High 3D Proton Conductivity of a 2D Zn(II) Metal–Organic Framework Synthesized via Water-Assisted Single-Crystal-to-Single-Crystal Phase Transformation

2020 ◽  
Vol 124 (35) ◽  
pp. 18901-18910
Author(s):  
Rashmi A. Agarwal ◽  
Amit Das ◽  
Shobit Omar
Keyword(s):  
Phase Transformation ◽  
Single Crystal ◽  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Crystal Phase ◽  
Metal Organic ◽  
Crystal Phase Transformation ◽  
Organic Framework

scholarly journals Guest-Dependent Single-Crystal-to-Single-Crystal Phase Transitions in a Two-Dimensional Uranyl-Based Metal–Organic Framework

2018 ◽  
Vol 19 (1) ◽  
pp. 506-512 ◽  
Author(s):  
Sylvia L. Hanna ◽  
Xuan Zhang ◽  
Ken-ichi Otake ◽  
Riki J. Drout ◽  
Peng Li ◽  
...  
Keyword(s):  
Phase Transitions ◽  
Single Crystal ◽  
Metal Organic Framework ◽  
Crystal Phase ◽  
Two Dimensional ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Enhanced proton conductivity in a flexible metal–organic framework promoted by single-crystal-to-single-crystal transformation

2021 ◽  
Vol 57 (1) ◽  
pp. 65-68
Author(s):  
Xi Chen ◽  
Zhongyue Zhang ◽  
Jin Chen ◽  
Sergei Sapchenko ◽  
Xue Han ◽  
...  
Keyword(s):  
Single Crystal ◽  
Proton Conductivity ◽  
Structural Transition ◽  
Metal Organic Framework ◽  
Crystal Transformation ◽  
P Transformation ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

Transformation of MFM-722(Pb)-DMA to MFM-722(Pb)-H2O leads to an increase in proton conductivity linked to a structural transition.

Single Crystal X-ray Diffraction Studies of Carbon Dioxide and Fuel-Related Gases Adsorbed on the Small Pore Scandium Terephthalate Metal Organic Framework, Sc2(O2CC6H4CO2)3

Langmuir ◽  
2009 ◽  
Vol 25 (6) ◽  
pp. 3618-3626 ◽  
Author(s):  
Stuart R. Miller ◽  
Paul A. Wright ◽  
Thomas Devic ◽  
Christian Serre ◽  
Gérard Férey ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Single Crystal ◽  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
X Ray ◽  
Small Pore ◽  
Metal Organic ◽  
Organic Framework

Superlong Single-Crystal Metal–Organic Framework Nanotubes

2018 ◽  
Vol 140 (45) ◽  
pp. 15393-15401 ◽  
Author(s):  
Lianli Zou ◽  
Chun-Chao Hou ◽  
Zheng Liu ◽  
Huan Pang ◽  
Qiang Xu
Keyword(s):  
Single Crystal ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

A Mn(II) Metal-Organic Framework Constructed from a Tetrahedral Silicon-Cored Ligand

2013 ◽  
Vol 275-277 ◽  
pp. 2367-2370
Author(s):  
Qing Yu Ma ◽  
Rui Fang Guan ◽  
Guo Zhong Li ◽  
Deng Xu Wang
Keyword(s):  
Single Crystal ◽  
Metal Organic Framework ◽  
Diffusion Method ◽  
X Ray Diffraction ◽  
X Ray ◽  
Slow Diffusion ◽  
Sheet Structure ◽  
Metal Organic ◽  
1D Chains ◽  
Organic Framework

A novel metal-organic framework, MnCl2(BIPS)2•2CH3OH•2H2O (1) were synthesized from MnCl2 and a tetrahedral silicon-cored ligand, Me2Si(p-C6H4-imdazol-1-yl)2 (BIPS) under the slow diffusion method. The structure was determined by single-crystal X-ray diffraction. Complex 1 is a 2D sheet structure constructed from 1D chains with 34-atom metallamacrocycles.

scholarly journals A confinement of N-heterocyclic molecules in a metal–organic framework for enhancing significant proton conductivity

RSC Advances ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 355-364
Author(s):  
My V. Nguyen ◽  
Thang B. Phan ◽  
Man V. Tran ◽  
Tuyet A. T. Nguyen ◽  
Hung N. Nguyen
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Heterocyclic Molecules ◽  
Metal Organic ◽  
Significant Proton ◽  
Organic Framework

A series of N-heterocyclic⊂VNU-23 materials have been prepared via the impregnation procedure of N-heterocyclic molecules into VNU-23.

Towards solvent tuning of slow magnetic relaxation and ferroelectric properties in a dysprosium metal–organic framework system

2019 ◽  
Vol 234 (1) ◽  
pp. 33-41
Author(s):  
Lina Zhang ◽  
Shuyan Guan ◽  
Yunchang Fan ◽  
Chenxia Du ◽  
Dan Zhao ◽  
...  
Keyword(s):  
Single Crystal ◽  
Single Molecule ◽  
Magnetic Relaxation ◽  
Metal Organic Framework ◽  
Ferroelectric Properties ◽  
Relaxation Rates ◽  
Slow Magnetic Relaxation ◽  
Metal Organic ◽  
Solvent Molecules ◽  
Organic Framework

Abstract A new dysprosium metal–organic framework {[Dy2(L)3(H2O)4]·(acetone)2·(H2O)3}n (Dy2-Acetone) with single-molecule magnet and ferroelectric properties was synthesized through a solvent-induced single-crystal-to-single-crystal (SCSC) transformation. Notably, exchange of the coordinated and guest solvent molecules lead to different magnetic relaxation and ferroelectric properties in the dysprosium MOF system, Dy2-DMF and Dy2-Acetone. Study reveals that the tunable magnetic relaxation behaviors are most likely a result of different local coordination sphere and lattice solvent molecules within the pores which influenced and tuned the relaxation rates of the magnetization. Moreover, disparate polar solvent molecules confined in the MOFs may be the key factors for their different ferroelectric properties.

Pressure-Induced Bond Rearrangement and Reversible Phase Transformation in a Metal-Organic Framework

2014 ◽  
Vol 126 (22) ◽  
pp. 5689-5692 ◽  
Author(s):  
Elinor C. Spencer ◽  
Mangalampalli S. R. N. Kiran ◽  
Wei Li ◽  
Upadrasta Ramamurty ◽  
Nancy L. Ross ◽  
...  
Keyword(s):  
Phase Transformation ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Bond Rearrangement ◽  
Reversible Phase ◽  
Organic Framework
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