-diisopropylphenyl)imidazolium cation within the crystal lattice. In the crystal, the cation and dichloromethane solvent molecules are linked to the coordination polymer by various C—H...O and C—H...Cl hydrogen bonds. There are no other significant intermolecular interactions present.

Metallic and bimetallic nanocatalysts incorporated into highly porous coordination polymer MIL-101

2009 ◽  
Vol 19 (41) ◽  
pp. 7625 ◽  
Author(s):  
M. Samy El-Shall ◽  
Victor Abdelsayed ◽  
Abd El Rahman S. Khder ◽  
Hassan M. A. Hassan ◽  
Hani M. El-Kaderi ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Porous Coordination Polymer ◽  
Bimetallic Nanocatalysts ◽  
Highly Porous

scholarly journals Recognition of 1,3-Butadiene by a Porous Coordination Polymer

2016 ◽  
Vol 128 (44) ◽  
pp. 13988-13992 ◽  
Author(s):  
Keisuke Kishida ◽  
Yoshikuni Okumura ◽  
Yoshihiro Watanabe ◽  
Megumi Mukoyoshi ◽  
Silvia Bracco ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Porous Coordination Polymer

Coordinatively Immobilized Monolayers on Porous Coordination Polymer Crystals

2010 ◽  
Vol 122 (31) ◽  
pp. 5455-5458 ◽  
Author(s):  
Mio Kondo ◽  
Shuhei Furukawa ◽  
Kenji Hirai ◽  
Susumu Kitagawa
Keyword(s):  
Coordination Polymer ◽  
Polymer Crystals ◽  
Porous Coordination Polymer

An Adsorbate Discriminatory Gate Effect in a Flexible Porous Coordination Polymer for Selective Adsorption of CO2 over C2H2

2016 ◽  
Vol 138 (9) ◽  
pp. 3022-3030 ◽  
Author(s):  
Maw Lin Foo ◽  
Ryotaro Matsuda ◽  
Yuh Hijikata ◽  
Rajamani Krishna ◽  
Hiroshi Sato ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Selective Adsorption ◽  
Gate Effect ◽  
Porous Coordination Polymer ◽  
Adsorption Of Co2
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