Thermodynamics of Electrical Double Layers with Electrostatic Correlations

2020 ◽  
Vol 124 (49) ◽  
pp. 26830-26842
Author(s):  
Ankur Gupta ◽  
Ananth Govind Rajan ◽  
Emily A. Carter ◽  
Howard A. Stone
Keyword(s):  
Double Layers ◽  
Electrical Double Layers

Electrokinetics of polymeric fluids in narrow rectangular confinements

Soft Matter ◽  
2021 ◽  
Author(s):  
Aditya Natu ◽  
Uddipta Ghosh
Keyword(s):  
Cross Section ◽  
Rectangular Cross Section ◽  
Double Layers ◽  
Polymeric Fluids ◽  
Polymeric Liquids ◽  
Electrical Double Layers

Flow of polymeric liquids in narrow confinements of rectangular cross section, in the presence of electrical double layers is analyzed here. Our analysis is motivated by the fact that many...

Molecular solvent models of electrical double layers

1991 ◽  
Vol 36 (11-12) ◽  
pp. 1677-1684 ◽  
Author(s):  
G.M. Torrie ◽  
G.N. Patey
Keyword(s):  
Double Layers ◽  
Electrical Double Layers ◽  
Solvent Models

Simulation of Flow and Mass Transport in a Meander Microchannel Subject to Electroosmotic Pumping

2003 ◽  
Author(s):  
Dominik P. J. Barz ◽  
Peter Ehrhard
Keyword(s):  
Mass Transport ◽  
Double Layers ◽  
Complex Flow ◽  
Electrical Field ◽  
Electrical Fields ◽  
Electrical Double Layers ◽  
Electroosmotic Pumping ◽  
Pressure Driven Flow ◽  
Flow And Mass Transport ◽  
Pressure Driven

We have investigated the flow and mass transport within an electroosmotically-pumped incompressible liquid through a meander microchannel system. We employ two-dimensional, time-dependent Finite Element simulations in conjunction with a matched asymptotic treatment of the electrical double layers. The electroosmotic pumping is realized for two idealized and two realistic electrical fields, while a pressure-driven flow is used for comparison. We focus on the aspects of the electroosmotic transport. We find for most of the electroosmotically-driven cases rather complex flow fields, involving recirculation regions. These recirculation regions in all cases increase dispersion. (i) The least dispersion is associated with a plug-type velocity profile, which is obtained for an idealized purely wall-tangential orientation of the electrical field. (ii, iii) We find that both, the idealized horizontal electrical field and the real electrical field between two vertical plates give considerably higher dispersion than the pressure-driven flow. Vertical plate electrodes, therefore, do not allow for a electrical field, which minimizes dispersion. (iv) The arrangement of two point electrodes at the in and out sections likewise proves to be no optimal means to reduce dispersion beyond the pressure-driven flow. Thus, meander geometries of channels, in general, cause severe problems if electroosmotic pumping needs to be achieved in combination with minimized dispersion.

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