High Oxidation Tolerance of Ru Nanoparticles on 12CaO·7Al2O3 Electride

2016 ◽  
Vol 120 (16) ◽  
pp. 8711-8716 ◽  
Author(s):  
Hitoshi Abe ◽  
Yasuhiro Niwa ◽  
Masaaki Kitano ◽  
Yasunori Inoue ◽  
Youichi Murakami ◽  
...  
Keyword(s):  
Ru Nanoparticles ◽  
High Oxidation ◽  
Oxidation Tolerance

The Structure and Properties of MoSi2 Thin Film in Mos Process

1980 ◽  
Vol 38 ◽  
pp. 326-327
Author(s):  
C.K. Wu ◽  
P. Chang ◽  
N. Godinho
Keyword(s):  
Thin Film ◽  
Integrated Circuits ◽  
High Performance ◽  
Large Scale ◽  
Process Development ◽  
Structure And Properties ◽  
Metal Silicides ◽  
High Oxidation ◽  
Important Approach ◽  
High Oxidation Resistance

Recently, the use of refractory metal silicides as low resistivity, high temperature and high oxidation resistance gate materials in large scale integrated circuits (LSI) has become an important approach in advanced MOS process development (1). This research is a systematic study on the structure and properties of molybdenum silicide thin film and its applicability to high performance LSI fabrication.

Electron Donation by Low-Crystalline Ba-La-Ce Oxygen-Deficient Composite Oxide Accumulating on Ru Nanoparticles for Ammonia Synthesis under Mild Conditions

2019 ◽  
Author(s):  
Katsutoshi Sato ◽  
Shin-ichiro Miyahara ◽  
Yuta Ogura ◽  
Kotoko Tsujimaru ◽  
Yuichiro Wada ◽  
...  
Keyword(s):  
Ammonia Synthesis ◽  
Bond Cleavage ◽  
Synthesis Process ◽  
Strong Electron ◽  
Mild Conditions ◽  
Ru Nanoparticles ◽  
Rate Determining Step ◽  
Highly Active ◽  
Composite Oxides ◽  
Low Crystalline

<p>To mitigate global problems related to energy and global warming, it is helpful to develop an ammonia synthesis process using catalysts that are highly active under mild conditions. Here we show that the ammonia synthesis activity of Ru/Ba/LaCeO<i><sub>x</sub></i> pre-reduced at 700 °C is the highest reported among oxide-supported Ru catalysts. Our results indicate that low crystalline oxygen-deficient composite oxides, which include Ba<sup>2+</sup>, Ce<sup>3+</sup> and La<sup>3+</sup>, with strong electron-donating ability, accumulate on Ru particles and thus promote N≡N bond cleavage, which is the rate determining step for ammonia synthesis.</p>

Electron Donation by Low-Crystalline Ba-La-Ce Oxygen-Deficient Composite Oxide Accumulating on Ru Nanoparticles for Ammonia Synthesis under Mild Conditions

2019 ◽  
Author(s):  
Katsutoshi Sato ◽  
Shin-ichiro Miyahara ◽  
Yuta Ogura ◽  
Kotoko Tsujimaru ◽  
Yuichiro Wada ◽  
...  
Keyword(s):  
Ammonia Synthesis ◽  
Bond Cleavage ◽  
Synthesis Process ◽  
Strong Electron ◽  
Mild Conditions ◽  
Ru Nanoparticles ◽  
Rate Determining Step ◽  
Highly Active ◽  
Composite Oxides ◽  
Low Crystalline

<p>To mitigate global problems related to energy and global warming, it is helpful to develop an ammonia synthesis process using catalysts that are highly active under mild conditions. Here we show that the ammonia synthesis activity of Ru/Ba/LaCeO<i><sub>x</sub></i> pre-reduced at 700 °C is the highest reported among oxide-supported Ru catalysts. Our results indicate that low crystalline oxygen-deficient composite oxides, which include Ba<sup>2+</sup>, Ce<sup>3+</sup> and La<sup>3+</sup>, with strong electron-donating ability, accumulate on Ru particles and thus promote N≡N bond cleavage, which is the rate determining step for ammonia synthesis.</p>

ALTEMP V36

Alloy Digest ◽  
1961 ◽  
Vol 10 (2) ◽  
Keyword(s):  
Corrosion Resistance ◽  
High Temperature ◽  
Precipitation Hardening ◽  
Base Alloy ◽  
Heat Treating ◽  
High Oxidation ◽  
Cobalt Base Alloy ◽  
Cobalt Base ◽  
Oxidation And Corrosion ◽  
Hardening Heat Treatment

Abstract Altemp V36 is a cobalt-base alloy recommended for high temperature applications. It has high oxidation and corrosion resistance. It shows a slight response to a precipitation-hardening heat treatment. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as creep, deformation, and fatigue. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Co-25. Producer or source: Allegheny Ludlum Corporation.

COLMONOY No. 21

Alloy Digest ◽  
1996 ◽  
Vol 45 (3) ◽  
Keyword(s):  
Cast Iron ◽  
Physical Properties ◽  
Oxidation Resistance ◽  
Base Alloy ◽  
Nickel Base Alloy ◽  
Powder Metal ◽  
High Oxidation ◽  
High Oxidation Resistance ◽  
Nickel Base

Abstract Colmonoy No. 21 is a nickel-base alloy for repairing cast iron parts. The deposit has high oxidation resistance, develops a hardness of Rockwell C 26-31, and is easily finished by filing or grinding. This datasheet provides information on composition, physical properties, and hardness. It also includes information on machining, joining, and powder metal forms. Filing Code: Ni-504. Producer or source: Wall Colmonoy Corporation.

CMN-155

Alloy Digest ◽  
1968 ◽  
Vol 17 (8) ◽  
Keyword(s):  
High Temperature ◽  
Heat Resistance ◽  
Physical Properties ◽  
Gas Turbine ◽  
Base Alloy ◽  
Heat Treating ◽  
Jet Engine ◽  
Iron Base Alloy ◽  
Temperature Performance ◽  
High Oxidation

Abstract CMN-155 is an austenitic iron-base alloy having high oxidation and heat resistance combined with good high temperature properties. It is recommended for jet engine and gas turbine components, high temperature fasteners, and rocket chambers. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as creep. It also includes information on high temperature performance as well as forming, heat treating, machining, and joining. Filing Code: SS-212. Producer or source: Cannon-Muskegon Corporation.

MULTIMET (N-155)

Alloy Digest ◽  
1961 ◽  
Vol 10 (12) ◽  
Keyword(s):  
High Temperature ◽  
Physical Properties ◽  
Heat Treating ◽  
Age Hardening ◽  
Nickel Chromium ◽  
Cobalt Nickel ◽  
Temperature Performance ◽  
High Oxidation ◽  
Scaling Resistance ◽  
Made In

Abstract MULTIMET alloy is cobalt-nickel-chromium-iron austenitic alloy having high oxidation and scaling resistance along with good high-temperature properties. It tends to work harden but does not respond significantly to age-hardening. It is made in a wrought grade (0.08-0.16% carbon) and a casting grade (0.20% max. carbon). This datasheet provides information on composition, physical properties, elasticity, and tensile properties as well as creep and fatigue. It also includes information on high temperature performance as well as forming, heat treating, machining, and joining. Filing Code: SS-28. Producer or source: Haynes Stellite Company. Originally published May 1955, revised December 1961.

Recent advances in the Silver catalysed synthesis of furan and its applications

2020 ◽  
Vol 09 ◽  
Author(s):  
C M A Afsina ◽  
Mohan Neetha ◽  
Thaipparambil Aneeja ◽  
Gopinathan Anilkumar
Keyword(s):  
Organic Synthesis ◽  
Oxidation Potential ◽  
Silver Complexes ◽  
Wide Spread ◽  
Silver Catalysts ◽  
Recent Advances ◽  
High Oxidation ◽  
Furan Moiety ◽  
Anti Fungal ◽  
Fragrance Compounds

: Furan and its derivatives find wide-spread application as pharmaceuticals, pigments, dyes, brighteners, flavour & fragrance compounds and insecticides. They also exhibit anti-hyperglycemic, analgesic, anti-inflammatory, antibacterial, anti-fungal and anti-tumour activities. Silver catalysts are nowadays commonly used in organic synthesis due to the high oxidation potential and versatile nature of silver complexes. In this review, we summarise the recent advances in the synthesis and applications of furan moiety using silver catalysis and covers literature from 2015-2020.

New dinuclear cobalt(II) octaaza macrocyclic complexes with high oxidation redox potentials: Their crystal structure and unusual magnetic properties

2008 ◽  
Vol 361 (9-10) ◽  
pp. 2747-2758 ◽  
Author(s):  
Jayanthi Narayanan ◽  
Alejandro Solano-Peralta ◽  
Víctor Manuel Ugalde-Saldivar ◽  
Roberto Escudero ◽  
Herbert Höpfl ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Macrocyclic Complexes ◽  
Redox Potentials ◽  
High Oxidation
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