scholarly journals Spin Multiplicity and Solid-State Electrochemical Behavior in Charge-Transfer Co-crystals of DBTTF/F4TCNQ

2021 ◽  
Author(s):  
Federica Solano ◽  
Paolo Inaudi ◽  
Mario Chiesa ◽  
Gabriele Kociok-Köhn ◽  
Enrico Salvadori ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Solid State ◽  
Electrochemical Behavior ◽  
Spin Multiplicity

Solid-state redox couple mediated water splitting

2021 ◽  
Author(s):  
Duanduan Liu ◽  
Wei Wei ◽  
Maidina Mahemu ◽  
Hao Qin ◽  
Kai Zhu ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Solid State ◽  
Water Splitting ◽  
Redox Couple ◽  
Electrochemical Water Splitting

The solid-state redox couple is a vital charge transfer medium for electrochemical water splitting.

Solid State Structural Properties of Multibridged [3n]Cyclophanes and Their Charge Transfer Complexes

ChemInform ◽  
2004 ◽  
Vol 35 (13) ◽  
Author(s):  
Mikio Yasutake ◽  
Toru Koga ◽  
Chultack Lim ◽  
Ming Zhou ◽  
Wakana Matsuda-Sentou ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Solid State ◽  
Structural Properties ◽  
Charge Transfer Complexes

Cationic tri(ferrocenecarbonitrile)silver(I)

2018 ◽  
Vol 73 (11) ◽  
pp. 759-764
Author(s):  
Frank Strehler ◽  
Tobias Rüffer ◽  
Julian Noll ◽  
Dieter Schaarschmidt ◽  
Alexander Hildebrandt ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Solid State ◽  
Electrochemical Behavior ◽  
Potential Range

AbstractThe synthesis of the tri-coordinated ferrocenecarbonitrile silver(I) complex [Ag(N≡CFc)3]OTf (3) is reported. Its electrochemical behavior shows that the three ferrocenyl units are oxidized in a very close potential range. In addition, the molecular structure of 3 in the solid state is discussed, showing that silver(I) is exclusively coordinated by three ferrocenecarbonitrile molecules.

Thiol end-capped titanium–copper complexes: Synthesis, solid state structure and electrochemical behavior

2008 ◽  
Vol 361 (6) ◽  
pp. 1659-1667 ◽  
Author(s):  
Heinrich Lang ◽  
Katrin Rößler ◽  
Deeb Taher ◽  
Rudolf Holze ◽  
Bernhard Walfort
Keyword(s):  
Solid State ◽  
Electrochemical Behavior ◽  
Copper Complexes ◽  
State Structure ◽  
Solid State Structure

The lowest energy excited states of the binuclear silver(I) halide complexes, Ag2(dmb)2X2. Metal-centered or charge transfer states?

1994 ◽  
Vol 72 (3) ◽  
pp. 705-713 ◽  
Author(s):  
Daniel Piché ◽  
Pierre D. Harvey
Keyword(s):  
Charge Transfer ◽  
Solid State ◽  
Excited States ◽  
Silver Halide ◽  
Molecular Orbital Calculations ◽  
Isocyanide Ligands ◽  
Visible Spectra ◽  
Halide Complexes ◽  
The Media ◽  
Uv Visible

The nature of the lowest energy excited states of the Ag2(dmb)2X2 complexes (X = Cl, Br, I; dmb = 1,8-diisocyano-ρ-menthane) have been addressed both experimentally and theoretically. It is shown that the lowest energy excited states of the complexes are charge transfer states from the silver-halide frame to the isocyanide ligands (M/XLCT) based upon UV-visible spectra and emission polarization ratio measurements, and extended Hückel molecular orbital calculations (EHMO). The metal-centered dσ* → pσ bands have been observed in the higher energy region of the spectra (232–242 nm). The complexes are luminescent (440 ≤ λe ≤ 480 nm) both in a glass and in the solid state at 77 K where the emission lifetimes, τe, range from 20 to 90 µs, which depend upon the nature of the halide (for the solid state data) and the media. No emission is observed at room temperature.

Bonding and interlayer charge transfer in the solid state compound Na1.9Cu2Se2Cu2O

1995 ◽  
Vol 216 (2) ◽  
pp. 177-182 ◽  
Author(s):  
Gerardo Chacon ◽  
Xiangyun Long ◽  
Chong Zheng
Keyword(s):  
Charge Transfer ◽  
Solid State

Charge-Transfer Crystal with Segregated Packing Structure Constructed with Hexaarylbenzene and Tetracyanoquinodimethane

CrystEngComm ◽  
2021 ◽  
Author(s):  
Rempei Ando ◽  
Mingoo Jin ◽  
Hajime Ito
Keyword(s):  
Charge Transfer ◽  
Solid State ◽  
Electron Donor ◽  
Packing Structure ◽  
Donor And Acceptor ◽  
Solid State Materials ◽  
Electron Donor And Acceptor ◽  
Acceptor Molecules

Charge-transfer (CT) crystals bearing segregated domains between the electron donor and acceptor molecules are a promising platform for developing new organic functional solid-state materials. However, there is limited diversity in...

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