scholarly journals Comparing Cyanophenyl and Pyridyl Ligands in the Formation of Porphyrin-Based Metal–Organic Coordination Networks

Author(s):  
Brian D. Baker Cortés ◽  
Nico Schmidt ◽  
Mihaela Enache ◽  
Meike Stöhr
Science ◽  
2020 ◽  
Vol 370 (6516) ◽  
pp. 587-592 ◽  
Author(s):  
Panagiota Perlepe ◽  
Itziar Oyarzabal ◽  
Aaron Mailman ◽  
Morgane Yquel ◽  
Mikhail Platunov ◽  
...  

Magnets derived from inorganic materials (e.g., oxides, rare-earth–based, and intermetallic compounds) are key components of modern technological applications. Despite considerable success in a broad range of applications, these inorganic magnets suffer several drawbacks, including energetically expensive fabrication, limited availability of certain constituent elements, high density, and poor scope for chemical tunability. A promising design strategy for next-generation magnets relies on the versatile coordination chemistry of abundant metal ions and inexpensive organic ligands. Following this approach, we report the general, simple, and efficient synthesis of lightweight, molecule-based magnets by postsynthetic reduction of preassembled coordination networks that incorporate chromium metal ions and pyrazine building blocks. The resulting metal-organic ferrimagnets feature critical temperatures up to 242°C and a 7500-oersted room-temperature coercivity.


2003 ◽  
Vol 42 (23) ◽  
pp. 2670-2673 ◽  
Author(s):  
Alexandre Dmitriev ◽  
Hannes Spillmann ◽  
Nian Lin ◽  
Johannes V. Barth ◽  
Klaus Kern

2014 ◽  
Vol 119 (1) ◽  
pp. 547-555 ◽  
Author(s):  
Marisa N. Faraggi ◽  
Vitaly N. Golovach ◽  
Sebastian Stepanow ◽  
Tzu-Chun Tseng ◽  
Nasiba Abdurakhmanova ◽  
...  

2012 ◽  
Vol 12 (5) ◽  
pp. 2234-2241 ◽  
Author(s):  
Qian Sun ◽  
Yan-Qin Wang ◽  
Ai-Ling Cheng ◽  
Kun Wang ◽  
En-Qing Gao

CrystEngComm ◽  
2010 ◽  
Vol 12 (11) ◽  
pp. 3437 ◽  
Author(s):  
Si-Tang Yan ◽  
Lian-Xu Shi ◽  
Fei-Fei Sun ◽  
Chuan-De Wu

Author(s):  
Owen R. Evans ◽  
Ren-Gen Xiong ◽  
Zhiyong Wang ◽  
George K. Wong ◽  
Wenbin Lin

2016 ◽  
Vol 40 (9) ◽  
pp. 7587-7595 ◽  
Author(s):  
Yong-Qing Huang ◽  
Yi Wan ◽  
Huai-Ying Chen ◽  
Yang Wang ◽  
Yue Zhao ◽  
...  

Three new metal–organic coordination networks with various metal-linker secondary building units are synthesized, which have luminescence and iodine adsorption properties.


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