scholarly journals X-ray Transient Absorption Studies of Exciton Self-Trapping

2021 ◽  
Author(s):  
Nathan A. Turner ◽  
Jason G. Mance ◽  
Klaus Attenkofer ◽  
Bernhard W. Adams ◽  
Xiaoyi Zhang ◽  
...  
Keyword(s):  
Transient Absorption ◽  
X Ray ◽  
Absorption Studies ◽  
Self Trapping

In Situ X-Ray Absorption Studies of the Electrochemical Reduction of Hydroxocobalamin

1997 ◽  
Vol 7 (C2) ◽  
pp. C2-619-C2-620 ◽  
Author(s):  
M. Giorgett ◽  
I. Ascone ◽  
M. Berrettoni ◽  
S. Zamponi ◽  
R. Marassi
Keyword(s):  
Electrochemical Reduction ◽  
X Ray ◽  
Absorption Studies ◽  
X Ray Absorption

Effect of trytophan as dopant on potassium acid phthalate single crystals

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Single Crystals ◽  
Room Temperature ◽  
Visible Region ◽  
X Ray Diffraction ◽  
X Ray ◽  
Slow Evaporation Technique ◽  
Absorption Studies ◽  
Evaporation Technique ◽  
Potassium Acid Phthalate ◽  
Acid Phthalate

Optically transparent single crystals of potassium acid phthalate (KAP, 0.5 g) 0.05 g and 0.1 g (1 and 2 mol %) trytophan were grown in aqueous solution by slow evaporation technique at room temperature. Single crystal X- ray diffraction analysis confirmed the changes in the lattice parameters of the doped crystals. The presence of functional groups in the crystal lattice has been determined qualitatively by FTIR analysis. Optical absorption studies revealed that the doped crystals possess very low absorption in the entire visible region. The dielectric constant has been studied as a function of frequency for the doped crystals. The thermal stability was evaluated by TG-DSC analysis.

X-ray Absorption Studies of Ruthenium Silicide

1993 ◽  
Vol 32 (S2) ◽  
pp. 746
Author(s):  
A. BZowski ◽  
T. K. Sham ◽  
B. X. Yang ◽  
J. M. Chen
Keyword(s):  
X Ray ◽  
Absorption Studies ◽  
Ruthenium Silicide ◽  
X Ray Absorption

scholarly journals Femtosecond Transient Absorption Studies of Two Novel Energetic Tetrazole Derivatives

2021 ◽  
pp. 100016
Author(s):  
Naga Krishnakanth Katturi ◽  
Chinmoy Biswas ◽  
Nagarjuna Kommu ◽  
Sai Santosh Kumar Raavi ◽  
Venugopal Rao Soma
Keyword(s):  
Transient Absorption ◽  
Femtosecond Transient Absorption ◽  
Absorption Studies ◽  
Tetrazole Derivatives

Ru L‐edge x‐ray absorption studies of the formation of Ru–Cu bimetallic aggregates on Cu(100)

1991 ◽  
Vol 95 (12) ◽  
pp. 8725-8731 ◽  
Author(s):  
T. K. Sham ◽  
T. Ohta ◽  
T. Yokoyama ◽  
Y. Takata ◽  
Y. Kitajima ◽  
...  
Keyword(s):  
X Ray ◽  
Absorption Studies ◽  
X Ray Absorption

scholarly journals Attosecond x-ray transient absorption spectroscopy in graphene

2021 ◽  
Vol 3 (1) ◽  
Author(s):  
Giovanni Cistaro ◽  
Luis Plaja ◽  
Fernando Martín ◽  
Antonio Picón
Keyword(s):  
Absorption Spectroscopy ◽  
Transient Absorption ◽  
Transient Absorption Spectroscopy ◽  
X Ray

scholarly journals X-ray transient absorption reveals the 1Au (nπ*) state of pyrazine in electronic relaxation

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Valeriu Scutelnic ◽  
Shota Tsuru ◽  
Mátyás Pápai ◽  
Zheyue Yang ◽  
Michael Epshtein ◽  
...  
Keyword(s):  
Electronic Excitation ◽  
Transient Absorption ◽  
Transient Absorption Spectroscopy ◽  
Electronic Relaxation ◽  
Nonadiabatic Dynamics ◽  
X Ray ◽  
Organic Chromophores ◽  
Dynamics Simulations ◽  
X Ray Absorption ◽  
Structure Calculations

AbstractElectronic relaxation in organic chromophores often proceeds via states not directly accessible by photoexcitation. We report on the photoinduced dynamics of pyrazine that involves such states, excited by a 267 nm laser and probed with X-ray transient absorption spectroscopy in a table-top setup. In addition to the previously characterized 1B2u (ππ*) (S2) and 1B3u (nπ*) (S1) states, the participation of the optically dark 1Au (nπ*) state is assigned by a combination of experimental X-ray core-to-valence spectroscopy, electronic structure calculations, nonadiabatic dynamics simulations, and X-ray spectral computations. Despite 1Au (nπ*) and 1B3u (nπ*) states having similar energies at relaxed geometry, their X-ray absorption spectra differ largely in transition energy and oscillator strength. The 1Au (nπ*) state is populated in 200 ± 50 femtoseconds after electronic excitation and plays a key role in the relaxation of pyrazine to the ground state.

scholarly journals Transient absorption spectroscopy using high harmonic generation: a review of ultrafast X-ray dynamics in molecules and solids

2019 ◽  
Vol 377 (2145) ◽  
pp. 20170463 ◽  
Author(s):  
Romain Geneaux ◽  
Hugo J. B. Marroux ◽  
Alexander Guggenmos ◽  
Daniel M. Neumark ◽  
Stephen R. Leone
Keyword(s):  
Time Scales ◽  
Harmonic Generation ◽  
Absorption Spectroscopy ◽  
Transient Absorption ◽  
High Harmonic ◽  
High Harmonic Generation ◽  
Transient Absorption Spectroscopy ◽  
Spectroscopic Techniques ◽  
X Rays ◽  
X Ray

Attosecond science opened the door to observing nuclear and electronic dynamics in real time and has begun to expand beyond its traditional grounds. Among several spectroscopic techniques, X-ray transient absorption spectroscopy has become key in understanding matter on ultrafast time scales. In this review, we illustrate the capabilities of this unique tool through a number of iconic experiments. We outline how coherent broadband X-ray radiation, emitted in high-harmonic generation, can be used to follow dynamics in increasingly complex systems. Experiments performed in both molecules and solids are discussed at length, on time scales ranging from attoseconds to picoseconds, and in perturbative or strong-field excitation regimes. This article is part of the theme issue ‘Measurement of ultrafast electronic and structural dynamics with X-rays’.

Photodissociation Structural Dynamics of TrirutheniumDodecacarbonyl Investigated by X-ray Transient Absorption Spectroscopy

2013 ◽  
Vol 117 (39) ◽  
pp. 9807-9813 ◽  
Author(s):  
Michael R. Harpham ◽  
Andrew, B. Stickrath ◽  
Xiaoyi, Zhang ◽  
Jier Huang ◽  
Michael W. Mara ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Structural Dynamics ◽  
Transient Absorption ◽  
Transient Absorption Spectroscopy ◽  
X Ray
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