Surface Microscopy of Atomic and Molecular Hydrogen from Field-Evaporating Semiconductors

2021 ◽  
Author(s):  
Lorenzo Rigutti ◽  
Enrico Di Russo ◽  
Florian Chabanais ◽  
Ivan Blum ◽  
Jonathan Houard ◽  
...  
Keyword(s):  
Molecular Hydrogen ◽  
Surface Microscopy

Interaction of H2O, O2 and H2 with Proton Conducting Oxides Based on Lanthanum Scandates

2019 ◽  
pp. 88-100
Author(s):  
A. S. Farlenkov ◽  
N. A. Zhuravlev ◽  
Т. A. Denisova ◽  
М. V. Ananyev
Keyword(s):  
Water Vapor ◽  
Partial Pressure ◽  
Gas Phase ◽  
Molecular Hydrogen ◽  
Proton Magnetic Resonance ◽  
Partial Pressure Of Oxygen ◽  
Proton Conducting ◽  
Conducting Oxides ◽  
Temperature Range ◽  
Apparent Level

The research uses the method of high-temperature thermogravimetric analysis to study the processes of interaction of the gas phase in the temperature range 300–950 °C in the partial pressure ranges of oxygen 8.1–50.7 kPa, water 6.1–24.3 kPa and hydrogen 4.1 kPa with La1–xSrxScO3–α oxides (x = 0; 0.04; 0.09). In the case of an increase in the partial pressure of water vapor at a constant partial pressure of oxygen (or hydrogen) in the gas phase, the apparent level of saturation of protons is shown to increase. An increase in the apparent level of saturation of protons of the sample also occurs with an increase in the partial pressure of oxygen at a constant partial pressure of water vapor in the gas phase. The paper discusses the causes of the observed processes. The research uses the hydrogen isotope exchange method with the equilibration of the isotope composition of the gas phase to study the incorporation of hydrogen into the structure of proton-conducting oxides based on strontium-doped lanthanum scandates. The concentrations of protons and deuterons were determined in the temperature range of 300–800 °C and a hydrogen pressure of 0.2 kPa for La0.91Sr0.09ScO3–α oxide. The paper discusses the role of oxygen vacancies in the process of incorporation of protons and deuterons from the atmosphere of molecular hydrogen into the structure of the proton conducting oxides La1–xSrxScO3–α (x = 0; 0.04; 0.09). The proton magnetic resonance method was used to study the local structure in the temperature range 23–110 °C at a rotation speed of 10 kHz (MAS) for La0.96Sr0.04ScO3–α oxide after thermogravimetric measurements in an atmosphere containing water vapor, and after exposures in molecular hydrogen atmosphere. The existence of proton defects incorporated into the volume of the investigated proton oxide from both the atmosphere containing water and the atmosphere containing molecular hydrogen is unambiguously shown. The paper considers the effect of the contributions of the volume and surface of La0.96Sr0.04ScO3–α oxide on the shape of the proton magnetic resonance spectra.

The Kinematics and Excitation of Molecular Hydrogen Emission in the Planetary Nebula BD +30o3639

1998 ◽  
Vol 498 (1) ◽  
pp. 267-277 ◽  
Author(s):  
D. L. Shupe ◽  
J. E. Larkin ◽  
R. A. Knop ◽  
L. Armus ◽  
K. Matthews ◽  
...  
Keyword(s):  
Planetary Nebula ◽  
Molecular Hydrogen ◽  
Hydrogen Emission

scholarly journals Line observations of the 30-Dor complex and N159A5 with the MPE imaging NIR spectrometer FAST

1991 ◽  
Vol 148 ◽  
pp. 205-206 ◽  
Author(s):  
A. Krabbe ◽  
J. Storey ◽  
V. Rotaciuc ◽  
S. Drapatz ◽  
R. Genzel
Keyword(s):  
Spatial Resolution ◽  
Molecular Hydrogen ◽  
Near Infrared ◽  
Large Magellanic Cloud ◽  
Magellanic Cloud ◽  
Emission Lines ◽  
Resolving Power ◽  
Max Planck ◽  
First Time ◽  
Infrared Array

Images with subarcsec spatial resolution in the light of near-infrared atomic (Bry) and molecular hydrogen H2 (S(1) v=1-0) emission lines were obtained for some extended, pointlike objects in the Large Magellanic Cloud (LMC) for the first time. We used the Max-Planck-Institut für extraterrestrische Physik (MPE) near-infrared array spectrometer FAST (image scale 0.8”/pix, spectral resolving power 950) at the ESO/MPI 2.2m telescope, La Silla. We present some results on the 30-Dor complex and N159A5.

Untangling the Origin of Molecular Hydrogen in the Lunar Exosphere

2019 ◽  
Vol 887 (1) ◽  
pp. 27
Author(s):  
Parker B. Crandall ◽  
Jeffrey J. Gillis-Davis ◽  
Ralf I. Kaiser
Keyword(s):  
Molecular Hydrogen ◽  
Lunar Exosphere

scholarly journals Molecular Hydrogen as a Potential Clinically Applicable Radioprotective Agent

2021 ◽  
Vol 22 (9) ◽  
pp. 4566
Author(s):  
Shin-ichi Hirano ◽  
Yusuke Ichikawa ◽  
Bunpei Sato ◽  
Haru Yamamoto ◽  
Yoshiyasu Takefuji ◽  
...  
Keyword(s):  
Radiation Damage ◽  
Molecular Hydrogen ◽  
Regulation Of Gene Expression ◽  
Animal Experiments ◽  
Radiation Energy ◽  
Water Radiolysis ◽  
Low Dose Radiation ◽  
Oxidizing Power ◽  
Radiation Induced ◽  
Radioprotective Agent

Although ionizing radiation (radiation) is commonly used for medical diagnosis and cancer treatment, radiation-induced damages cannot be avoided. Such damages can be classified into direct and indirect damages, caused by the direct absorption of radiation energy into DNA and by free radicals, such as hydroxyl radicals (•OH), generated in the process of water radiolysis. More specifically, radiation damage concerns not only direct damages to DNA, but also secondary damages to non-DNA targets, because low-dose radiation damage is mainly caused by these indirect effects. Molecular hydrogen (H2) has the potential to be a radioprotective agent because it can selectively scavenge •OH, a reactive oxygen species with strong oxidizing power. Animal experiments and clinical trials have reported that H2 exhibits a highly safe radioprotective effect. This paper reviews previously reported radioprotective effects of H2 and discusses the mechanisms of H2, not only as an antioxidant, but also in intracellular responses including anti-inflammation, anti-apoptosis, and the regulation of gene expression. In doing so, we demonstrate the prospects of H2 as a novel and clinically applicable radioprotective agent.

Structure and Dynamics of Molecular Hydrogen in the Interlayer Pores of a Swelling 2:1 Clay by Neutron Scattering

2014 ◽  
Vol 118 (44) ◽  
pp. 25740-25747 ◽  
Author(s):  
Jacqueline S. Edge ◽  
Neal T. Skipper ◽  
Felix Fernandez-Alonso ◽  
Arthur Lovell ◽  
Gadipelli Srinivas ◽  
...  
Keyword(s):  
Neutron Scattering ◽  
Molecular Hydrogen ◽  
Structure And Dynamics

scholarly journals Molecular Hydrogen Maintains the Storage Quality of Chinese Chive through Improving Antioxidant Capacity

Plants ◽  
2021 ◽  
Vol 10 (6) ◽  
pp. 1095
Author(s):  
Ke Jiang ◽  
Yong Kuang ◽  
Liying Feng ◽  
Yuhao Liu ◽  
Shu Wang ◽  
...  
Keyword(s):  
Antioxidant Capacity ◽  
Molecular Hydrogen ◽  
Practical Significance ◽  
Total Phenolic ◽  
Guaiacol Peroxidase ◽  
Storage Quality ◽  
Decay Index ◽  
Chinese Chive ◽  
Dpph Scavenging

Chinese chive usually becomes decayed after a short storage time, which was closely observed with the redox imbalance. To cope with this practical problem, in this report, molecular hydrogen (H2) was used to evaluate its influence in maintaining storage quality of Chinese chive, and the changes in antioxidant capacity were also analyzed. Chives were treated with 1%, 2%, or 3% H2, and with air as the control, and then were stored at 4 ± 1 °C. We observed that, compared with other treatment groups, the application of 3% H2 could significantly prolong the shelf life of Chinese chive, which was also confirmed by the obvious mitigation of decreased decay index, the loss ratio of weight, and the reduction in soluble protein content. Meanwhile, the decreasing tendency in total phenolic, flavonoid, and vitamin C contents was obviously impaired or slowed down by H2. Results of antioxidant capacity revealed that the accumulation of reactive oxygen species (ROS) and hydrogen peroxide (H2O2) was differentially alleviated, which positively matched with 2,2-Diphenyl-1-picrylhydrazyl (DPPH) scavenging activity and the improved activities of antioxidant enzymes, including superoxide dismutase (SOD), guaiacol peroxidase (POD), catalase (CAT), and ascorbate peroxidase (APX). Above results clearly suggest that postharvest molecular hydrogen application might be a potential useful approach to improve the storage quality of Chinese chive, which is partially achieved through the alleviation of oxidative damage happening during the storage periods. These findings also provide potential theoretical and practical significance for transportation and consumption of perishable vegetables.

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