scholarly journals Thermal Decomposition of Tin(II) Oxyhydroxide and Subsequent Oxidation in Air: Kinetic Deconvolution of Overlapping Heterogeneous Processes

2015 ◽  
Vol 119 (28) ◽  
pp. 16188-16199 ◽  
Author(s):  
Suguru Kitabayashi ◽  
Nobuyoshi Koga
Keyword(s):  
Thermal Decomposition ◽  
Subsequent Oxidation ◽  
Heterogeneous Processes ◽  
Kinetic Deconvolution ◽  
Oxidation In Air

scholarly journals Thermal decomposition of mixed calcium oxalate hydrates – kinetic deconvolution of complex heterogeneous processes

2020 ◽  
Vol 22 (16) ◽  
pp. 8889-8901
Author(s):  
Roman Svoboda ◽  
Zuzana Olmrová Zmrhalová ◽  
Dušan Galusek ◽  
Daniela Brandová ◽  
Jozef Chovanec
Keyword(s):  
Thermal Decomposition ◽  
Calcium Oxalate ◽  
Co Oxidation ◽  
Oxidation Kinetics ◽  
Decomposition Reaction ◽  
Single Step ◽  
Heterogeneous Processes ◽  
Kinetic Deconvolution

Whereas thermogravimetry monitors only a single-step CaOx decomposition reaction, DSC in addition reveals the complex competing CO oxidation kinetics.

Thermal decomposition of volcanic glass (rhyolite): kinetic deconvolution of dehydration and dehydroxylation process

2021 ◽  
pp. 179082
Author(s):  
Panagiotis M. Angelopoulos ◽  
Nebojsa Manic ◽  
Bojan Jankovic ◽  
Maria Taxiarchou
Keyword(s):  
Thermal Decomposition ◽  
Volcanic Glass ◽  
Kinetic Deconvolution

scholarly journals Thermal Decomposition of Maya Blue: Extraction of Indigo Thermal Decomposition Steps from a Multistep Heterogeneous Reaction Using a Kinetic Deconvolution Analysis

Molecules ◽  
2019 ◽  
Vol 24 (13) ◽  
pp. 2515 ◽  
Author(s):  
Yamamoto ◽  
Koga
Keyword(s):  
Thermal Decomposition ◽  
Clay Minerals ◽  
Materials Science ◽  
Heterogeneous Reaction ◽  
Practical Method ◽  
Isoconversional Method ◽  
Deconvolution Analysis ◽  
Decomposition Processes ◽  
Maya Blue ◽  
Kinetic Deconvolution

Examining the kinetics of solids’ thermal decomposition with multiple overlapping steps is of growing interest in many fields, including materials science and engineering. Despite the difficulty of describing the kinetics for complex reaction processes constrained by physico-geometrical features, the kinetic deconvolution analysis (KDA) based on a cumulative kinetic equation is one practical method of obtaining the fundamental information needed to interpret detailed kinetic features. This article reports the application of KDA to thermal decomposition of clay minerals and indigo–clay mineral hybrid compounds, known as Maya blue, from ancient Mayan civilization. Maya blue samples were prepared by heating solid mixtures of indigo and clay minerals (palygorskite and sepiolite), followed by purification. The multistep thermal decomposition processes of the clay minerals and Maya blue samples were analyzed kinetically in a stepwise manner through preliminary kinetic analyses based on a conventional isoconversional method and mathematical peak deconvolution to finally attain the KDA. By comparing the results of KDA for the thermal decomposition processes of the clay minerals and the Maya blue samples, information about the thermal decomposition steps of the indigo incorporated into the Maya blue samples was extracted. The thermal stability of Maya blue samples was interpreted through the kinetic characterization of the extracted indigo decomposition steps.

Tetrakis(Triphenylphosphine Oxide)Lithium Di(Iodo)Aurate(I)

2006 ◽  
Vol 61 (8) ◽  
pp. 956-960
Author(s):  
Oliver Schuster ◽  
Hubert Schmidbaur
Keyword(s):  
Title Compound ◽  
Triphenylphosphine Oxide ◽  
Relative Orientation ◽  
Molar Ratio ◽  
Reference Compound ◽  
Space Group ◽  
Subsequent Oxidation ◽  
Oxidation In Air ◽  
Mode Of Attachment

The title compound, [(Ph3PO)4Li]+ AuI2 −, crystallized from a reaction mixture obtained from Ph3PAuC≡CPh, LiMe and MeI (molar ratio 1 : 1 : 2) in diethylether upon subsequent oxidation in air. The triclinic crystals, space group P1̅, are isomorphous with those of the corresponding di(bromo)cuprate(I). The gold atoms of the two independent [AuI2]− anions reside on centers of inversion and have no close interanionic contacts. The structure of the complete [(Ph3PO)4Li]+ cation does not approach any standard symmetry (e. g., S4 or D2d). Its conformation is similar to that reported for the isomorphous reference compound with the anion CuBr2 −, but different from that in the bromide・ acetonitrile, Li-phthalocyaninate or iodide ・ triphenylphosphine oxide salts, suggesting that the relative orientation of the four Ph3PO molecules at the Li+ center is flexible and co-determined by the packing in the crystals. Even the O4Li core units are affected by the variations in the mode of attachment of the Ph3PO ligands, and their distortions are significant as shown by the ranges of Li-O distances and O-Li-O angles, which are small in the title compound, but spread from 1.886(5) to 1.953(9) Å and from 105.1(4) to 111.8(4)◦, respectively, when taking into account all known salts with the [(Ph3PO)4Li]+ cation

Applications of Photoelectron Microscopy

1976 ◽  
Vol 34 ◽  
pp. 506-507
Author(s):  
William J. Baxter
Keyword(s):  
Electron Microscopy ◽  
Thermal Decomposition ◽  
Chemical Composition ◽  
Ultraviolet Radiation ◽  
Thin Layer ◽  
Edge Effects ◽  
Electron Optics ◽  
Surface Layers ◽  
Crystalline Orientation ◽  
Fluorescent Screen

In this form of electron microscopy, photoelectrons emitted from a metal by ultraviolet radiation are accelerated and imaged onto a fluorescent screen by conventional electron optics. image contrast is determined by spatial variations in the intensity of the photoemission. The dominant source of contrast is due to changes in the photoelectric work function, between surfaces of different crystalline orientation, or different chemical composition. Topographical variations produce a relatively weak contrast due to shadowing and edge effects.Since the photoelectrons originate from the surface layers (e.g. ∼5-10 nm for metals), photoelectron microscopy is surface sensitive. Thus to see the microstructure of a metal the thin layer (∼3 nm) of surface oxide must be removed, either by ion bombardment or by thermal decomposition in the vacuum of the microscope.

Preparation and characterisation of vanadium pentoxide supported rhodium catalyst

1988 ◽  
Vol 46 ◽  
pp. 946-947
Author(s):  
A. Legrouri
Keyword(s):  
Aqueous Solution ◽  
Thermal Decomposition ◽  
Physicochemical Properties ◽  
Surface Area ◽  
Vanadium Pentoxide ◽  
High Purity ◽  
Gas Adsorption ◽  
Rhodium Catalyst ◽  
Optical Methods ◽  
Reducible Oxides

The industrial importance of metal catalysts supported on reducible oxides has stimulated considerable interest during the last few years. This presentation reports on the study of the physicochemical properties of metallic rhodium supported on vanadium pentoxide (Rh/V2O5). Electron optical methods, in conjunction with other techniques, were used to characterise the catalyst before its use in the hydrogenolysis of butane; a reaction for which Rh metal is known to be among the most active catalysts.V2O5 powder was prepared by thermal decomposition of high purity ammonium metavanadate in air at 400 °C for 2 hours. Previous studies of the microstructure of this compound, by HREM, SEM and gas adsorption, showed it to be non— porous with a very low surface area of 6m2/g3. The metal loading of the catalyst used was lwt%Rh on V2Q5. It was prepared by wet impregnating the support with an aqueous solution of RhCI3.3H2O.

Observations of the Thermal Decomposition of Brucite

1968 ◽  
Vol 26 ◽  
pp. 446-447
Author(s):  
P. L. Burnett ◽  
W. R. Mitchell ◽  
C. L. Houck
Keyword(s):  
Thermal Decomposition ◽  
Magnesium Oxide ◽  
Basal Plane ◽  
Magnesium Ions ◽  
A Value ◽  
Reaction Proceeds

Natural Brucite (Mg(OH)2) decomposes on heating to form magnesium oxide (MgO) having its cubic ﹛110﹜ and ﹛111﹜ planes respectively parallel to the prism and basal planes of the hexagonal brucite lattice. Although the crystal-lographic relation between the parent brucite crystal and the resulting mag-nesium oxide crystallites is well known, the exact mechanism by which the reaction proceeds is still a matter of controversy. Goodman described the decomposition as an initial shrinkage in the brucite basal plane allowing magnesium ions to shift their original sites to the required magnesium oxide positions followed by a collapse of the planes along the original <0001> direction of the brucite crystal. He noted that the (110) diffraction spots of brucite immediately shifted to the positions required for the (220) reflections of magnesium oxide. Gordon observed separate diffraction spots for the (110) brucite and (220) magnesium oxide planes. The positions of the (110) and (100) brucite never changed but only diminished in intensity while the (220) planes of magnesium shifted from a value larger than the listed ASTM d spacing to the predicted value as the decomposition progressed.

A magnetic super lattice

1987 ◽  
Vol 45 ◽  
pp. 360-361 ◽  
Author(s):  
M.D. Bentzon ◽  
J. v. Wonterghem ◽  
A. Thölén
Keyword(s):  
Thermal Decomposition ◽  
Oleic Acid ◽  
Magnetic Fluid ◽  
Magnetic Particles ◽  
Carbon Film ◽  
Thick Layer ◽  
Amorphous Iron ◽  
Super Lattice ◽  
Carrier Liquid ◽  
Median Diameter

We report on the oxidation of a magnetic fluid. The oxidation results in magnetic super lattice crystals. The “atoms” are hematite (α-Fe2O3) particles with a diameter ø = 6.9 nm and they are covered with a 1-2 nm thick layer of surfactant molecules.Magnetic fluids are homogeneous suspensions of small magnetic particles in a carrier liquid. To prevent agglomeration, the particles are coated with surfactant molecules. The magnetic fluid studied in this work was produced by thermal decomposition of Fe(CO)5 in Declin (carrier liquid) in the presence of oleic acid (surfactant). The magnetic particles consist of an amorphous iron-carbon alloy. For TEM investigation a droplet of the fluid was added to benzine and a carbon film on a copper net was immersed. When exposed to air the sample starts burning. The oxidation and electron irradiation transform the magnetic particles into hematite (α-Fe2O3) particles with a median diameter ø = 6.9 nm.

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