Reaction Mechanism of Nerve-Agent Decomposition with Zr-Based Metal Organic Frameworks

2016 ◽  
Vol 120 (51) ◽  
pp. 29312-29323 ◽  
Author(s):  
Diego Troya
Keyword(s):  
Reaction Mechanism ◽  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Metal Organic

Efficient MOF-based degradation of organophosphorus compounds in non-aqueous environments

2018 ◽  
Vol 6 (7) ◽  
pp. 3038-3045 ◽  
Author(s):  
Dorina F. Sava Gallis ◽  
Jacob A. Harvey ◽  
Charles J. Pearce ◽  
Morgan G. Hall ◽  
Jared B. DeCoste ◽  
...  
Keyword(s):  
Organophosphorus Compounds ◽  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Aqueous Environments ◽  
Metal Organic

Metal–organic frameworks are shown to degrade organophosphorus compounds in non-aqueous environments, highlighting appropriate simulants for the nerve agent sarin.

Synthesis of nanocrystals of Zr-based metal–organic frameworks with csq-net: significant enhancement in the degradation of a nerve agent simulant

2015 ◽  
Vol 51 (54) ◽  
pp. 10925-10928 ◽  
Author(s):  
Peng Li ◽  
Rachel C. Klet ◽  
Su-Young Moon ◽  
Timothy C. Wang ◽  
Pravas Deria ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Significant Enhancement ◽  
Metal Organic

The synthesis of nano-sized particles of NU-1000 (length from 75 nm to 1200 nm) and PCN-222/MOF-545 (length from 350 nm to 900 nm) is reported.

Thermodynamic complexity of carbon capture in alkylamine-functionalized metal–organic frameworks

2015 ◽  
Vol 3 (8) ◽  
pp. 4248-4254 ◽  
Author(s):  
D. Wu ◽  
T. M. McDonald ◽  
Z. Quan ◽  
S. V. Ushakov ◽  
P. Zhang ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Carbon Capture ◽  
Metal Organic Frameworks ◽  
Adsorption Calorimetry ◽  
Adsorption Enthalpy ◽  
Metal Organic

The CO2 adsorption enthalpy on an alkylamine-appended MOF, mmen-Mg2(dobpdc), was directly identified by adsorption calorimetry at 298, 323 and 348 K. The data suggest three adsorption events as function of coverage: two types of strong chemisorption and one weak physisorption. A multistage reaction mechanism was proposed.

Cerium(IV) vs Zirconium(IV) Based Metal–Organic Frameworks for Detoxification of a Nerve Agent

2017 ◽  
Vol 29 (7) ◽  
pp. 2672-2675 ◽  
Author(s):  
Timur Islamoglu ◽  
Ahmet Atilgan ◽  
Su-Young Moon ◽  
Gregory W. Peterson ◽  
Jared B. DeCoste ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Metal Organic

Water Reaction Mechanism in Metal Organic Frameworks with Coordinatively Unsaturated Metal Ions: MOF-74

2014 ◽  
Vol 26 (23) ◽  
pp. 6886-6895 ◽  
Author(s):  
Kui Tan ◽  
Sebastian Zuluaga ◽  
Qihan Gong ◽  
Pieremanuele Canepa ◽  
Hao Wang ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Metal Ions ◽  
Metal Organic Frameworks ◽  
Metal Organic

Adsorptive removal of nerve-agent simulant with zirconium-based metal-organic frameworks modified by hydrophobic monocarboxylic acids

2019 ◽  
Vol 285 ◽  
pp. 61-69 ◽  
Author(s):  
Kyung Ho Cho ◽  
Sachin K. Chitale ◽  
Seung-Joo Kim ◽  
Ga-Young Cha ◽  
Do-Young Hong ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Monocarboxylic Acids ◽  
Adsorptive Removal ◽  
Metal Organic

Adenine-Based Zn(II)/Cd(II) Metal–Organic Frameworks as Efficient Heterogeneous Catalysts for Facile CO2Fixation into Cyclic Carbonates: A DFT-Supported Study of the Reaction Mechanism

2019 ◽  
Vol 58 (17) ◽  
pp. 11389-11403 ◽  
Author(s):  
Yadagiri Rachuri ◽  
Jintu Francis Kurisingal ◽  
Ramesh Kumar Chitumalla ◽  
Srimai Vuppala ◽  
Yunjang Gu ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Heterogeneous Catalysts ◽  
Metal Organic Frameworks ◽  
Cyclic Carbonates ◽  
Metal Organic

Tuning the Lewis acidity of metal–organic frameworks for enhanced catalysis

2021 ◽  
Author(s):  
Venkata Swaroopa Datta Devulapalli ◽  
Mélissandre Richard ◽  
Tian-Yi Luo ◽  
Mattheus L. De Souza ◽  
Nathaniel L. Rosi ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Nerve Agent ◽  
Metal Salts ◽  
Lewis Acidity ◽  
Kinetics Of Hydrolysis ◽  
Nitrophenyl Phosphate ◽  
Transition Metal Salts ◽  
Metal Organic ◽  
Kinetics Of ◽  
Hydrolysis Of

The kinetics of hydrolysis of dimethyl nitrophenyl phosphate (DMNP), a simulant of the nerve agent Soman, was studied and revealed transition metal salts as catalysts.

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