Hydroxyl versus Carboxyl Substituent: Effects of Competitive and Cooperative Multiple Hydrogen Bonds on Concentration-Controlled Self-Assembly

2016 ◽  
Vol 120 (26) ◽  
pp. 14187-14197 ◽  
Author(s):  
Kai Miao ◽  
Yi Hu ◽  
Bao Zha ◽  
Li Xu ◽  
Xinrui Miao ◽  
...  
2008 ◽  
Vol 8 (5) ◽  
pp. 1585-1594 ◽  
Author(s):  
Blanca R. Manzano ◽  
Félix A. Jalón ◽  
M. Laura Soriano ◽  
Ana M. Rodríguez ◽  
Antonio de la Hoz ◽  
...  

2020 ◽  
Vol 108 (4) ◽  
pp. 249-260 ◽  
Author(s):  
Evgeny V. Nazarchuk ◽  
Dmitri O. Charkin ◽  
Dmitri V. Kozlov ◽  
Oleg I. Siidra ◽  
Stepan N. Kalmykov

AbstractNine new templated uranyl sulfates and selenates, [(H9O4)2(H2O)][(UO2)2(SO4)3(H2O)2] (H9US), [(C5H7 NO)2(H2O)][(UO2)2(SeO4)3(H2O)2](H2O) (OUSe), [C6H6N3][H5O2] [(UO2)2(SeO4)3(H2O)] (BH5USe), [C6H6N3][H7O3][(UO2)2(SO4)3 (H2O)](H2O) (BH7US), [C6H16N][H5O2][(UO2)2(SeO4)3(H2O)] (TeH5USe), [C6H18N2][(UO2)2(SO4)3(H2O)] (TmUS), [H5O2]2 [(UO2)2(SeO4)3(H2O)](H2O) (H5USe-1), [H5O2]2[(UO2)2(SeO4)3 (H2O)2](H2O)9 (H5USe-2), and [C4H14N2][(UO2)2(SeO4)3(H2O)](H2O) (DmUSe) have been prepared by isothermal evaporation of aqueous solutions containing extra sulfuric or selenic acid. Their crystal structures can be considered as organo-inorganic hybrids constructed of alternating [(UO2)2 (TO4)3(H2O)n]2− slabs (T = Se6+, S6+, n = 1, 2) and layers containing templating organic moieties and/or hydronium ions and water molecules. The organic and inorganic parts of the structures are linked by multiple hydrogen bonds. Besides structure description, we offer topological analysis of the inorganic fragments with UO2:TO4 ratio of 2:3 as modular units resulting from self-assembly of fundamental chains formed by [(UO2)2(TO4)2] tetramers and TO4 tetrahedra.


2011 ◽  
Vol 27 (04) ◽  
pp. 918-924
Author(s):  
LIU Yun ◽  
◽  
HE You-Zhou ◽  
YUAN Li-Hua ◽  
FENG Wen

2014 ◽  
Vol 30 (8) ◽  
pp. 1501-1508
Author(s):  
HE You-Zhou ◽  
◽  
LIU Yun ◽  
LIU Peng ◽  
FENG Wen ◽  
...  

2000 ◽  
pp. 41-42 ◽  
Author(s):  
Kenji Kobayashi ◽  
Toshiaki Shirasaka ◽  
Ernst Horn ◽  
Naomichi Furukawa ◽  
Kentaro Yamaguchi ◽  
...  

ChemInform ◽  
2000 ◽  
Vol 31 (42) ◽  
pp. no-no
Author(s):  
Steven C. Zimmerman ◽  
Perry S. Corbin

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