Storage and Separation of Carbon Dioxide and Methane in Hydrated Covalent Organic Frameworks

2016 ◽  
Vol 120 (41) ◽  
pp. 23756-23762 ◽  
Author(s):  
J. M. Vicent-Luna ◽  
A. Luna-Triguero ◽  
S. Calero
Keyword(s):  
Carbon Dioxide ◽  
Covalent Organic Frameworks

scholarly journals Reticular Electronic Tuning of Porphyrin Active Sites in Covalent Organic Frameworks for Electrocatalytic Carbon Dioxide Reduction

2018 ◽  
Vol 140 (3) ◽  
pp. 1116-1122 ◽  
Author(s):  
Christian S. Diercks ◽  
Song Lin ◽  
Nikolay Kornienko ◽  
Eugene A. Kapustin ◽  
Eva M. Nichols ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Active Sites ◽  
Carbon Dioxide Reduction ◽  
Covalent Organic Frameworks ◽  
Electronic Tuning

scholarly journals Molecular Insights into Carbon Dioxide Sorption in Hydrazone-Based Covalent Organic Frameworks with Tertiary Amine Moieties

2019 ◽  
Vol 31 (6) ◽  
pp. 1946-1955 ◽  
Author(s):  
Kerstin Gottschling ◽  
Linus Stegbauer ◽  
Gökcen Savasci ◽  
Nathan A. Prisco ◽  
Zachariah J. Berkson ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Tertiary Amine ◽  
Covalent Organic Frameworks ◽  
Carbon Dioxide Sorption

scholarly journals Synthesis of Sidechain Free Hydrazone-Linked Covalent Organic Frameworks Through Supercritical Carbon Dioxide Activation

2021 ◽  
Author(s):  
Shashini D Diwakara ◽  
Gregory T McCandless ◽  
Sampath B Alahakoon ◽  
Ronald Smaldone
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Narrow Range ◽  
High Surface ◽  
Covalent Organic Frameworks ◽  
Surface Areas ◽  
Carbon Dioxide Activation ◽  
Supercritical Carbon

Supercritical carbon dioxide (scCO2) activation provides milder conditions to process covalent organic frameworks (COFs) without compromising their crystallinity and porosity. To this end, three hydrazone COFs (TFPB-DHz COF, TFPT-DHz COF, Py-DHz COF) were synthesized with a terephthaloyl dihydrazide linker (DHz) which has no substituents. To date, the synthesis of hydrazone COFs without a narrow range of alkoxy linkers has not been possible. The scCO2 activated hydrazone-linked COFs in this study were crystalline and had high surface areas (TFPB-DHz COF, TFPT-DHz COF and Py-DHz COF were 790 m²/g, 1199 m²/g, and 932 m²/g, respectively). This study shows the significance of using milder activation methods for making hydrazone-linked COF structures that were previously inaccessible.

Synthesis of Benzobisoxazole-Linked Two-Dimensional Covalent Organic Frameworks and Their Carbon Dioxide Capture Properties

2016 ◽  
Vol 5 (9) ◽  
pp. 1055-1058 ◽  
Author(s):  
David A. Pyles ◽  
Jonathan W. Crowe ◽  
Luke A. Baldwin ◽  
Psaras L. McGrier
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Capture ◽  
Two Dimensional ◽  
Covalent Organic Frameworks

Carbon Dioxide Capture: Covalent Organic Frameworks for CO2Capture (Adv. Mater. 15/2016)

2016 ◽  
Vol 28 (15) ◽  
pp. 3032-3032 ◽  
Author(s):  
Yongfei Zeng ◽  
Ruqiang Zou ◽  
Yanli Zhao
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Capture ◽  
Covalent Organic Frameworks

scholarly journals Two-Dimensional Covalent Organic Frameworks for Carbon Dioxide Capture through Channel-Wall Functionalization

2015 ◽  
Vol 127 (10) ◽  
pp. 3029-3033 ◽  
Author(s):  
Ning Huang ◽  
Xiong Chen ◽  
Rajamani Krishna ◽  
Donglin Jiang
Keyword(s):  
Carbon Dioxide ◽  
Channel Wall ◽  
Carbon Dioxide Capture ◽  
Two Dimensional ◽  
Covalent Organic Frameworks
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