scholarly journals Earth-Abundant and Non-Toxic SiX (X = S, Se) Monolayers as Highly Efficient Thermoelectric Materials

2017 ◽  
Vol 121 (1) ◽  
pp. 123-128 ◽  
Author(s):  
Ji-Hui Yang ◽  
Qinghong Yuan ◽  
Huixiong Deng ◽  
Su-Huai Wei ◽  
Boris I. Yakobson
2017 ◽  
Vol 5 (44) ◽  
pp. 23139-23145 ◽  
Author(s):  
Rajiv Ramanujam Prabhakar ◽  
Wilman Septina ◽  
Sebastian Siol ◽  
Thomas Moehl ◽  
René Wick-Joliat ◽  
...  

A highly efficient Sb2Se3photocathode is resistant to photocorrosion in strongly acidic media without protective overlayers.


Nanomaterials ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 929 ◽  
Author(s):  
Sajjad Hussain ◽  
Kamran Akbar ◽  
Dhanasekaran Vikraman ◽  
Rana Afzal ◽  
Wooseok Song ◽  
...  

To find an effective alternative to scarce, high-cost noble platinum (Pt) electrocatalyst for hydrogen evolution reaction (HER), researchers are pursuing inexpensive and highly efficient materials as an electrocatalyst for large scale practical application. Layered transition metal dichalcogenides (TMDCs) are promising candidates for durable HER catalysts due to their cost-effective, highly active edges and Earth-abundant elements to replace Pt electrocatalysts. Herein, we design an active, stable earth-abundant TMDCs based catalyst, WS(1−x)Sex nanoparticles-decorated onto a 3D porous graphene/Ni foam. The WS(1−x)Sex/graphene/NF catalyst exhibits fast hydrogen evolution kinetics with a moderate overpotential of ~−93 mV to drive a current density of 10 mA cm−2, a small Tafel slope of ~51 mV dec−1, and a long cycling lifespan more than 20 h in 0.5 M sulfuric acid, which is much better than WS2/NF and WS2/graphene/NF catalysts. Our outcomes enabled a way to utilize the TMDCs decorated graphene and precious-metal-free electrocatalyst as mechanically robust and electrically conductive catalyst materials.


2020 ◽  
Vol 8 (40) ◽  
pp. 14037-14048
Author(s):  
Pavan Kumar-Ventrapati ◽  
Shantanu Misra ◽  
Gaëlle Delaizir ◽  
Anne Dauscher ◽  
Bertrand Lenoir ◽  
...  

The n-type chalcogenide Bi8Se7 is the parent compound of a new class of highly-efficient thermoelectric materials for near-room-temperature thermoelectric applications.


Science ◽  
2019 ◽  
Vol 365 (6460) ◽  
pp. 1418-1424 ◽  
Author(s):  
Wenke He ◽  
Dongyang Wang ◽  
Haijun Wu ◽  
Yu Xiao ◽  
Yang Zhang ◽  
...  

Thermoelectric technology allows conversion between heat and electricity. Many good thermoelectric materials contain rare or toxic elements, so developing low-cost and high-performance thermoelectric materials is warranted. Here, we report the temperature-dependent interplay of three separate electronic bands in hole-doped tin sulfide (SnS) crystals. This behavior leads to synergistic optimization between effective mass (m*) and carrier mobility (μ) and can be boosted through introducing selenium (Se). This enhanced the power factor from ~30 to ~53 microwatts per centimeter per square kelvin (μW cm−1 K−2 at 300 K), while lowering the thermal conductivity after Se alloying. As a result, we obtained a maximum figure of merit ZT (ZTmax) of ~1.6 at 873 K and an average ZT (ZTave) of ~1.25 at 300 to 873 K in SnS0.91Se0.09 crystals. Our strategy for band manipulation offers a different route for optimizing thermoelectric performance. The high-performance SnS crystals represent an important step toward low-cost, Earth-abundant, and environmentally friendly thermoelectrics.


ChemNanoMat ◽  
2015 ◽  
Vol 1 (7) ◽  
pp. 528-528
Author(s):  
Faruk Ozel ◽  
Adem Yar ◽  
Emre Aslan ◽  
Emre Arkan ◽  
Abdalaziz Aljabour ◽  
...  

2000 ◽  
Vol 34 (4) ◽  
pp. 376-380 ◽  
Author(s):  
V. A. Kutasov ◽  
L. N. Luk’yanova ◽  
P. P. Konstantinov

2014 ◽  
Vol 43 (22) ◽  
pp. 7787-7812 ◽  
Author(s):  
Jingrun Ran ◽  
Jun Zhang ◽  
Jiaguo Yu ◽  
Mietek Jaroniec ◽  
Shi Zhang Qiao

Active and robust cocatalysts constructed from earth-abundant elements greatly contribute to the highly efficient, stable and cost-effective photocatalytic water splitting.


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