Potential of Zero Charge and Its Temperature Derivative for Au(111) Electrode|Alkanethiol SAM|1.0 M Aqueous Electrolyte Solution Interfaces: Impact of Electrolyte Solution Ionic Strength and Its Effect on the Structure of the Modified Electrode|Electrolyte Solution Interface

2017 ◽  
Vol 121 (17) ◽  
pp. 9260-9272 ◽  
Author(s):  
John F. Smalley
Keyword(s):  
Ionic Strength ◽  
Modified Electrode ◽  
Electrolyte Solution ◽  
Aqueous Electrolyte ◽  
Aqueous Electrolyte Solution ◽  
Temperature Derivative ◽  
Potential Of Zero Charge ◽  
Solution Ionic Strength ◽  
Solution Interface ◽  
Zero Charge

Electrokinetics of the silica and aqueous electrolyte solution interface: Viscoelectric effects

2016 ◽  
Vol 234 ◽  
pp. 108-131 ◽  
Author(s):  
Wei-Lun Hsu ◽  
Hirofumi Daiguji ◽  
David E. Dunstan ◽  
Malcolm R. Davidson ◽  
Dalton J.E. Harvie
Keyword(s):  
Electrolyte Solution ◽  
Aqueous Electrolyte ◽  
Aqueous Electrolyte Solution ◽  
Solution Interface

A Poisson–Boltzmann treatment of the capacitance of a layer of symmetrical spherical dipoles

1978 ◽  
Vol 56 (6) ◽  
pp. 861-868 ◽  
Author(s):  
Penny Dalrymple-Alford ◽  
Keith B. Oldham
Keyword(s):  
Charge Distribution ◽  
Electrolyte Solution ◽  
Applied Field ◽  
Potential Distribution ◽  
Aqueous Electrolyte ◽  
Aqueous Electrolyte Solution ◽  
Point Of Zero Charge ◽  
One Dimensional ◽  
Solution Interface ◽  
Poisson Boltzmann

The capacitance of a layer of spherical orientable dipoles has been determined. The properties attributed to each dipole are those of two point charges on a diameter of the sphere and equidistant from its centre. A one-dimensional potential distribution is assumed to exist normal to the layer and to be coupled to the charge distribution via Poisson's law. The orientation of the dipoles is random in the absence of polarization, but is taken as governed by Boltzmannian statistics when an applied field is present. The treatment predicts that the capacitance will display a pronounced hump at the point of zero charge. Though this study was motivated by a wish to interpret the inner-layer capacitance at a mercury/aqueous electrolyte solution interface, the treatment is shown to be inapplicable quantitatively to such a system.

Structure of the metal-aqueous electrolyte solution interface

1997 ◽  
Vol 107 (12) ◽  
pp. 4719-4728 ◽  
Author(s):  
D. R. Bérard ◽  
M. Kinoshita ◽  
N. M. Cann ◽  
G. N. Patey
Keyword(s):  
Electrolyte Solution ◽  
Aqueous Electrolyte ◽  
Aqueous Electrolyte Solution ◽  
Solution Interface
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