In Situ/Operando Methods of Characterizing All-Solid-State Li-Ion Batteries: Understanding Li-Ion Transport during Cycle

2021 ◽  
Author(s):  
Anirudha Jena ◽  
Zizheng Tong ◽  
Behrouz Bazri ◽  
Kevin Iputera ◽  
Ho Chang ◽  
...  
Keyword(s):  
Solid State ◽  
Ion Transport ◽  
Li Ion Batteries ◽  
Li Ion

scholarly journals Molecular Dynamics Study of Ion Transport in Polymer Electrolytes of All-Solid-State Li-Ion Batteries

Micromachines ◽  
2021 ◽  
Vol 12 (9) ◽  
pp. 1012
Author(s):  
Takuya Mabuchi ◽  
Koki Nakajima ◽  
Takashi Tokumasu
Keyword(s):  
Molecular Dynamics ◽  
Solid State ◽  
Ion Transport ◽  
Polyethylene Oxide ◽  
Polymer Electrolytes ◽  
Li Ion Batteries ◽  
Transport Mechanisms ◽  
Li Ion ◽  
Dynamics Simulations ◽  
The Relationship

Atomistic analysis of the ion transport in polymer electrolytes for all-solid-state Li-ion batteries was performed using molecular dynamics simulations to investigate the relationship between Li-ion transport and polymer morphology. Polyethylene oxide (PEO) and poly(diethylene oxide-alt-oxymethylene), P(2EO-MO), were used as the electrolyte materials, and the effects of salt concentrations and polymer types on the ion transport properties were explored. The size and number of LiTFSI clusters were found to increase with increasing salt concentrations, leading to a decrease in ion diffusivity at high salt concentrations. The Li-ion transport mechanisms were further analyzed by calculating the inter/intra-hopping rate and distance at various ion concentrations in PEO and P(2EO-MO) polymers. While the balance between the rate and distance of inter-hopping was comparable for both PEO and P(2EO-MO), the intra-hopping rate and distance were found to be higher in PEO than in P(2EO-MO), leading to a higher diffusivity in PEO. The results of this study provide insights into the correlation between the nanoscopic structures of ion solvation and the dynamics of Li-ion transport in polymer electrolytes.

Seamless Integration of an Elastomer with Electrode Matrix and its In-Situ Conversion into a Solid State Electrolyte for Robust Li-Ion Batteries

2013 ◽  
Vol 23 (47) ◽  
pp. 5941-5951 ◽  
Author(s):  
Matthew M. Ombaba ◽  
Ruxandra Vidu ◽  
Logeeswaran Veerayah Jayaraman ◽  
Mark Triplett ◽  
Jonathan Hsu ◽  
...  
Keyword(s):  
Solid State ◽  
Li Ion Batteries ◽  
Seamless Integration ◽  
Solid State Electrolyte ◽  
Li Ion ◽  
Electrode Matrix

In-situ electron holography charactering Li ions accumulation in the interface between electrode and solid-state-electrolyte

2021 ◽  
Author(s):  
Yang Yang ◽  
Jie Cui ◽  
Hui-Juan Guo ◽  
Xi Shen ◽  
Yuan Yao ◽  
...  
Keyword(s):  
Solid State ◽  
Ion Transport ◽  
Charge Distribution ◽  
Transport Mechanism ◽  
Electron Holography ◽  
Solid State Electrolyte ◽  
Solid State Batteries ◽  
Li Ion ◽  
Solid State Electrolytes

Intensive understanding of the Li-ion transport mechanism in solid-state-electrolytes (SSEs) is crucial for the buildup of industrially scalable solid-state batteries. Here, we report the charge distribution near the electrode/SSEs interface...

In Situ and Ex Situ Diagnosis of Nanoscale Electrochemical Processes Using Miniature All-Solid-State Li-Ion Batteries

2012 ◽  
Vol 18 (S2) ◽  
pp. 1322-1323 ◽  
Author(s):  
V.P. Oleshko ◽  
D. Ruzmetov ◽  
P.M. Haney ◽  
H.J. Lezec ◽  
A.K. Agrawal ◽  
...  
Keyword(s):  
Solid State ◽  
Ex Situ ◽  
Li Ion Batteries ◽  
Electrochemical Processes ◽  
Li Ion

Extended abstract of a paper presented at Microscopy and Microanalysis 2012 in Phoenix, Arizona, USA, July 29 – August 2, 2012.

scholarly journals Unraveling the Reaction Mechanisms of SiO Anodes for Li-Ion Batteries by Combining in Situ 7Li and ex Situ 7Li/29Si Solid-State NMR Spectroscopy

2019 ◽  
Vol 141 (17) ◽  
pp. 7014-7027 ◽  
Author(s):  
Keitaro Kitada ◽  
Oliver Pecher ◽  
Pieter C. M. M. Magusin ◽  
Matthias F. Groh ◽  
Robert S. Weatherup ◽  
...  
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Reaction Mechanisms ◽  
Solid State Nmr ◽  
Ex Situ ◽  
Li Ion Batteries ◽  
Solid State Nmr Spectroscopy ◽  
Li Ion
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