Inelastic Scattering of CN Radicals at the Gas–Liquid Interface Probed by Frequency-Modulated Absorption Spectroscopy

2020 ◽  
Vol 124 (30) ◽  
pp. 16439-16448
Author(s):  
Paul D. Lane ◽  
Katya E. Moncrieff ◽  
Stuart J. Greaves ◽  
Kenneth G. McKendrick ◽  
Matthew L. Costen
2005 ◽  
Vol 76 (5) ◽  
pp. 054104 ◽  
Author(s):  
Jan-Dierk Grunwaldt ◽  
Michael Ramin ◽  
Markus Rohr ◽  
Alexej Michailovski ◽  
Greta R. Patzke ◽  
...  

The kinetics of the reaction between oxygen atoms and cyanogen have been studied in a capacity flow reactor at temperatures between 570 and 687 °K. The concentration of CN radicals was measured by electronic absorption spectroscopy. This work confirms the previously proposed mechanism (part II). The initial step has a rate constant of k 1 = 2∙5 (± 0∙3) x 10 13 exp ( – 11000±2000/ RT ) cm 3 mole –1 s –1 . CN radicals are removed mainly by reactions (4) and (2) for which k 4 = 6∙3 (±3∙5) x 10 13 exp (–2400±700/ RT ) cm 3 mole –1 s –1 and k 2 = 4∙4 (±2∙0) x 10 12 cm 3 mole –1 s –1 . CN+O = CO+N, (4) CN+O 2 = NCO+O. (2) The rates of reaction of CN with NO and NH 3 were also measured; for CH 4 and H 2 limiting values were obtained.


In the current study, we have experimentally and comparatively investigated and compared malignant human cancer cells and tissues before and after irradiating of synchrotron radiation using Nuclear Inelastic Scattering Spectroscopy (NISS) and Nuclear inelastic Absorption Spectroscopy (NIAS). It is clear that malignant human cancer cells and tissues have gradually transformed to benign human cancer cells and tissues under synchrotron radiation with the passing of time (Figures 1 and 2)[1–126].


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