Insight into Electron-Donating Ancillary Ligands in Ruthenium Terpyridyl Complexes Configuration on Performances of Dye-Sensitized Solar Cells

2017 ◽  
Vol 121 (16) ◽  
pp. 8752-8759 ◽  
Author(s):  
Wang-Chao Chen ◽  
Fan-Tai Kong ◽  
Rahim Ghadari ◽  
Zhao-Qian Li ◽  
Xue-Peng Liu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Ancillary Ligands ◽  
Dye Sensitized ◽  
Sensitized Solar Cells ◽  
Insight Into

Zn2SnO4-Based Dye-Sensitized Solar Cells: Insight into Dye-Selectivity and Photoelectric Behaviors

2014 ◽  
Vol 135 ◽  
pp. 242-248 ◽  
Author(s):  
Kai Wang ◽  
Yantao Shi ◽  
Wei Guo ◽  
Xiaoqiang Yu ◽  
Tingli Ma
Keyword(s):  
Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized ◽  
Sensitized Solar Cells ◽  
Insight Into

Influence of Ancillary Ligands in Dye-Sensitized Solar Cells

2016 ◽  
Vol 116 (16) ◽  
pp. 9485-9564 ◽  
Author(s):  
Babak Pashaei ◽  
Hashem Shahroosvand ◽  
Michael Graetzel ◽  
Mohammad Khaja Nazeeruddin
Keyword(s):  
Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Ancillary Ligands ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

scholarly journals Insight into the liquid state of organo-lead halide perovskites and their new roles in dye-sensitized solar cells

2014 ◽  
Vol 2 (27) ◽  
pp. 10355 ◽  
Author(s):  
Qiong Wang ◽  
Jung-Ho Yun ◽  
Meng Zhang ◽  
Hongjun Chen ◽  
Zhi-Gang Chen ◽  
...  
Keyword(s):  
Solar Cells ◽  
Liquid State ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized ◽  
Halide Perovskites ◽  
Sensitized Solar Cells ◽  
Lead Halide ◽  
Insight Into

scholarly journals Theoretical Insight into the Spectral Characteristics of Fe(II)-Based Complexes for Dye-Sensitized Solar Cells—Part I: Polypyridyl Ancillary Ligands

2011 ◽  
Vol 2011 ◽  
pp. 1-11 ◽  
Author(s):  
Xiaoqing Lu ◽  
Shuxian Wei ◽  
Chi-Man Lawrence Wu ◽  
Ning Ding ◽  
Shaoren Li ◽  
...  
Keyword(s):  
Solar Cells ◽  
Charge Transfer ◽  
Optical Absorption ◽  
Absorption Spectra ◽  
Dye Sensitized Solar Cells ◽  
Optical Absorption Spectra ◽  
Ancillary Ligands ◽  
Dye Sensitized ◽  
Ligand Charge Transfer ◽  
Sensitized Solar Cells

The design of light-absorbent dyes with cheaper, safer, and more sustainable materials is one of the key issues for the future development of dye-sensitized solar cells (DSSCs). We report herein a theoretical investigation on a series of polypyridyl Fe(II)-based complexes of FeL2(SCN)2, [FeL3]2+, [FeL′(SCN)3]-, [FeL′2]2+, and FeL′′(SCN)2(L = 2,2′-bipyridyl-4,4′-dicarboxylic acid, L′ = 2,2′,2″-terpyridyl-4,4′,4″-tricarboxylic acid, L″= 4,4‴-dimethyl-2,2′ : 6′,2″ :6″,2‴-quaterpyridyl-4′,4″-biscarboxylic acid) by density functional theory (DFT) and time-dependent DFT (TD-DFT). Molecular geometries, electronic structures, and optical absorption spectra are predicted in both the gas phase and methyl cyanide (MeCN) solution. Our results show that polypyridyl Fe(II)-based complexes display multitransition characters of Fe → polypyridine metal-to-ligand charge transfer and ligand-to-ligand charge transfer in the range of 350–800 nm. Structural optimizations by choosing different polypyridyl ancillary ligands lead to alterations of the molecular orbital energies, oscillator strength, and spectral response range. Compared with Ru(II) sensitizers, Fe(II)-based complexes show similar characteristics and improving trend of optical absorption spectra along with the introduction of different polypyridyl ancillary ligands.

Ruthenium(ii) complexes incorporating carbazole–diazafluorene based bipolar ligands for dye sensitized solar cell applications

2017 ◽  
Vol 41 (13) ◽  
pp. 5605-5612 ◽  
Author(s):  
Radhakrishnan Sivakumar ◽  
Rodrigo Recabarren ◽  
Sekar Ramkumar ◽  
Arumugam Manivel ◽  
Jans Alzate-Morales ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized Solar Cell ◽  
Ancillary Ligands ◽  
Dye Sensitized ◽  
New Type ◽  
Sensitized Solar Cells

A new type of ruthenium sensitizers, S3 and S4, consisting of carbazole–diazafluorene based bipolar ancillary ligands have been synthesized and characterized for dye sensitized solar cells.

Benzimidazole-functionalized ancillary ligands for heteroleptic Ru(ii) complexes: synthesis, characterization and dye-sensitized solar cell applications

2015 ◽  
Vol 44 (33) ◽  
pp. 14697-14706 ◽  
Author(s):  
Tejaswi Jella ◽  
Malladi Srikanth ◽  
Rambabu Bolligarla ◽  
Yarasi Soujanya ◽  
Surya Prakash Singh ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized Solar Cell ◽  
Polypyridyl Complexes ◽  
Ancillary Ligands ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Three new heteroleptic Ru(ii) polypyridyl complexes have been designed with a pyridine-benzimidazole functionalized ligand for dye-sensitized solar cells.

An insight into the controllable synthesis of Cd(ii) complexes with a new multifunctional ligand and its application in dye-sensitized solar cells and luminescence properties

2015 ◽  
Vol 3 (11) ◽  
pp. 6053-6063 ◽  
Author(s):  
Song Gao ◽  
Rui Qing Fan ◽  
Xin Ming Wang ◽  
Liang Sheng Qiang ◽  
Li Guo Wei ◽  
...  
Keyword(s):  
Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Luminescence Properties ◽  
Multifunctional Materials ◽  
Controllable Synthesis ◽  
Dye Sensitized ◽  
Sensitized Solar Cells ◽  
Insight Into ◽  
Multifunctional Ligand ◽  
The Way

This synergism, resulting from the combination of luminescence and DSSCs, opens up the way to new multifunctional materials.

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